Acceleration of the methanolysis of phosphate diesters promoted by La(OTf)3 - The analysis of non-integer s spH/rate profiles resulting from changes in metal ion speciation

Canadian Journal of Chemistry

Volumn 83, Issue 9, 2005, Pages 1268-1276

  Gibson, Graham T T ^a   Neverov, Alexei A ^a   Teng, Allen Chun Tien ^a   Brown, R S ^a  

^a QUEEN S UNIVERSITY   (Canada)

Author keywords

DNA model methanolysis; Kinetics; Lanthanides; Metal ion catalysis of methanolysis; Methanolysis; Phosphate diester; Speciation

Indexed keywords

CATALYSIS; DNA; IONS; KINETIC THEORY; LANTHANUM COMPOUNDS; MATHEMATICAL MODELS; PH EFFECTS; RARE EARTH ELEMENTS; REACTION KINETICS;

DNA MODEL METHANOLYSIS; METAL ION CATALYSIS OF METHANOLYSIS; METHANOLYSIS; PHOSPHATE DIESTER; SPECIATION;

ESTERS;

BIS(4 NITROPHENYL) PHOSPHATE; DIPHENYLPHOSPHATE; DNA; LANTHANIDE; LANTHANUM; METAL ION; METHYL 4 NITROPHENYLPHOSPHATE; ORGANOPHOSPHATE; UNCLASSIFIED DRUG;

AQUEOUS SOLUTION; ARTICLE; CALCULATION; CALIBRATION; CATALYSIS; CHEMICAL STRUCTURE; DECOMPOSITION; ELECTROSPRAY MASS SPECTROMETRY; KINETICS; METHANOLYSIS; PH; PKA; POTENTIOMETRY; REACTION ANALYSIS; REACTION TIME; SPECTROMETER; STRUCTURE ANALYSIS; TITRIMETRY;

EID: 33644601622     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/v05-065     Document Type: Article

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