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0344817517
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note
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C on the solvent polarity as a function of power series of [S].
-
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-
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42
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0344817513
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note
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-2 within the acuracy of our experiments.
-
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-
-
43
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0344385811
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note
-
Expectedly, photolysis of 1 in ethanol-d gave deuterated hydrosilane 4-d, where deuterium was incorporated almost quantitatively as Si-D.
-
-
-
-
44
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0344385810
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note
-
The NPE states are treated as a set in the subsequent discussion.
-
-
-
-
45
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2142649831
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2 mixtures at constant ethanol concentration, to elucidate the effects of solvent polarity on the importance of formations of 2 and 3 relative to that of 4. However, the photolysis of 1 in such solvent systems gave a complex mixture including products from the photoreactions of 1 with dichloromethane. For photoreactions of an aryldisilane with a chloroalkane see: Sluggett, G. W.; Leigh, W. J. Organometallics 1994, 13, 1005.
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The authors thank a reviewer for modification of the discussion in this section.
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49
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0344385809
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note
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a state more favorable.
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