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Crystal data and structure refinements for compound 2: C 74H160MnMo6N7O29, M, 2242.67 gmol-1; an orange, crystal (0.16 × 0.16×0.16 mm3) was measured on a Bruker Apex II CCD diffractometer using Mokα radiation (λ =0.71073 Å) at 100(2) K. Orthorhombic, space group Pna21, a, 18.5540(8) Å, b, 20.2839(8) Å, c, 26.0613(11) Å, V, 9808.1 (7) Å3, Z, 4, 18510 unique, 17243 observed (1 > 2σ(I, R1= 0.0281. wR2 (all data, 0.0744. Compound 3: C94H212MnMo6N 7O7O35 M, 2631 gmol-1; an orange, crystal (0.10 × 0.03 × 0.03 mm3, Monoclinic. space group C2/c. a, 49.590(10) Å, b, 28.512(6) Å, c, 25.585(5) Å, β, 99.78(3, V, 35 649(12) Å3, Z, 12, 32869 unique, 24464 observed 1 >
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