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3 as the ligand. For reference, see: Smeets, A.; Van den Bergh, K.; De Winter, J.; Gerbaux, P.; Verbiest, T.; Koeckelberghs, G. Macromolecules 2009, 42, 7638-7641
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31P NMR spectroscopy experiments were performed at higher concentrations of nickel ([Ni] = 0.03 M) compared to the lab-scale polymerizations ([Ni] = 0.0015 M).
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31P NMR spectroscopy experiments were performed at higher concentrations of nickel ([Ni] = 0.03 M) compared to the lab-scale polymerizations ([Ni] = 0.0015 M).
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73
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Though not understood at this time, the downfield resonances are substantially broadened at these elevated temperatures (see Supporting Information).
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Though not understood at this time, the downfield resonances are substantially broadened at these elevated temperatures (see Supporting Information).
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74
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Reference 39f.
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For recent examples of phosphine ligand-based steric effects in transmetalation reactions, see
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For recent examples of phosphine ligand-based steric effects in transmetalation reactions, see: Ariafard, A.; Yates, B. F. J. Am. Chem. Soc. 2009, 131, 13891-13991
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The generalized equivalent cone angles for dppe (177°) and depe (175°) are similar. See ref 20.
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The generalized equivalent cone angles for dppe (177°) and depe (175°) are similar. See ref 20.
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For leading references on phosphine ligand-based electronic effects in reductive eliminations, see: Korenaga, T.; Abe, K.; Ko, A.; Maenishi, R.; Sakai, T. Organometallics 2010, 29, 4025-4035
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