Concerted proton-electron transfer in a ruthenium terpyridyl-benzoate system with a large separation between the redox and basic sites

Journal of the American Chemical Society

Volumn 131, Issue 29, 2009, Pages 9874-9875

  Manner, Virginia W ^a   Mayer, James M ^a  

^a UNIVERSITY OF WASHINGTON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANALOGOUS REACTIONS; ANALOGOUS SYSTEMS; BASIC SITES; BOND-DISSOCIATION FREE ENERGIES; ELECTRON TRANSFER; HYDROGEN ATOMS; HYDROGEN TRANSFER; O-H BOND; ONE POT; ONE-ELECTRON OXIDATION; ORDERS OF MAGNITUDE; P-CYMENE; P-METHOXYPHENOL; PROTON-COUPLED ELECTRON TRANSFER; RADICAL CATIONS; RU COMPLEXES; RUTHENIUM COMPLEXES; SECOND-ORDER RATE CONSTANTS; TEMPO RADICAL; TERPYRIDINE;

ATOMS; CARBOXYLATION; ELECTRON TRANSITIONS; FREE RADICAL REACTIONS; HYDROGEN; METAL RECOVERY; PROTONS; RATE CONSTANTS; RUTHENIUM; RUTHENIUM COMPOUNDS; SEPARATION;

PROTON TRANSFER;

4' (4 CARBOXYPHENYL)TERPYRIDINE; CARBOXYLIC ACID; HYDROGEN; LIGAND; METAL; RUTHENIUM COMPLEX; RUTHENIUM DERIVATIVE; RUTHENIUM TERPYRIDYL BENZOATE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; DISSOCIATION; ELECTRON TRANSPORT; ENERGY; KINETICS; OXIDATION; OXIDATION REDUCTION REACTION; PROTON COUPLED ELECTRON TRANSFER; PROTON TRANSPORT; SYNTHESIS;

BENZOATES; ELECTRONS; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; PROTONS; RUTHENIUM; THERMODYNAMICS;

EID: 67651224886     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja902942g     Document Type: Article

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