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Closed-shell allylic C-H activation of COD and a radical chain electron transfer oxidation of COD involving disproportionation of small amounts of rhodium(II) intermediates have been reported, see:
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Closed-shell allylic C-H activation of COD and a radical chain electron transfer oxidation of COD involving disproportionation of small amounts of rhodium(II) intermediates have been reported, see:
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16
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19
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0041841294
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I species with a hydroxide ligand acts as a catalyst precursor; however, the formation of oxidized COD and the rhodium-hydride species from above mentioned pathways cannot be completely ruled out.
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I species with a hydroxide ligand acts as a catalyst precursor; however, the formation of oxidized COD and the rhodium-hydride species from above mentioned pathways cannot be completely ruled out.
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80052883233
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The ketone/alcohol ratio was 1.8/1.0.
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The ketone/alcohol ratio was 1.8/1.0.
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22
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80052915408
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1HNMR analysis revealed no incorporation of deuterium into the migration product (see the Supporting Information).
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1HNMR analysis revealed no incorporation of deuterium into the migration product (see the Supporting Information).
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25
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77957301388
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103Rh-H coupling of 43.2Hz was reported, see
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Cyclobutene synthesis from alkynes and alkenes has been reported, see:
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Cyclobutene synthesis from alkynes and alkenes has been reported, see:
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