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84862460791
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2O. All manipulations must be performed in an inert atmosphere
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2O. All manipulations must be performed in an inert atmosphere.
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note
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CAUTION: Ozone is a known health hazard and care must be taken to prevent exposure. Ozone should only be generated and used in a well-ventilated environment, such as a fume hood. In addition, ozone is damaging to electronic equipment. A protocol is available in the literature for trapping ozone on silica gel in a glass vessel at dry-ice temperatures. We chose not to employ this method due to the risk of explosion if the vessel is allowed to warm to near room temperature.
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Decreasing the valve-sample distance to ∼7.5 cm resulted in no discernible effect
-
Decreasing the valve-sample distance to ∼7.5 cm resulted in no discernible effect.
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30
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8344244380
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note
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Both a hot filament ion gauge and a cold cathode ionization gauge in operation in the chamber during dosing of O-containing gases were found to generate species capable of oxidizing the Si headgroup of the monolayer.
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8344269230
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Supporting Information for XPS wide scans before and after ozone-induced oxidation
-
See Supporting Information for XPS wide scans before and after ozone-induced oxidation.
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44
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8344268414
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The Si 2s core level exhibits a shift to higher binding energy but is difficult to quantify due to its low photoelectron cross section and broad natural line width
-
The Si 2s core level exhibits a shift to higher binding energy but is difficult to quantify due to its low photoelectron cross section and broad natural line width.
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47
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8344251818
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The difference in the amount of C remaining for the experiments performed in the two chambers may arise from differences in the ozone flux that reaches the sample
-
The difference in the amount of C remaining for the experiments performed in the two chambers may arise from differences in the ozone flux that reaches the sample.
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1442308409
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