Theoretical investigations on reactions of a series of stable dialkyl-substituted silicon-chalcogen doubly bonded compounds

Organometallics

Volumn 29, Issue 3, 2010, Pages 527-535

  Sheu, Jeng Horng ^a   Su, Ming Der ^a  

^a NATIONAL CHIAYI UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

CHALCOGEN ATOMS; CHALCOGENS; CYCLOADDITION REACTION; DIAGNOSTIC TOOLS; EXPERIMENTAL OBSERVATION; MIXING MODELS; MODEL REACTANT; RELATIVE REACTIVITIES; SINGLET-TRIPLET; THEORETICAL INVESTIGATIONS;

QUANTUM CHEMISTRY; SILICON COMPOUNDS; TELLURIUM COMPOUNDS;

CYCLOADDITION;

EID: 76149106848     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om900594z     Document Type: Article

References (44)

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44. As suggested by a reviewer, in eq B, it could be possible to produce such a Te-O bond formation product, i.e., formation of the isomer opposite the one shown in Scheme 1. We tried to obtain such reaction mechanisms using the present DFT method. However, they always failed. We thus believe that the Si-X bond formation product is the only product for the alcohol addition reaction.