-
1
-
-
0001009612
-
-
Rappoport, Z., Apeloig, Y., Eds.; Wiley: New York
-
For recent reviews on silyl cations: (a) Maerker, C.; Schleyer, P. v. R. In The Chemistry of Organosilicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: New York, 1998; Vol. 2, p 513.
-
(1998)
The Chemistry of Organosilicon Compounds
, vol.2
, pp. 513
-
-
Maerker, C.1
Schleyer, P.V.R.2
-
2
-
-
0000879050
-
-
Rappoport, Z., Apeloig, Y., Eds.; Wiley: New York
-
(b) Lickiss, P. D. In The Chemistry of Organosilicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: New York, 1998; Vol. 2, p 557.
-
(1998)
The Chemistry of Organosilicon Compounds
, vol.2
, pp. 557
-
-
Lickiss, P.D.1
-
3
-
-
0030948011
-
-
(a) Lambert, J. B.; Zhao, Y. Angew. Chem., Int. Ed. 1997, 36, 400.
-
(1997)
Angew. Chem., Int. Ed.
, vol.36
, pp. 400
-
-
Lambert, J.B.1
Zhao, Y.2
-
4
-
-
0001219908
-
-
(b) Müller, T.; Zhao, Y.; Lambert, J. B. Organometallics 1998, 17, 278.
-
(1998)
Organometallics
, vol.17
, pp. 278
-
-
Müller, T.1
Zhao, Y.2
Lambert, J.B.3
-
5
-
-
0033516298
-
-
(c) Lambert, J. B.; Zhao, Y.; Wu, H.; Tse, W. C.; Kuhlmann, B. J. Am. Chem. Soc. 1999, 121, 5001.
-
(1999)
J. Am. Chem. Soc.
, vol.121
, pp. 5001
-
-
Lambert, J.B.1
Zhao, Y.2
Wu, H.3
Tse, W.C.4
Kuhlmann, B.5
-
6
-
-
0000116329
-
-
(d) Kraka, E.; Sosa, C. P.; Gräfenstein, J.; Cremer, D. Chem. Phys. Lett. 1997, 9, 279.
-
(1997)
Chem. Phys. Lett.
, vol.9
, pp. 279
-
-
Kraka, E.1
Sosa, C.P.2
Gräfenstein, J.3
Cremer, D.4
-
7
-
-
0034721460
-
-
(a) Nishinaga, T.; Izukawa, Y.; Komatsu, K. J. Am. Chem. Soc. 2000, 122, 9312.
-
(2000)
J. Am. Chem. Soc.
, vol.122
, pp. 9312
-
-
Nishinaga, T.1
Izukawa, Y.2
Komatsu, K.3
-
8
-
-
0035938265
-
-
(b) Nishinaga, T.; Izukawa, Y.; Komatsu, K. Tetrahedron 2001, 57, 3645.
-
(2001)
Tetrahedron
, vol.57
, pp. 3645
-
-
Nishinaga, T.1
Izukawa, Y.2
Komatsu, K.3
-
9
-
-
0034669696
-
-
Sekiguchi, A.; Matsuno, T.; Ichinole, M. J. Am. Chem. Soc. 2000, 122, 11250.
-
(2000)
J. Am. Chem. Soc.
, vol.122
, pp. 11250
-
-
Sekiguchi, A.1
Matsuno, T.2
Ichinole, M.3
-
10
-
-
33748503634
-
-
Donors with lone pairs: (a) Chuit, C.; Corriu, R. J. P.; Medhi, A.; Reyé, C. Angew. Chem., Int. Ed. 1993, 32, 1311.
-
(1993)
Angew. Chem., Int. Ed.
, vol.32
, pp. 1311
-
-
Chuit, C.1
Corriu, R.J.P.2
Medhi, A.3
Reyé, C.4
-
11
-
-
0001124527
-
-
(b) Belzner, J.; Schär, D.; Kneisel, B. O.; Herbst-Irmer, R. Organometallics 1995, 14, 1840.
-
(1995)
Organometallics
, vol.14
, pp. 1840
-
-
Belzner, J.1
Schär, D.2
Kneisel, B.O.3
Herbst-Irmer, R.4
-
12
-
-
0033549577
-
-
(c) Berlekamp, U.-H.; Jutzi, P.; Mix, A.; Neumann, B.; Stammler, H.-G.; Schoeller; W. W. Angew. Chem., Int. Ed. 1999, 38, 2048.
-
(1999)
Angew. Chem., Int. Ed.
, vol.38
, pp. 2048
-
-
Berlekamp, U.-H.1
Jutzi, P.2
Mix, A.3
Neumann, B.4
Stammler, H.-G.5
Schoeller, W.W.6
-
13
-
-
0030951821
-
-
Donors with π bonds: (a) Steinberger, H.-U.; Müller, T.; Auner, N.; Maerker, C.; Schleyer, P. v. R. Angew. Chem., Int. Ed. 1997, 36, 626,
-
(1997)
Angew. Chem., Int. Ed.
, vol.36
, pp. 626
-
-
Steinberger, H.-U.1
Müller, T.2
Auner, N.3
Maerker, C.4
Schleyer, P.V.R.5
-
14
-
-
0040784802
-
-
(b) Müller, T.; Meyer, R.; Lennartz, D.; Siehl, H.-U. Angew. Chem., Int. Ed. 2000, 39, 3074.
-
(2000)
Angew. Chem., Int. Ed.
, vol.39
, pp. 3074
-
-
Müller, T.1
Meyer, R.2
Lennartz, D.3
Siehl, H.-U.4
-
15
-
-
0011500718
-
-
(c) Werner, K.; Meyer, R.; Müller, T. Book of Abstracts, 34th Organosilicon Symposium; White Plains, NY, 2001; P2-9.
-
Book of Abstracts, 34th Organosilicon Symposium; White Plains, NY, 2001
, pp. 2-9
-
-
Werner, K.1
Meyer, R.2
Müller, T.3
-
16
-
-
4243314457
-
-
(d) Lickiss, P. D.; Masangane, P. C.; Sohal, W. Book of Abstracts, 34th Organosilicon Symposium; White Plains, NY, 2001, C-16.
-
Book of Abstracts, 34th Organosilicon Symposium; White Plains, NY, 2001
-
-
Lickiss, P.D.1
Masangane, P.C.2
Sohal, W.3
-
18
-
-
0000936078
-
-
Auner, N., Weis, J., Eds.; VCH: Weinheim, Germany
-
Maerker, C.; Kapp, J.; Schleyer, P. v. R. In Organosilicon Chemistry II: From Molecules to Materials; Auner, N., Weis, J., Eds.; VCH: Weinheim, Germany, 1995; p 329.
-
(1995)
Organosilicon Chemistry II: From Molecules to Materials
, pp. 329
-
-
Maerker, C.1
Kapp, J.2
Schleyer, P.V.R.3
-
20
-
-
84985631338
-
-
(a) Hensen, K.; Zengerley, T.; Pickel, P.; Klebe, G. Angew. Chem., Int. Ed. 1983, 22, 725.
-
(1983)
Angew. Chem., Int. Ed.
, vol.22
, pp. 725
-
-
Hensen, K.1
Zengerley, T.2
Pickel, P.3
Klebe, G.4
-
22
-
-
84983979231
-
-
(c) Hensen, K.; Zengerley, T.; Müller, T.; Pickel, P. Z. Anorg. Allg. Chem. 1988, 558, 21.
-
(1988)
Z. Anorg. Allg. Chem.
, vol.558
, pp. 21
-
-
Hensen, K.1
Zengerley, T.2
Müller, T.3
Pickel, P.4
-
23
-
-
0034620781
-
-
(d) MacLachlan, M. J.; Bourke, S. C.; Lough, A. J.; Manners, I. J. Am. Chem. Soc. 2000, 122, 2126.
-
(2000)
J. Am. Chem. Soc.
, vol.122
, pp. 2126
-
-
MacLachlan, M.J.1
Bourke, S.C.2
Lough, A.J.3
Manners, I.4
-
24
-
-
0003686469
-
-
For examples of silylnitrilium ions see: (a) Olah, G. A.; Narang, S. C.; Gupta, B. G. B.; Malhotra, R. J. Org. Chem. 1979, 44, 1247.
-
(1979)
J. Org. Chem.
, vol.44
, pp. 1247
-
-
Olah, G.A.1
Narang, S.C.2
Gupta, B.G.B.3
Malhotra, R.4
-
27
-
-
37049085252
-
-
(d) Xie, Z.; Liston, D. J.; Jelinek, T.; Mitro, V.; Bau, R.; Reed, C. A. J. Chem. Soc., Chem. Commun. 1993, 384.
-
(1993)
J. Chem. Soc., Chem. Commun.
, pp. 384
-
-
Xie, Z.1
Liston, D.J.2
Jelinek, T.3
Mitro, V.4
Bau, R.5
Reed, C.A.6
-
28
-
-
0001744460
-
-
(e) Lambert, J. B.; Zhang, S.; Ciro, S. M. Organometallics 1994, 13, 2430.
-
(1994)
Organometallics
, vol.13
, pp. 2430
-
-
Lambert, J.B.1
Zhang, S.2
Ciro, S.M.3
-
29
-
-
0032486809
-
-
(f) Johannsen, M.; Jorgensen, K. A.; Helmchen, G. J. Am. Chem. Soc. 1998, 120, 7637.
-
(1998)
J. Am. Chem. Soc.
, vol.120
, pp. 7637
-
-
Johannsen, M.1
Jorgensen, K.A.2
Helmchen, G.3
-
30
-
-
0000391949
-
-
For examples of silyloxonium ions see: (a) Kira, M.; Hino, T.; Sakurai, H. J. Am. Chem. Soc. 1992, 114, 6697.
-
(1992)
J. Am. Chem. Soc.
, vol.114
, pp. 6697
-
-
Kira, M.1
Hino, T.2
Sakurai, H.3
-
31
-
-
0001164437
-
-
(b) Olah, G. A.; Li, X.-Y.; Wang, Q.; Rasul, G.; Prakash, G. K. S. J. Am. Chem. Soc. 1995, 117, 8962.
-
(1995)
J. Am. Chem. Soc.
, vol.117
, pp. 8962
-
-
Olah, G.A.1
Li, X.-Y.2
Wang, Q.3
Rasul, G.4
Prakash, G.K.S.5
-
32
-
-
37049079937
-
-
(c) Xie, Z.; Bau, R.; Reed, C. A. J. Chem. Soc., Chem. Commun. 1994, 2519.
-
(1994)
J. Chem. Soc., Chem. Commun.
, pp. 2519
-
-
Xie, Z.1
Bau, R.2
Reed, C.A.3
-
33
-
-
0035907818
-
-
(d) Driess, M.; Barmeyer, R.; Monsé, C.; Merz, K. Angew. Chem., Int. Ed. 2001, 40, 2308.
-
(2001)
Angew. Chem., Int. Ed.
, vol.40
, pp. 2308
-
-
Driess, M.1
Barmeyer, R.2
Monsé, C.3
Merz, K.4
-
34
-
-
0000844613
-
-
(a) Lambert, J. B.; Zhang, S.; Stern, C.; Huffman, J. C. Science 1993, 260, 1917.
-
(1993)
Science
, vol.260
, pp. 1917
-
-
Lambert, J.B.1
Zhang, S.2
Stern, C.3
Huffman, J.C.4
-
38
-
-
33748217457
-
-
(e) Schleyer, P. v. R.; Buzek, P.; Müller, T.; Apeloig, Y.; Siehl, H.-U. Angew. Chem., Int. Ed. 1993, 32, 1471.
-
(1993)
Angew. Chem., Int. Ed.
, vol.32
, pp. 1471
-
-
Schleyer, P.V.R.1
Buzek, P.2
Müller, T.3
Apeloig, Y.4
Siehl, H.-U.5
-
40
-
-
84962406897
-
-
(g) Arshadi, M.; Johnels, D.; Edlund, U.; Ottoson, C.-H. Cremer, D. J. Am. Chem. Soc. 1996, 118, 5120.
-
(1996)
J. Am. Chem. Soc.
, vol.118
, pp. 5120
-
-
Arshadi, M.1
Johnels, D.2
Edlund, U.3
Ottoson, C.-H.4
Cremer, D.5
-
41
-
-
0000995266
-
-
(h) Olah, G. A.; Rasul, G.; Buchholz, H. A. Li, X.-Y.; Prakash, G. K. S. Bull. Soc. Chim. Fr. 1995, 132, 569.
-
(1995)
Bull. Soc. Chim. Fr.
, vol.132
, pp. 569
-
-
Olah, G.A.1
Rasul, G.2
Buchholz, H.A.3
Li, X.-Y.4
Prakash, G.K.S.5
-
42
-
-
0028212962
-
-
(i) Olah, G. A.; Rasul, G.; Buchholz, H. A.; Li, X.-Y.; Sanford, G.; Prakash, G. K. S. Science 1994, 263, 983.
-
(1994)
Science
, vol.263
, pp. 983
-
-
Olah, G.A.1
Rasul, G.2
Buchholz, H.A.3
Li, X.-Y.4
Sanford, G.5
Prakash, G.K.S.6
-
43
-
-
0028212962
-
-
(j) Pauling, L. Science 1994, 263, 983.
-
(1994)
Science
, vol.263
, pp. 983
-
-
Pauling, L.1
-
45
-
-
33748242700
-
-
(a) Jutzi, P.; Bunte, A. E. Angew. Chem., Int. Ed. 1992, 31, 1605.
-
(1992)
Angew. Chem., Int. Ed.
, vol.31
, pp. 1605
-
-
Jutzi, P.1
Bunte, A.E.2
-
46
-
-
0011505920
-
-
Ph.D. Thesis, Universität Bielefeld
-
(b) Kühler, T. Ph.D. Thesis, Universität Bielefeld, 2000.
-
(2000)
-
-
Kühler, T.1
-
47
-
-
0011512650
-
-
Auner, N., Weis, J., Eds.; VCH: Weinheim, Germany
-
(c) Jutzi, P. In Organosilicon Chemistry I: From Molecules to Materials; Auner, N., Weis, J., Eds.; VCH: Weinheim, Germany, 1994; p 87.
-
(1994)
Organosilicon Chemistry I: From Molecules to Materials
, pp. 87
-
-
Jutzi, P.1
-
48
-
-
0000776345
-
-
Rappoport, Z., Apeloig, Y., Eds.; Wiley: New York
-
(d) Jutzi, P. In The Chemistry of Organosilicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: New York, 1998; Vol. 2, p 2129.
-
(1998)
The Chemistry of Organosilicon Compounds
, vol.2
, pp. 2129
-
-
Jutzi, P.1
-
49
-
-
0011512651
-
-
(a) All calculations were performed with Gaussian 94, Revisions C2-E2, and Gaussians 98, Revisions A3-A8; Gaussian; Inc.: Pittsburth, PA
-
(a) All calculations were performed with Gaussian 94, Revisions C2-E2, and Gaussians 98, Revisions A3-A8; Gaussian; Inc.: Pittsburth, PA, 1995 and 1999.
-
(1995)
-
-
-
55
-
-
0345491105
-
-
(c) Lee, C.; Yang, W.; Parr, R. G. Phys. Rev. B 1988, 37, 785.
-
(1988)
Phys. Rev. B
, vol.37
, pp. 785
-
-
Lee, C.1
Yang, W.2
Parr, R.G.3
-
57
-
-
25044455217
-
-
(b) Head-Gordon, M.; Pople, J. A.; Frish, M. Chem. Phys. Lett. 1988, 153, 503.
-
(1988)
Chem. Phys. Lett.
, vol.153
, pp. 503
-
-
Head-Gordon, M.1
Pople, J.A.2
Frish, M.3
-
58
-
-
0011682081
-
-
Pople, J. A.; Head-Gordon, M.; Raghavachari, K. J. Chem. Phys. 1987, 87, 5968.
-
(1987)
Chem. Phys.
, vol.87
, pp. 5968
-
-
Pople, J.A.1
Head-Gordon, M.2
Raghavachari, K.J.3
-
59
-
-
0011481569
-
-
NBO 4.0; Theoretical Chemistry Institute, University of Wisconsin, Madison, WI
-
(a) Glendening, E. D.; Badenhoop, J. K.; Reed, A. E.; Carpenter, J. E.; Weinhold, F. NBO 4.0; Theoretical Chemistry Institute, University of Wisconsin, Madison, WI, 1996.
-
(1996)
-
-
Glendening, E.D.1
Badenhoop, J.K.2
Reed, A.E.3
Carpenter, J.E.4
Weinhold, F.5
-
60
-
-
0011083499
-
-
(b) Reed, A. E.; Curtiss, L. A.; Weinhold, F. Chem. Rev. 1988, 88, 899.
-
(1988)
Chem. Rev.
, vol.88
, pp. 899
-
-
Reed, A.E.1
Curtiss, L.A.2
Weinhold, F.3
-
62
-
-
0001158953
-
-
(b) Wolinski, K.; Hilton, J. F.; Pulay, P. J. Am. Chem. Soc. 1982, 104, 5667.
-
(1982)
J. Am. Chem. Soc.
, vol.104
, pp. 5667
-
-
Wolinski, K.1
Hilton, J.F.2
Pulay, P.3
-
63
-
-
1242268874
-
-
(c) Cheeseman, J. R.; Trucks, G. W.; Keith, T. A.; Frisch, M. J. J. Chem. Phys. 1996, 104, 5497.
-
(1996)
J. Chem. Phys.
, vol.104
, pp. 5497
-
-
Cheeseman, J.R.1
Trucks, G.W.2
Keith, T.A.3
Frisch, M.J.4
-
65
-
-
0011413447
-
-
note
-
5 bonded).
-
-
-
-
66
-
-
0011413627
-
-
note
-
2v) have been fixed to be equal during the optimization procedure. This results in a calculated structure for 3b with SiC distances of 2.448 Å (at B3LYP/6-31G(d)).
-
-
-
-
68
-
-
0000880746
-
-
1.5 coordination in main group chemistry: Fisher, J. D.; Budzelaar, P. H. M.; Shapiro, P. J.; Staples, R. J.; Yap, G. P. A.; Rheingold, A. L. Organometallics 1997, 16, 871.
-
(1997)
Organometallics
, vol.16
, pp. 871
-
-
Fisher, J.D.1
Budzelaar, P.H.M.2
Shapiro, P.J.3
Staples, R.J.4
Yap, G.P.A.5
Rheingold, A.L.6
-
69
-
-
0000263012
-
-
Fisher, J. D.; Wei, M.-Y.; Willet, R.; Shapiro, P. J. Organometallics 1994, 13, 3324.
-
(1994)
Organometallics
, vol.13
, pp. 3324
-
-
Fisher, J.D.1
Wei, M.-Y.2
Willet, R.3
Shapiro, P.J.4
-
70
-
-
0001755974
-
-
(a) Schoeller, W. W.; Friedrich, O.; Sundermann, A.; Rozhenko, A. Organometallics 1999, 18, 2099.
-
(1999)
Organometallics
, vol.18
, pp. 2099
-
-
Schoeller, W.W.1
Friedrich, O.2
Sundermann, A.3
Rozhenko, A.4
-
71
-
-
0011510482
-
-
note
-
1.5 coordination for this isomer.
-
-
-
-
79
-
-
0011415704
-
-
TrongAnh, N.; Elian, M.; Hoffmann, R. J. Am. Chem. Soc. 1978, 100, 110.
-
(1978)
J. Am. Chem. Soc.
, vol.100
, pp. 110
-
-
TrongAnh, N.1
Elian, M.2
Hoffmann, R.3
-
80
-
-
0011518342
-
-
note
-
γ').
-
-
-
-
81
-
-
0011413629
-
-
note
-
j are the energies of the corresponding orbitals.
-
-
-
-
82
-
-
0000939857
-
-
Ottosson, C.-H.; Szabó, K. J.; Cremer, D. Organometallics 1997, 16, 2377.
-
(1997)
Organometallics
, vol.16
, pp. 2377
-
-
Ottosson, C.-H.1
Szabó, K.J.2
Cremer, D.3
-
83
-
-
84891308797
-
-
Pidun, U.; Stahl, M.; Frenking, G. Chem. Eur. J. 1996, 2, 869.
-
(1996)
Chem. Eur. J.
, vol.2
, pp. 869
-
-
Pidun, U.1
Stahl, M.2
Frenking, G.3
-
84
-
-
0001744460
-
-
Lambert, J. B.; Zhang, S.; Stern, C. L.; Ciro, S. M. Organometallics 1994, 13, 2430.
-
(1994)
Organometallics
, vol.13
, pp. 2430
-
-
Lambert, J.B.1
Zhang, S.2
Stern, C.L.3
Ciro, S.M.4
-
85
-
-
0011409889
-
-
note
-
-1. We are indebted to one of the reviewers for drawing our attention to this point.
-
-
-
-
86
-
-
84986461296
-
-
Hobza, P.; Šponer, J.; Reschel, T. J. Comput. Chem. 1995, 16, 1315.
-
(1995)
J. Comput. Chem.
, vol.16
, pp. 1315
-
-
Hobza, P.1
Šponer, J.2
Reschel, T.3
-
88
-
-
36549104578
-
-
(a) Nowak, R.; Menapace, J. A.; Bernstein, E. R. J. Chem. Phys. 1988, 89, 1309.
-
(1988)
J. Chem. Phys.
, vol.89
, pp. 1309
-
-
Nowak, R.1
Menapace, J.A.2
Bernstein, E.R.3
-
89
-
-
0031250361
-
-
(b) Wesolowski, T. A.; Parisel, O.; Ellinger, Y.; Weber, J. J. Phys. Chem. A 1997, 101, 7818.
-
(1997)
J. Phys. Chem. A
, vol.101
, pp. 7818
-
-
Wesolowski, T.A.1
Parisel, O.2
Ellinger, Y.3
Weber, J.4
-
90
-
-
33748217457
-
-
Schleyer, P. v. R.; Buzek, P.; Müller, T.; Apeloig, Y.; Siehl, H.-U. Angew. Chem., Int. Ed. 1993, 32, 1471.
-
(1993)
Angew. Chem., Int. Ed.
, vol.32
, pp. 1471
-
-
Schleyer, P.V.R.1
Buzek, P.2
Müller, T.3
Apeloig, Y.4
Siehl, H.-U.5
-
91
-
-
84962460770
-
-
(a) Cremer, D.; Olsson, L.; Ottoson, C.-H. J. Mol. Struct. (THEOCHEM) 1994, 313, 91.
-
(1994)
J. Mol. Struct. (THEOCHEM)
, vol.313
, pp. 91
-
-
Cremer, D.1
Olsson, L.2
Ottoson, C.-H.3
-
92
-
-
0001316475
-
-
(b) Olsson, L.; Ottosson, C.-H.; Cremer, D. J. Am. Chem. Soc. 1995, 117, 7460.
-
(1995)
J. Am. Chem. Soc.
, vol.117
, pp. 7460
-
-
Olsson, L.1
Ottosson, C.-H.2
Cremer, D.3
-
93
-
-
0003612389
-
-
Auner, N., Weis, J., Eds.; VCH; Weinheim, Germany
-
Auner, N.; Müller, T.; Ostermeier, M.; Schuppan, J.; Steinberger, H.-U. In Organosilicon Chemistry: From Molecules to Materials IV; Auner, N., Weis, J., Eds.; VCH; Weinheim, Germany, 2000; p 127.
-
(2000)
Organosilicon Chemistry: From Molecules to Materials IV
, pp. 127
-
-
Auner, N.1
Müller, T.2
Ostermeier, M.3
Schuppan, J.4
Steinberger, H.-U.5
-
94
-
-
0035969273
-
-
Schuppan, J.; Herrschaft, B.; Müller, T. Organometallics 2001, 20, 4584.
-
(2001)
Organometallics
, vol.20
, pp. 4584
-
-
Schuppan, J.1
Herrschaft, B.2
Müller, T.3
-
95
-
-
0011502929
-
-
note
-
The most stable isomer at B3LYP/6-31G(d) is 2c, although at the higher B3LYP/6-311G(2d,p) level, 2f is favored. Therefore, the free geometry optimization of the solvates 9 and 10 results in silyl cation structures which closely resemble 2c. Consequently, the calculated chemical shifts of 9 and 10 have to be compared with those predicted for 2c.
-
-
-
-
96
-
-
84985579900
-
-
Jutzi, P.; Wippermann, T.; Krüger, C.; Kraus, H.-J. Angew. Chem., Int. Ed. 1983, 22, 250.
-
(1983)
Angew. Chem., Int. Ed.
, vol.22
, pp. 250
-
-
Jutzi, P.1
Wippermann, T.2
Krüger, C.3
Kraus, H.-J.4
|