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Volumn 37, Issue 17, 1998, Pages 2392-2395

Catalytic asymmetric allenylation: Regulation of the equilibrium between propargyl- and allenylstannanes during the catalytic process

Author keywords

Aldehydes; Asymmetric catalysis; Lewis acids; Synthetic methods; Titanium

Indexed keywords


EID: 0032544714     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980918)37:17<2392::AID-ANIE2392>3.0.CO;2-D     Document Type: Article
Times cited : (96)

References (40)
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    • Allenyltin compounds are reported (H. Tanaka, A. K. M. Abdul Hai, H. Ogawa, S. Torri, Synlett 1993, 835-836) to be obtained under conditions similar to those we used to obtain propargyltin compounds from 3-substituted propargyl bromides.
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    • note
    • 2CuLi at -78°C in THF. Although the literature procedure can be used to prepare regiochemically pure triphenyltin analogues of 4 and 6, it turned out to be unpromising for this purpose mainly because of the lack of reactivity.
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    • and references therein
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.