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Volumn 120, Issue 12, 1998, Pages 2843-2853

Mechanistic investigation of catalytic Carbon-Carbon bond activation and formation by platinum and palladium phosphine complexes

Author keywords

[No Author keywords available]

Indexed keywords

HYDROCARBON; PALLADIUM COMPLEX; PLATINUM;

EID: 0032053641     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja973368d     Document Type: Article
Times cited : (188)

References (78)
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    • 3 could not be examined due to limitations in dynamic range in the NMR determinations.
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    • It is possible that phosphine dissociation from 2 is rate determining (i.e., recoordination of phosphine to form 2 is slow), and that trans-to-cis isomerization, phosphine recoordination, and reductive elimination are all rapid and irreversible. This would also lead to a lack of dependence of the rate of tetraphenylene formation on the phosphine concentration. We feel it is unlikely, however, that reaction of phosphine with the three-coordinate 14-electron intermediate would be slow.
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    • note
    • It has been noted that the integration program SAINT produces cell constant errors that are unreasonably small, since systematic error is not included. More reasonable errors might be estimated at 10× the listed value.
  • 78


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