Synthesis and reactivity of a stable silylene

Journal of the American Chemical Society

Volumn 120, Issue 49, 1998, Pages 12714-12719

  Haaf, Michael ^a   Schmiedl, Andreas ^a   Schmedake, Thomas A ^a   Powell, Douglas R ^a   Millevolte, Anthony J ^a   Denk, Michael ^a   West, Robert ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL; IMINE; LITHIUM SALT; METHYL IODIDE; SELENIUM; SILANE DERIVATIVE; SILOXANE; SPIRO COMPOUND; SULFUR; WATER;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CRYSTAL STRUCTURE; MOLECULAR STABILITY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 0032539236     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9733999     Document Type: Article

References (19)

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2. For reviews, see Caspar, P. P.; West, R. In Chemistry of Organosilicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: New York, 1998; Vol. 2, pp. 2463-2568; Nefedov, O. M.; Egorov, M. P.; Ioffe, A. I.; Menchikov, C. G.; Zuev, P. S.; Minikin, V. L.; Simkin, B. Y.; Glukhovtsev, M. N. Pure Appl. Chem. 1992, 64, 265.
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18. This crystal structure is in agreement with one obtained by workers at the Du Pont Co. We thank A. J. Arduengo III and J. C. Calabrese for communication of their independent results.
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