메뉴 건너뛰기




Volumn 121, Issue 15, 1999, Pages 3651-3656

Mechanistic studies of photochemical silylene extrusion from 2,2- diphenylhexamethyltrisilane

Author keywords

[No Author keywords available]

Indexed keywords

2,2 DIPHENYLHEXAMEHTYLTRISILANE; ARYLOLIGOSILANE; SILANE DERIVATIVE; UNCLASSIFIED DRUG;

EID: 0033594464     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja983370k     Document Type: Article
Times cited : (17)

References (56)
  • 1
    • 0000833148 scopus 로고    scopus 로고
    • Rappoport, Z., Apeloig, Y., Eds.; John Wiley: New York, Chapter 22
    • For recent reviews, see: (a) Kira, M.; Miyazawa, T. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; John Wiley: New York, 1998; Vol. 2, Chapter 22.
    • (1998) The Chemistry of Organic Silicon Compounds , vol.2
    • Kira, M.1    Miyazawa, T.2
  • 2
    • 0037990787 scopus 로고    scopus 로고
    • Rappoport, Z., Apeloig, Y., Eds.; John Wiley: New York, Chapter 21
    • (b) Brook, A. G. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; John Wiley: New York, 1998; Vol. 2, Chapter 21.
    • (1998) The Chemistry of Organic Silicon Compounds , vol.2
    • Brook, A.G.1
  • 3
    • 0344817555 scopus 로고
    • Patai, S., Rappoport, Z., Eds.; John Wiley: New York, Chapter 15
    • (c) Brook, A. G. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; John Wiley: New York, 1989; Chapter 15.
    • (1989) The Chemistry of Organic Silicon Compounds
    • Brook, A.G.1
  • 4
  • 41
    • 0344817517 scopus 로고    scopus 로고
    • note
    • C on the solvent polarity as a function of power series of [S].
  • 42
    • 0344817513 scopus 로고    scopus 로고
    • note
    • -2 within the acuracy of our experiments.
  • 43
    • 0344385811 scopus 로고    scopus 로고
    • note
    • Expectedly, photolysis of 1 in ethanol-d gave deuterated hydrosilane 4-d, where deuterium was incorporated almost quantitatively as Si-D.
  • 44
    • 0344385810 scopus 로고    scopus 로고
    • note
    • The NPE states are treated as a set in the subsequent discussion.
  • 45
    • 2142649831 scopus 로고
    • 2 mixtures at constant ethanol concentration, to elucidate the effects of solvent polarity on the importance of formations of 2 and 3 relative to that of 4. However, the photolysis of 1 in such solvent systems gave a complex mixture including products from the photoreactions of 1 with dichloromethane. For photoreactions of an aryldisilane with a chloroalkane see: Sluggett, G. W.; Leigh, W. J. Organometallics 1994, 13, 1005.
    • (1994) Organometallics , vol.13 , pp. 1005
    • Sluggett, G.W.1    Leigh, W.J.2
  • 48
    • 0345248664 scopus 로고    scopus 로고
    • note
    • The authors thank a reviewer for modification of the discussion in this section.
  • 49
    • 0344385809 scopus 로고    scopus 로고
    • note
    • a state more favorable.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.