α,β-Divinyl tetrahydropyrroles as chiral chain diene ligands in rhodium(I)-catalyzed enantioselective conjugated additions

Organic Letters

Volumn 13, Issue 5, 2011, Pages 1122-1125

  Li, Qian ^a   Dong, Zhe ^a   Yu, Zhi Xiang ^a  

^a PEKING UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ALKADIENE; LIGAND; PYRROLE DERIVATIVE; RHODIUM;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; COMBINATORIAL CHEMISTRY; STEREOISOMERISM; SYNTHESIS;

ALKADIENES; CATALYSIS; COMBINATORIAL CHEMISTRY TECHNIQUES; LIGANDS; MOLECULAR STRUCTURE; PYRROLES; RHODIUM; STEREOISOMERISM;

EID: 79952127103     PISSN: 15237060     EISSN: 15237052     Source Type: Journal    
DOI: 10.1021/ol103152t     Document Type: Article

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57. As one referee required that at least one reaction should be tested using the enantiomeric pure diene ligand, we carried out a standard reaction shown in Table 1 using diene ligand 1a in 100% ee, which was obtained by preparative HPLC (Chiralpak OD column). In this case, 97% ee was obtained (see entry 9, Table 1, and the study of nonlinear effect part of the Supporting Information).