Stereochemically controlled asymmetric 1,2-reduction of enones mediated by a chiral sulfoxide moiety and a lanthanum(III) ion

Journal of Organic Chemistry

Volumn 76, Issue 10, 2011, Pages 3922-3936

  Motohashi, Shigeyasu ^a   Nagase, Kouichi ^a   Nakakita, Toshinori ^a   Matsuo, Takeshi ^a   Yoshida, Yoshikazu ^a   Kawakubo, Takashi ^b   Miura, Motofumi ^a   Toriyama, Masaharu ^a   Barybin, Mikhail V ^c  

^a NIHON UNIVERSITY   (Japan)

^b JIKEI UNIVERSITY HOSPITAL   (Japan)

^c UNIVERSITY OF KANSAS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYLIC ALCOHOL; CHELATING AGENT; HIGH YIELD; REDUCTANTS;

CHELATION;

ALCOHOL DERIVATIVE; BETA SULFINYL ENONE DERIVATIVE; LANTHANUM; LEWIS ACID; LITHIUM DERIVATIVE; POTASSIUM BOROHYDRIDE; REDUCING AGENT; SODIUM BOROHYDRIDE; SULFINIC ACID DERIVATIVE; SULFOXIDE; UNCLASSIFIED DRUG;

ARTICLE; ASYMMETRIC REDUCTION; CHEMICAL STRUCTURE; CHIRALITY; ENANTIOMER; REDUCTION KINETICS; STEREOCHEMISTRY; SULFATION AND DESULFURIZATION; SYNTHESIS;

ALKENES; KETONES; LANTHANUM; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; PROPANOLS; STEREOISOMERISM; SUBSTRATE SPECIFICITY; SULFOXIDES;

EID: 79956092103     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo200373a     Document Type: Article

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