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Volumn 2, Issue 11, 2010, Pages 1411-1415

Synthesis of secondary amines by iron-catalyzed reductive amination

Author keywords

Aldehydes; Amines; Homogeneous catalysis; Hydrosilylation; Iron

Indexed keywords


EID: 79954428402     PISSN: 18673880     EISSN: 18673899     Source Type: Journal    
DOI: 10.1002/cctc.201000180     Document Type: Article
Times cited : (65)

References (57)
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    • (2004) nd
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    • Comprehensive Asymmetric Catalysis (Eds.: E.N. Jacobsen, A. Pfaltz, H. Yamamoto), Springer, Berlin, 1999;
    • Comprehensive Asymmetric Catalysis (Eds.: E.N. Jacobsen, A. Pfaltz, H. Yamamoto), Springer, Berlin, 1999;
  • 17
    • 79957770902 scopus 로고    scopus 로고
    • Example for reductive aminations, see also references therein:
    • Example for reductive aminations, see also references therein:
  • 34
  • 39
    • 79957706473 scopus 로고    scopus 로고
    • Yields achieved on addition of various ligands: Triethylamine<1%; N,N,N',N'-tetramethylethylendiamine<1%; urotropine<1%; 2,2,6,6-tetramethylpiperidine<1%; N,N,N',N'-tetramethylguanidine<1%; N,N'-diphenyl urea16%; pyridine19%; N,N-dimethylpyridine<1%; 4-methylpyridine28%; 4-hydroxypyridine18%; 2,6-dimethylpyridine5%; 2,2'-bipyridine12%; indazole41%; pyridazine46%; pyrazine17%; phenanzine36%; acridine45%; imidazole7%; phenol20%; 2,4,6-tri-tert-butylphenol5%; 1,1,1,3,3,3-hexafluoropropanol46%. Reactions were carried out for 1h at 60°C, as described in Table1, entry1. In the case of monodentate systems, a metal/ligand ratio of 1:2 was used, whereas for polydentate systems the ratio was 1:1.
    • Yields achieved on addition of various ligands: Triethylamine<1%; N, N, N', N'-tetramethylethylendiamine<1%; urotropine<1%; 2, 2, 6, 6-tetramethylpiperidine<1%; N, N, N', N'-tetramethylguanidine<1%; N, N'-diphenyl urea16%; pyridine19%; N, N-dimethylpyridine<1%; 4-methylpyridine28%; 4-hydroxypyridine18%; 2, 6-dimethylpyridine5%; 2, 2'-bipyridine12%; indazole41%; pyridazine46%; pyrazine17%; phenanzine36%; acridine45%; imidazole7%; phenol20%; 2, 4, 6-tri-tert-butylphenol5%; 1, 1, 1, 3, 3, 3-hexafluoropropanol46%. Reactions were carried out for 1h at 60°C, as described in Table1, entry1. In the case of monodentate systems, a metal/ligand ratio of 1:2 was used, whereas for polydentate systems the ratio was 1:1.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.