Chemoenzymatic synthesis and application of bicyclo [2.2.2] octadiene ligands: Increased efficiency in rhodium-catalyzed asymmetric conjugate additions by electronic tuning

Angewandte Chemie - International Edition

Volumn 49, Issue 15, 2010, Pages 2750-2754

  Luo, Yunfei ^a   Carnell, Andrew J ^a  

^a UNIVERSITY OF LIVERPOOL   (United Kingdom)

Author keywords

Asymmetric catalysis; Chemoenzymatic synthesis; Chiral dienes; Conjugate addition; Rhodium

Indexed keywords

ASYMMETRIC CATALYSIS; ASYMMETRIC CONJUGATE ADDITION; BORONIC ACID; CHEMO-ENZYMATIC SYNTHESIS; CHIRAL DIENES; CONJUGATE ADDITION; DIENE LIGANDS; ELECTRONIC TUNING; METHYL GROUP; OCTADIENE; RHODIUM-CATALYZED; STEP SEQUENCES;

ADDITION REACTIONS; CATALYSIS; LIGANDS; OLEFINS; RHODIUM; SYNTHESIS (CHEMICAL);

CHELATION;

BICYCLO COMPOUND; BICYCLO(2.2.2)OCT 2 ENE; BICYCLO(2.2.2)OCT-2-ENE; BORONIC ACID DERIVATIVE; LIGAND; RHODIUM; TRIACYLGLYCEROL LIPASE;

ARTICLE; CATALYSIS; CHEMISTRY; ELECTRON; METABOLISM; STEREOISOMERISM;

BICYCLO COMPOUNDS; BORONIC ACIDS; CATALYSIS; ELECTRONS; LIGANDS; LIPASE; RHODIUM; STEREOISOMERISM;

EID: 77950463156     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.200907033     Document Type: Article

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