Relaxed but highly compact diansa metallacyclophanes

Journal of the American Chemical Society

Volumn 133, Issue 41, 2011, Pages 16537-16552

  Farràs, Pau ^a   Teixidor, Francesc ^a   Rojo, Isabel ^a   Kivekäs, Raikko ^b   Sillanpää, Reijo ^c   González Cardoso, Patricia ^a   Viñas, Clara ^a  

^a UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

^b UNIVERSITY OF HELSINKI   (Finland)

^c UNIVERSITY OF JYVÄSKYLÄ   (Finland)

Author keywords

[No Author keywords available]

Indexed keywords

ACCEPTOR MOIETIES; CHALCOGEN ATOMS; DFT CALCULATION; DONOR AND ACCEPTOR; ELECTRON DELOCALIZATION; ELECTRON LONE PAIR; LONE PAIR; MALDI TOF MS; NMR CHEMICAL SHIFTS; PHOSPHINE DONORS; SINGLE CRYSTAL X-RAY DIFFRACTION; SYNERGISTIC EFFECT; TECHNIQUES USED; UV VISIBLE SPECTROSCOPY; VAN DER WAALS RADIUS;

BENZENE; CRYSTAL STRUCTURE; HYDROGEN PEROXIDE; OXIDATION; PHOSPHORUS; PHOSPHORUS COMPOUNDS; SELENIUM; SELENIUM COMPOUNDS; SINGLE CRYSTALS; SULFUR; ULTRAVIOLET SPECTROSCOPY; VAN DER WAALS FORCES; X RAY DIFFRACTION;

CYCLIC VOLTAMMETRY;

CHALCOGEN; CYCLOPHANE DERIVATIVE; HYDROGEN PEROXIDE; METALLACYCLOPHANE; OXYGEN; PHOSPHORUS; SELENIUM; SULFUR; UNCLASSIFIED DRUG;

ARTICLE; ATOM; CHEMICAL BOND; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; CYCLIC POTENTIOMETRY; DENSITY FUNCTIONAL THEORY; ELECTROCHEMISTRY; ELECTRON; ISOMER; LOW TEMPERATURE; NUCLEAR MAGNETIC RESONANCE; OXIDATION; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; RACEMIC MIXTURE; STRUCTURE ANALYSIS; SYNTHESIS; X RAY DIFFRACTION;

COBALT; CRYSTALLOGRAPHY, X-RAY; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; QUANTUM THEORY; STEREOISOMERISM;

EID: 80054720852     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja205850p     Document Type: Article

References (67)

1. Hawthorne, M. F.; Young, D. C.; Wegner, P. A. J. Am. Chem. Soc. 1965, 87, 1818
2. Hawthorne, M. F.; Andrews, T. D. Chem. Commun. 1965, 443
3. Hawthorne, M. F.; Young, D. C.; Andrews, T. D.; Hove, D. V.; Pilling, R. L.; Pitts, A. D.; Reinjes, M.; Warren, L. F.; Wegner, P. A. J. Am. Chem. Soc. 1968, 90, 879
4. Mingos, D. M. P. J. Chem. Soc., Dalton Trans. 1977, 602
5. Grabulosa, A. P-Stereogenic Ligands in Enantioselective Catalysis; RSC Catalysis Series; Royal Society of Chemistry: Cambridge, 2011.
6. Rinehart, A. K., Jr.; Frerichs, P. A.; Kittle, L. F.; Westmann, L. F.; Gustafson, R. L.; Pruett, J. E.; McMahon, J. E. J. Am. Chem. Soc. 1960, 82, 4111
7. Osborne, A. G.; Whiteley, R. H. J. Organomet. Chem. 1975, 101, C27
8. For a recent review see: Herbert, D. E.; Mayer, U. F. J.; Manners, I. Angew. Chem., Int. Ed. 2007, 46, 5060
9. Brandt, P. F.; Compton, D. L.; Rauchfuss, T. B. Organometallics 1998, 17, 2702
10. Rojo, I.; Teixidor, F.; Viñas, C.; Kivekäs, R.; Sillanpää, R. Chem.-Eur. J. 2003, 9, 4311
11. Connelly, N. G.; Geiger, W. E. Chem. Rev. 1996, 96, 877
12. Sivaev, I. B.; Bregadze, V. I. Collect. Czech. Chem. Commun. 1999, 64, 783
13. Chamberlin, R. M.; Scott, B. L.; Melo, M. M.; Abney, K. D. Inorg. Chem. 1997, 36, 809
14. Juárez-Pérez, E. J.; Viñas, C.; González- Campo, A.; Teixidor, F.; Sillanpää, R.; Kivekäs, R.; Núñez, R. Chem.-Eur. J. 2008, 14, 4924
15. Viñas, C.; Pedrajas, J.; Bertran, J.; Teixidor, F.; Kivekäs, R.; Sillanpää, R. Inorg. Chem. 1997, 36, 2482
16. Viñas, C.; Gomez, S.; Bertran, J.; Teixidor, F.; Dozol, J. F.; Rouquette, H. Chem. Commun. 1998, 191
17. Viñas, C.; Gomez, S.; Bertran, J.; Teixidor, F.; Dozol, J. F.; Rouquette, H. Inorg. Chem. 1998, 37, 3640
18. Viñas, C.; Bertran, J.; Gomez, S; Teixidor, F.; Dozol, J. F.; Rouquette, H.; Kivekäs, R.; Sillanpää, R. J. Chem. Soc., Dalton Trans. 1998, 2849
19. Viñas, C.; Pedrajas, J.; Teixidor, F.; Kivekäs, R.; Sillanpää, R.; Welch, A. J. Inorg. Chem. 1997, 36, 2988
20. Francis, J. N.; Hawthorne, M. F. Inorg. Chem. 1971, 10, 594
21. Shelly, K.; Knobler, C. B.; Hawthorne, M. F. New J. Chem. 1988, 317
22. Mortimer, M. D.; Knobler, C. B.; Hawthorne, M. F. Inorg. Chem. 1996, 35, 5750
23. Rojo, I.; Teixidor, F.; Kivekäs, R.; Sillanpää, R.; Viñas, C. Organometallics 2003, 22, 4642
24. Beletskaya, I. P.; Bregadze, V. I.; Ivushkin, V. A.; Petrovskii, P. V.; Sivaev, I. B.; Sjöberg, S.; Zhigareva, G. G. J. Organomet. Chem. 2004, 689, 2920
25. Farràs, P; Olid-Britos, D.; Viñas, F.; Teixidor, F. Eur. J. Inorg. Chem. 2011, 2525
26. Plesek, J.; Hermánek, S.; Base, K.; Todd, L. J.; Wright, W. F. Collect. Czech. Chem. Commun. 1976, 41, 3509
27. González-Cardoso, P.; Stoica, A.-I.; Farràs, P.; Pepiol, A.; Viñas, C.; Teixidor, F. Chem.-Eur. J. 2010, 16, 6660
28. Teixidor, F.; Viñas, C.; Abad, M. M.; Kivekäs, R.; Sillanpää, R. J. Organomet. Chem. 1996, 509, 139
29. Viñas, C.; Núñez, R.; Teixidor, F.; Sillanpää, R.; Kivekäs, R. Organometallics 1999, 18, 4717
30. Verkade, J. G.; Mosbo, J. A. In Phosphorus-31 NMR Spectroscopy in Stereochemical Analysis; Quin, L. D.; Verkade, J. G., Eds.; VCH: New York, 1987; pp 425-463.
31. McFarlane, W.; Rycroft, D. S. J. Chem. Soc., Dalton Trans. 1973, 20, 2162
32. Allen, D. W.; Taylor, B. F. J. Chem. Soc., Dalton Trans. 1982, 1, 51
33. Jameson, C. J. In Phosphorus-31 NMR Spectroscopy in Stereochemical Analysis; Quin, L. D.; Verkade, J. G., Eds.; VCH: New York, 1987; pp 205-230.
34. Klapötke, T. M.; Broschag, M. Compilation of Reported 77Se NMR Chemical Shifts; Wiley: Chichester, 1996.
35. Burford, N.; Royan, B. W.; Spence, R. E. v. H.; Rogers, R. D. Dalton. Trans. 1990, 7, 2111
36. Pyykkö, P.; Atsumi, M. Chem.-Eur. J. 2009, 15, 12770
37. Stoeckli-Evans, H.; Osborne, A. G.; Whiteley, R. H. J. Organomet. Chem. 1980, 194, 91
38. Butler, I. R.; Cullenm, W. R.; Einstein, F.W. B.; Rettig, S. J.; Willis, A. J. Organometallics 1983, 2, 128
39. Patra, S. K.; Whittell, G. R.; Nagiah, S.; Ho, C.-L.; Wong, W.-Y.; Manners, I. Chem.-Eur. J. 2010, 16, 3240
40. Rojo, I.; Teixidor, F.; Kivekäs, R.; Sillanpää, R.; Viñas, C. J. Am. Chem. Soc. 2003, 125, 14720
41. Cook, J. B.; Nicholson, B. K.; Smith, D. W. J. Organomet. Chem. 2004, 689, 860 and references therein
42. Popescu, A. R.; Laromaine, A.; Teixidor, F.; Sillanpää, R.; Kivekäs, R.; Llambias, J. I.; Viñas, C. Chem.-Eur. J. 2011, 17, 4429
43. Allen, F. H. Acta Crystallogr. 2002, B58, 380
44. Bondi, A. J. Phys. Chem. 1964, 68, 441
45. Bader, R. F. W. Atoms in Molecules: A Quantum Theory; Clarendon Press: Oxford, New York, 1990.
46. Todd, L. J.; Siedle, A. R. Prog NMR Spectrosc. 1979, 13, 87
47. Grimes, R. N. Carboranes, 2 nd ed.; Elsevier: New York/Oxford, 2011.
48. Hermanek, S.; Plesek, J.; Stibr, B.; Grigor, V. J. Chem. Soc., Chem. Commun. 1977, 561
49. Stanko, V. I.; Babushkina, T. A.; Klimova, T. P.; Goltyapin, Y. U.; Klimova, A. I.; Vasilev, A. M.; Alymov, A. M.; Khrapov, V. V. Zh. Obshch. Khim. 1976, 46, 1071
50. Teixidor, F.; Viñas, C.; Rudolph, R. W. Inorg. Chem. 1986, 25, 3339
51. Bühl, M.; Hnyk, D.; Machácek, J. Chem.-Eur. J. 2005, 11, 4109
52. Pennanen, T. O.; Machácek, J.; Taubert, S.; Vaara, J.; Hynk, D. Phys. Chem. Chem. Phys. 2010, 12, 7018
53. Parish, R. V. NMR, NQR, EPR, and Mössbauer spectroscopy in Inorganic Chemistry; Ellis Horwood Series in Inorganic Chemistry. J. Burgess., Ed.; Ellis Horwood Limited: West Sussex, England, 1990.
54. Rojo, I.; Teixidor, F.; Viñas, C.; Kivekäs, R.; Sillanpää, R. Chem.-Eur. J. 2004, 10, 5376
55. Teixidor, F.; Núñez, R.; Viñas, C.; Sillanpää, R.; Kivekäs, R. Angew. Chem., Int. Ed. 2000, 39, 4290
56. Núñez, R.; Farràs, P.; Teixidor, F.; Viñas, C.; Sillanpää, R.; Kivekäs, R. Angew. Chem., Int. Ed. 2006, 45, 1270
57. Teixidor, F.; Núñez, R.; Viñas, C.; Kivekäs, R.; Sillanpää, R. Inorg. Chem. 2001, 40, 2587
58. Manners, I. Ring-Opening Polymerization of Metallocenophanes: A New Route to Transition Metal-Based Polymers; Advances in Organometallic Chemistry, Vol. 37; Academic Press: New York, 1995.
59. Pudelski, J. K.; Foucher, D. A.; Honeyman, C. H.; Lough, A. J.; Manners, I.; Barlow, S.; OHare, D. Organometallics 1995, 14, 2470
60. Oliva, J. M.; Viñas, C. J. Mol. Struct. 2000, 556, 33
61. Lever, A. B. P. Inorg. Chem. 1990, 29, 1271
62. Lever, A. B. P. Inorg. Chem. 1991, 30, 1980
63. Lever, A. B. P.; Dodsworth, E. S. Inorganic Electronic Structure and Spectroscopy; Solomon, E. I.; Lever, A. B. P., Eds.; Wiley: New York, 1999; Vol. 2, pp 227-287.
64. Matel, L.; Macásek, F.; Rajec, P.; Hermánek, S.; Plesek, J. Polyhedron 1982, 1, 511
65. Cerný, V.; Pavlík, I.; Kustková-Maxová, E. Collect. Czech. Chem. Commun. 1976, 41, 3232
66. Fally, S.; Carleer, M.; Vandaele, A. C. J. Quant. Spectrosc. Radiat. Transfer 2009, 110, 766
67. Juárez-Pérez, E. J.; Núñez, R.; Viñas, C.; Sillanpää, R.; Teixidor, F. Eur. J. Inorg. Chem. 2010, 2385