Proton-coupled electron transfer reactions at a heme-propionate in an iron-protoporphyrin-IX model compound

Journal of the American Chemical Society

Volumn 133, Issue 22, 2011, Pages 8544-8551

  Warren, Jeffrey J ^a   Mayer, James M ^b  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^b UNIVERSITY OF WASHINGTON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVE SITE; BENZOQUINONES; BOND-DISSOCIATION FREE ENERGIES; ELECTRON TRANSFER; HEME MODELS; HEME PROPIONATES; HEME PROTEINS; IRON CENTERS; KEY COMPONENT; MODEL COMPOUND; N-METHYLIMIDAZOLE; PROPIONIC ACIDS; PROTON-COUPLED ELECTRON TRANSFER; PROTON-COUPLED ELECTRON TRANSFER REACTIONS; PROTOPORPHYRINS;

ACETONITRILE; ELECTRON TRANSITIONS; EQUILIBRIUM CONSTANTS; KETONES; ORGANIC SOLVENTS; PHENOLS; PORPHYRINS; PROTEINS; PROTONS; VOLATILE FATTY ACIDS;

CARBON DIOXIDE;

1 METHYLIMIDAZOLE; 5,6 ISOPROPYLIDINE ASCORBIC ACID; ACETONITRILE; ASCORBIC ACID DERIVATIVE; BENZOQUINONE; CARBON DIOXIDE; HEME; HEMOPROTEIN; HYDROQUINONE; HYDROXYLAMINE; IRON; PROPIONIC ACID; PROTON; PROTOPORPHYRIN; SOLVENT; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL MODEL; CHEMICAL REACTION; DISSOCIATION CONSTANT; EFFECTIVE BOND DISSOCIATION FREE ENERGY; ELECTRON TRANSPORT; EQUILIBRIUM CONSTANT; PROTON COUPLED ELECTRON TRANSFER; PROTON TRANSPORT; REACTION ANALYSIS;

CRYSTALLOGRAPHY, X-RAY; ELECTRON TRANSPORT; HEME; HYDROGEN BONDING; MODELS, BIOLOGICAL; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; PROPIONATES; PROTONS; PROTOPORPHYRINS; THERMODYNAMICS;

EID: 79957992397     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja201663p     Document Type: Article

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