Profile of trans fatty acids (FAs) including trans polyunsaturated fas in representative fast food samples

Journal of Agricultural and Food Chemistry

Volumn 60, Issue 18, 2012, Pages 4567-4577

  Tyburczy, Cynthia ^a   Delmonte, Pierluigi ^a   Fardin Kia, Ali Reza ^a   Mossoba, Magdi M ^a   Kramer, John K G ^b   Rader, Jeanne I ^a  

^a CENTER FOR DRUG EVALUATION AND RESEARCH   (United States)

^b GUELPH RESEARCH AND DEVELOPMENT CENTRE   (Canada)

Author keywords

AOCS Official Method Ce 1j 07; fast food; gas chromatography; SLB IL111 ionic liquid column; SP 2560 column; trans fat

Indexed keywords

AOCS OFFICIAL METHOD CE 1J-07; FAST FOOD; ISOMERIC COMPOSITIONS; LIQUID COLUMNS; METHYL ESTERS; QUANTITATIVE RESULT; SAMPLE ANALYSIS; TRANS FATS; TRANS FATTY ACID;

GAS CHROMATOGRAPHY; IONIC LIQUIDS; OILS AND FATS;

UNSATURATED FATTY ACIDS;

TRANS FATTY ACID; UNSATURATED FATTY ACID;

CATERING SERVICE; CHEMISTRY; COMPARATIVE STUDY; CONFERENCE PAPER; FAST FOOD; FOOD CONTROL; GAS CHROMATOGRAPHY; METHODOLOGY; STANDARD; STEREOISOMERISM; UNITED STATES;

FAST FOODS; FATTY ACIDS, UNSATURATED; FLAME IONIZATION; FOOD INSPECTION; MARYLAND; RESTAURANTS; STEREOISOMERISM; TRANS FATTY ACIDS;

EID: 84861043651     PISSN: 00218561     EISSN: 15205118     Source Type: Journal    
DOI: 10.1021/jf300585s     Document Type: Conference Paper

References (37)

1. Mozaffarian, D.; Aro, A.; Willett, W. C. Health effects of trans -fatty acids: Experimental and observational evidence Eur. J. Clin. Nutr. 2009, 63, S5-S21
2. Hill, E. G.; Johnson, S. B.; Lawson, L. D.; Mahfouz, M. M.; Holman, R. T. Perturbation of the metabolism of essential fatty acids by dietary partially hydrogenated vegetable oil Proc. Natl. Acad. Sci. U.S.A. 1982, 79, 953-957
3. Innis, S. M. Trans fatty intakes during pregnancy, infancy and early childhood Atheroscler. Suppl. 2006, 7, 17-20 (Pubitemid 43831745)
4. Food and Nutrition Board. Letter Report on Dietary Reference Intakes for Trans Fatty Acids; The National Academies Press: Washington, DC, 2002.
5. Third Report of the National Cholesterol Education Program (NCEP) Expert Panel on Detection, Evaluation, and Treatment of High Blood Cholesterol in Adults (Adult Treatment Panel III) final report. Circulation 2002, 106, 3143-3421.
6. Kris-Etherton, P. M.; Innis, S. American Dietetic Association; Dietitians of Canada. Position of the American Dietetic Association and Dietitians of Canada: Dietary fatty acids J. Am. Diet. Assoc. 2007, 107, 1599-1611
7. Wolff, R. L. Trans -polyunsaturated fatty acids in French edible rapeseed and soybean oils J. Am. Oil. Chem. Soc. 1992, 69, 106-110
8. Bruhl, L. Determination of trans fatty acids in cold pressed oils Eur. J. Med. Res. 1995, 1, 89-93
9. Fournier, V.; Destaillats, F.; Hug, B.; Golay, P. A.; Joffre, F.; Juaneda, P.; Semon, E.; Dionisi, F.; Lambelet, P.; Sebedio, J. L.; Berdeaux, O. Quantification of eicosapentaenoic and docosahexaenoic acid geometrical isomers formed during fish oil deodorization by gas-liquid chromatography J. Chromatogr., A 2007, 1154, 353-359 (Pubitemid 46850740)
10. Baylin, A.; Kabagambe, E. K.; Ascherio, A.; Spiegelman, D.; Campos, H. High 18:2 trans -fatty acids in adipose tissue are associated with increased risk of nonfatal acute myocardial infarction in Costa Rican adults J. Nutr. 2003, 133, 1186-1191 (Pubitemid 36407147)
11. Lemaitre, R. N.; King, I. B.; Mozaffarian, D.; Sotoodehnia, N.; Rea, T. D.; Kuller, L. H.; Tracy, R. P.; Siscovick, D. S. Plasma phospholipid trans fatty acids, fatal ischemic heart disease, and sudden cardiac death in older adults: The Cardiovascular Health Study Circulation 2006, 114, 209-215 (Pubitemid 44297114)
12. Lemaitre, R. N.; King, I. B.; Raghunathan, T. E.; Pearce, R. M.; Weinmann, S.; Knopp, R. H.; Copass, M. K.; Cobb, L. A.; Siscovick, D. S. Cell membrane trans -fatty acids and the risk of primary cardiac arrest Circulation 2002, 105, 697-701 (Pubitemid 34157372)
13. Food Labeling; Nutrition Labeling of Standard Menu Items in Restaurants and Similar Retail Food Establishments; Proposed Rule. Fed. Regist. 2011, 76, 19191-19236.
14. Mozaffarian, D.; Jacobson, M. F.; Greenstein, J. S. Food reformulations to reduce trans fatty acids N. Engl. J. Med. 2010, 362, 2037-2039
15. AOCS. AOCS Official Method Ce 1h-05: Determination of cis -, trans -, saturated, monounsaturated and polyunsaturated fatty acids in vegetable or non-ruminant animal oils and fats by capillary GLC. Official Methods and Recommended Practices of the AOCS, 6 th ed.; AOCS: Champaign, IL, 2009.
16. AOCS. AOCS Official Method Ce 1j-07: Determination of cis -, trans -, saturated, monounsaturated, and polyunsaturated fatty acids in extracted fats by capillary GLC. Official Methods and Recommended Practices of the AOCS, 6 th ed.; AOCS: Champaign, IL, 2009.
17. AOCS. AOAC Official Method 996.06: Fat (total, saturated, and unsaturated) in foods. Official Methods of Analysis, 18 th ed.; AOAC International: Gaithersburg, MD, 2005.
18. Delmonte, P.; Kia, A. R.; Hu, Q.; Rader, J. I. Review of methods for preparation and gas chromatographic separation of trans and cis reference fatty acids J. AOAC Int. 2009, 92, 1310-1326
19. Delmonte, P.; Rader, J. I. Evaluation of gas chromatographic methods for the determination of trans fat Anal. Bioanal. Chem. 2007, 389, 77-85 (Pubitemid 47325214)
20. Delmonte, P.; Fardin Kia, A. R.; Kramer, J. K.; Mossoba, M. M.; Sidisky, L.; Rader, J. I. Separation characteristics of fatty acid methyl esters using SLB-IL111, a new ionic liquid coated capillary gas chromatographic column J. Chromatogr., A 2011, 1218, 545-554
21. Delmonte, P.; Fardin Kia, A. R.; Kramer, J. K.; Mossoba, M. M.; Sidisky, L.; Tyburczy, C.; Rader, J. I. Evaluating the ionic liquid GC column SLB-IL111 for the determination of the fatty acids in milk fat J. Chromatogr., A 2012, 1233, 137-146
22. Delmonte, P.; Hu, Q.; Kia, A. R.; Rader, J. I. Preparation, chromatographic separation and relative retention times of cis / trans heptadecaenoic (17:1) fatty acids J. Chromatogr., A 2008, 1214, 30-36
23. Rozema, B.; Mitchell, B.; Winters, D.; Kohn, A.; Sullivan, D.; Meinholz, E. Proposed modifications to AOAC 996.06, optimizing the determination of trans fatty acids: Presentation of data J. AOAC Int. 2008, 91, 92-97 (Pubitemid 351315748)
24. Ratnayake, W. M. Overview of methods for the determination of trans fatty acids by gas chromatography, silver-ion thin-layer chromatography, silver-ion liquid chromatography, and gas chromatography/mass spectrometry J. AOAC Int. 2004, 87, 523-539
25. Brenna, J. T.; Tyburczy, C. Identification of double bond location in fatty acid methyl esters by covalent adduct chemical ionization tandem mass spectrometry. http://lipidlibrary.aocs.org/topics/caci-ms/index.htm.
26. Precht, D.; Molkentin, J. Trans fatty acids: Implications for health, analytical methods, incidence in edible fats and intake (a review) Nahrung 1995, 39, 343-374
27. Stender, S.; Dyerberg, J.; Astrup, A. High levels of industrially produced trans fat in popular fast foods N. Engl. J. Med. 2006, 354, 1650-1652
28. Eckel, R. H.; Borra, S.; Lichtenstein, A. H.; Yin-Piazza, S. Y. Understanding the complexity of trans fatty acid reduction in the American diet: American Heart Association Trans Fat Conference 2006: Report of the Trans Fat Conference Planning Group Circulation 2007, 115, 2231-2246 (Pubitemid 46659080)
29. Lichtenstein, A. H.; Appel, L. J.; Brands, M.; Carnethon, M.; Daniels, S.; Franch, H. A.; Franklin, B.; Kris-Etherton, P.; Harris, W. S.; Howard, B.; Karanja, N.; Lefevre, M.; Rudel, L.; Sacks, F.; Van Horn, L.; Winston, M.; Wylie-Rosett, J. Diet and Lifestyle Recommendations, Revision 2006: A scientific statement from the American Heart Association Nutrition Committee Circulation 2006, 114, 82-96 (Pubitemid 44305278)
30. Richter, E. K.; Shawish, K. A.; Scheeder, M. R. L.; Colombani, P. C. Trans fatty acid content of selected Swiss foods: The TransSwissPilot study J. Food Compos. Anal. 2009, 22, 479-484
31. U.S. Food and Drug Administration. Food labeling; trans fatty acids in nutrition labeling; consumer research to consider nutrient content and health cleaims and possible footnote or disclosure statements; final rule and proposed rule. Fed. Regist. 2003, 68, 41434-41506.
32. Lock, A. L.; Bauman, D. E. Modifying milk fat composition of dairy cows to enhance fatty acids beneficial to human health Lipids 2004, 39, 1197-1206
33. Bauman, D. E.; Griinari, J. M. Nutritional regulation of milk fat synthesis Annu. Rev. Nutr. 2003, 23, 203-227 (Pubitemid 37059722)
34. Cruz-Hernandez, C.; Kramer, J. K.; Kennelly, J. J.; Glimm, D. R.; Sorensen, B. M.; Okine, E. K.; Goonewardene, L. A.; Weselake, R. J. Evaluating the conjugated linoleic acid and trans 18:1 isomers in milk fat of dairy cows fed increasing amounts of sunflower oil and a constant level of fish oil J. Dairy Sci. 2007, 90, 3786-801 (Pubitemid 350045258)
35. Aldai, N.; Dugan, M. E. R.; Rolland, D. C.; Kramer, J. K. Survey of the fatty acid composition of Canadian beef: Backfat and longissimus lumborum muscle Can. J. Anim. Sci. 2009, 89, 315-329
36. Ratnayake, W. M.; Plouffe, L. J.; Pasquier, E.; Gagnon, C. Temperature-sensitive resolution of cis-and trans -fatty acid isomers of partially hydrogenated vegetable oils on SP-2560 and CP-Sil 88 capillary columns J. AOAC Int. 2002, 85, 1112-1118 (Pubitemid 135694537)
37. Precht, D.; Molkentin, J. Overestimation of linoleic acid and trans -C18:2 isomers in milk fats with emphasis on trans 9, trans 12-octadecadienoic acid Milchwissenschaft 2003, 58, 30-34 (Pubitemid 36178374)