Fragmentation of a linoleate-derived γ-hydroperoxy-α,β- unsaturated epoxide to γ-hydroxy- and γ-oxo-alkenals involves a unique pseudo-symmetrical diepoxycarbinyl radical

Free Radical Biology and Medicine

Volumn 52, Issue 3, 2012, Pages 601-606

  Gu, Xiaodong ^a,b   Salomon, Robert G ^a  

^a CASE WESTERN RESERVE UNIVERSITY   (United States)

^b LERNER RESEARCH INSTITUTE   (United States)

Author keywords

unsaturated epoxide; Free radicals; HNE; HODA; KODA; Linoleate derived hydroperoxy ; Lipid peroxidation; ONE; Pseudo symmetrical diepoxycarbinyl radical

Indexed keywords

13 HYDROPEROXY 9,10 EPOXYOCTADECA 11 ENOIC ACID; 4 HYDROXYNONENAL; 4 OXO 2 NONENAL; 9 HYDROXY 12 OXO 10 DODECENOIC ACID; 9 KETO 12 OXO 10 DODECENOIC ACID; ALDEHYDE DERIVATIVE; EPOXIDE; UNCLASSIFIED DRUG; UNSATURATED FATTY ACID;

ARTICLE; COLLISIONALLY ACTIVATED DISSOCIATION; FRAGMENTATION REACTION; LIPID PEROXIDATION; LIQUID CHROMATOGRAPHY; MASS SPECTROMETRY; PRIORITY JOURNAL;

ALDEHYDES; EPOXY COMPOUNDS; FREE RADICALS; HYDROLYSIS; IRON; LINOLEIC ACIDS; LIPID PEROXIDATION; OXIDATION-REDUCTION; TANDEM MASS SPECTROMETRY;

EID: 84856279992     PISSN: 08915849     EISSN: 18734596     Source Type: Journal    
DOI: 10.1016/j.freeradbiomed.2011.11.013     Document Type: Article

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