Remote stereocontrol mediated by a sulfinyl group: Synthesis of allylic alcohols via chemoselective and diastereoselective reduction of γ-methylene δ-ketosulfoxides

Journal of Organic Chemistry

Volumn 74, Issue 3, 2009, Pages 1200-1204

  Ruano, José L García ^a   Fernández Ibáñez, M Ángeles ^a   Fernández Salas, José A ^a   Maestro, M Carmen ^a   Márquez López, Pablo ^a   Rodríguez Fernández, M Mercedes ^a  

^a UNIVERSIDAD AUTÓNOMA DE MADRID   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYLIC ALCOHOLS; CHELATING AGENTS; CHEMO SELECTIVITIES; CHEMO-SELECTIVE; DIASTEREO SELECTIVITIES; DIASTEREOSELECTIVE REDUCTIONS; ENANTIOMERIC PURITIES; GEL TREATMENTS; REDUCTION PRODUCTS; REMOTE CONTROLLERS; REMOTE STEREOCONTROL; SULFINYL GROUPS; ULTRASOUND IRRADIATIONS; UNSATURATED KETONES;

CHELATION; GELATION; METHANOL; SILICA; SILICA GEL; YTTERBIUM;

KETONES;

1 [2 (4 TOLYLSULFINYL)PHENYL]ALKAN 2 ONE DERIVATIVE; 2 [2 (4 TOLYLSULFINYL)PHENYL]BUT 3 EN 2 ONE DERIVATIVE; ALCOHOL DERIVATIVE; ALLYLIC ALCOHOL DERIVATIVE; CHELATING AGENT; DELTA KETOSULFOXIDE DERIVATIVE; GAMMA METHYLENE SULFOXIDE DERIVATIVE; SODIUM BOROHYDRIDE; SULFINIC ACID DERIVATIVE; SULFOXIDE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; ENANTIOMER; MANNICH REACTION; METHYLATION; QUANTUM YIELD; STEREOCHEMISTRY; SYNTHESIS;

EID: 64549110313     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo802378s     Document Type: Article

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