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Volumn , Issue , 2007, Pages 1-17

Asymmetric Organocatalysis: A New Stream in Organic Synthesis

Author keywords

Asymmetric organocatalysis; Catalysts; Enantioselective organocatalysis; Historical background; Organic synthesis; Reaction types

Indexed keywords


EID: 84861508079     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9783527610945.ch1     Document Type: Chapter
Times cited : (10)

References (154)
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    • As defined in Ref. [71]: "There are two aminocatalytic pathways. Iminium catalysis directly utilizes the higher reactivity of the iminium ion in comparison to the carbonyl species and facilitates Knoevenagel-type condensations, cyclo-and nucleophilic additions, and cleavage of s-bonds adjacent to the α-carbon. Enamine catalysis on the other hand involves catalytically generated enamine intermediates that are formed via deprotonation of an iminium ion, and react with various electrophiles or undergo pericyclic reactions."
    • As defined in Ref. [71]: "There are two aminocatalytic pathways. Iminium catalysis directly utilizes the higher reactivity of the iminium ion in comparison to the carbonyl species and facilitates Knoevenagel-type condensations, cyclo-and nucleophilic additions, and cleavage of s-bonds adjacent to the α-carbon. Enamine catalysis on the other hand involves catalytically generated enamine intermediates that are formed via deprotonation of an iminium ion, and react with various electrophiles or undergo pericyclic reactions."
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    • The natural compound is extracted essentially from chicken feathers.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.