Mechanistic aspects of the Kharasch addition reaction catalyzed by organonickel(II) complexes containing the monoanionic terdentate aryldiamine ligand system [C6H2(CH2NMe2) 2-2,6-R-4]-

Organometallics

Volumn 16, Issue 23, 1997, Pages 4985-4994

  Van De Kuil, Lucia A ^a   Grove, David M ^a   Gossage, Robert A ^a   Zwikker, Jan W ^a   Jenneskens, Leonardus W ^a   Drenth, Wiendelt ^a   Van Koten, Gerard ^a  

^a UTRECHT UNIVERSITY   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001613819     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970061e     Document Type: Article

References (100)

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94. 8g prefer to use the term Michaelis-Menten to describe the rate dependence on alkene concentration.
95. Preliminary molecular modeling studies (MM2 and ZINDO as implemented in CAChe Scientific software; Oxford Molecular Group) show that such an encounter species (A, Figure 6) is a viable intermediate, see: Grove, D. M. Unpublished results.
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97. For examples of isolated transition metal complexes that contain halogenated alkanes bound through halide-metal interactions, see: (a) Kulawiec, R. J.; Crabtree, R. H. Coord. Chem. Rev. 1990, 99, 89 and references given therein. (b) Peng, T.-S.; Winter, C. H.; Gladysz, J. A. Inorg. Chem. 1994, 33, 2534. (c) Pathak, D. D.; Adams, H.; White, C. J. Chem. Soc., Chem. Commun. 1994, 733.
98. For examples of isolated transition metal complexes that contain halogenated alkanes bound through halide-metal interactions, see: (a) Kulawiec, R. J.; Crabtree, R. H. Coord. Chem. Rev. 1990, 99, 89 and references given therein. (b) Peng, T.-S.; Winter, C. H.; Gladysz, J. A. Inorg. Chem. 1994, 33, 2534. (c) Pathak, D. D.; Adams, H.; White, C. J. Chem. Soc., Chem. Commun. 1994, 733.
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