Inserting polyoxomolybdate cluster into poly(ε-caprolactone) to create a class of new heteropolymer: Synthesis and supramolecular structures

Polymer

Volumn 52, Issue 8, 2011, Pages 1772-1780

  Xia, Nan ^a   Yu, Wei ^a   Wang, Yongliang ^a   Han, Yaokun ^a   Zheng, Ping ^a   Wang, Wei ^a   Sakaguchi, Go ^b   Matsuda, Kuniaki ^b   Saijo, Kenji ^b   Takenaka, Mikihito ^b   Hasegawa, Hirokazu ^b  

^a NANKAI UNIVERSITY   (China)

^b KYOTO UNIVERSITY   (Japan)

Author keywords

Hybrid polymers; Poly( caprolactone); Polyoxometalates

Indexed keywords

ELECTRIC IMPEDANCE TOMOGRAPHY; MONOMERS; SELF ASSEMBLY;

3D ELECTRON TOMOGRAPHY; CAPROLACTONE; CRYSTALLIZATION PROCESS; HYBRID POLYMERS; POLY (EPSILONCAPROLACTONE); POLYOXOMETALATES; SPHERICAL AGGREGATES; SUPRAMOLECULAR STRUCTURE;

RING OPENING POLYMERIZATION;

EID: 79953191753     PISSN: 00323861     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymer.2011.02.018     Document Type: Article

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72. 2- of pentaerythritol, which were directly connected with POM, even shifted to 60 ppm. We considered the electronegativity of POM affected the reactivity of the two hydroxyls intensely and therefore the control of the ROP procedure and the molecular weight may not be desirable. The long polymerization time and high reaction temperature also led to chain-transfer side reaction. Nevertheless, the analysis in the crystallization behavior and the self-assembly revealed the dominant composition and effect of the heteropolymers.