Ring opening of the cyclopropylcarbinyl radical and its N- and O- substituted analogues: A theoretical examination of very fast unimolecular reactions

Journal of the American Chemical Society

Volumn 120, Issue 39, 1998, Pages 10223-10233

  Smith, David M ^a   Nicolaides, Athanassios ^a,c   Golding, Bernard T ^b   Radom, Leo ^a  

^a AUSTRALIAN NATIONAL UNIVERSITY   (Australia)

^b NEWCASTLE UNIVERSITY   (United Kingdom)

^c MIE UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

AZIRIDINE DERIVATIVE; CYCLOPROPANE DERIVATIVE; METHANOL DERIVATIVE; RADICAL;

ARTICLE; CHEMICAL REACTION; ENERGY TRANSFER; MOLECULAR DYNAMICS; REACTION ANALYSIS; STEREOCHEMISTRY; THEORY; THERMODYNAMICS;

EID: 0032494434     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja980635m     Document Type: Article

References (9)

1. Beckwith, A. L. J.; Bowry, V. J. Am. Chem. Soc. 1994, 116, 2710-2716.
2. For a recent review, see: Nonhebel, D. C. Chem. Soc. Rev. 1993, 347-359.
3. See, for example: He, M.; Dowd, P. J. Am. Chem. Soc. 1996, 118, 711.
4. See, for example: Newcomb, M.; Le Tadic-Biadatti, M.; Chestney, D. L.; Roberts, E. S.; Hollenberg, P. F. J. Am. Chem. Soc. 1995, 117, 12085-12091.
5. For a recent review, see: Newcomb, M. Tetrahedron 1993, 49, 1151-1176.
6. Buckel, W.; Golding, B. T. Chem. Soc. Rev. 1996, 329-337.
7. Ballinger, M. D.; Frey, P. A.; Reed, G. H.; LoBrutto, R. Biochemistry 1995, 34, 10086-10093.
8. Baldwin, J. E.; Adlington, R. M.; Lajoie, G. A.; Lowe, C.; Baird, P. D. J. Chem. Soc., Chem. Commun. 1988, 775.
9. Silverman, R. B.; Cesarone, J. M.; Xingliang, L. J. Am. Chem. Soc. 1993, 115, 4955-4961.