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Volumn 3, Issue 9, 2011, Pages 1419-1421

"Ligand-Consuming" formation of rhodium-hydride species from [Rh(OH)(cod)]2 without any additional hydride sources for catalytic olefin isomerizations and cyclobutene synthesis

Author keywords

Carbocycles; Homogeneous catalysis; Isomerization; Rhodium

Indexed keywords


EID: 80052872199     PISSN: 18673880     EISSN: 18673899     Source Type: Journal    
DOI: 10.1002/cctc.201100185     Document Type: Article
Times cited : (23)

References (37)
  • 1
    • 77955911241 scopus 로고    scopus 로고
    • Modern Rhodium-Catalyzed Organic Reactions
    • in (Ed.: P.A. Evans), Wiley-VCH, Weinheim, chap.
    • K. Yoshida, T. Hayashi in Modern Rhodium-Catalyzed Organic Reactions (Ed.: P.A. Evans), Wiley-VCH, Weinheim, 2005, chap.3.
    • (2005)
    • Yoshida, K.1    Hayashi, T.2
  • 15
    • 80052882224 scopus 로고    scopus 로고
    • Closed-shell allylic C-H activation of COD and a radical chain electron transfer oxidation of COD involving disproportionation of small amounts of rhodium(II) intermediates have been reported, see:
    • Closed-shell allylic C-H activation of COD and a radical chain electron transfer oxidation of COD involving disproportionation of small amounts of rhodium(II) intermediates have been reported, see:
  • 19
    • 0041841294 scopus 로고    scopus 로고
    • I species with a hydroxide ligand acts as a catalyst precursor; however, the formation of oxidized COD and the rhodium-hydride species from above mentioned pathways cannot be completely ruled out.
    • I species with a hydroxide ligand acts as a catalyst precursor; however, the formation of oxidized COD and the rhodium-hydride species from above mentioned pathways cannot be completely ruled out.
    • (2003) Organometallics , vol.22 , pp. 3022
    • Hetterscheid, D.G.H.1    deBruin, B.2    Smits, J.M.M.3    Gal, A.W.4
  • 21
    • 80052883233 scopus 로고    scopus 로고
    • The ketone/alcohol ratio was 1.8/1.0.
    • The ketone/alcohol ratio was 1.8/1.0.
  • 22
    • 80052915408 scopus 로고    scopus 로고
    • 1HNMR analysis revealed no incorporation of deuterium into the migration product (see the Supporting Information).
    • 1HNMR analysis revealed no incorporation of deuterium into the migration product (see the Supporting Information).
  • 25
    • 77957301388 scopus 로고    scopus 로고
    • 103Rh-H coupling of 43.2Hz was reported, see
    • 103Rh-H coupling of 43.2Hz was reported, see: S. Sarkar, S. Li, B. B. Wayland, J. Am. Chem. Soc. 2010, 132, 13569.
    • (2010) J. Am. Chem. Soc. , vol.132 , pp. 13569
    • Sarkar, S.1    Li, S.2    Wayland, B.B.3
  • 29
    • 80052899300 scopus 로고    scopus 로고
    • Cyclobutene synthesis from alkynes and alkenes has been reported, see:
    • Cyclobutene synthesis from alkynes and alkenes has been reported, see:


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.