Ni[In{C(SiMe3)3}4]: An organometallic nickel-indium compound analogous to [Ni(CO)4]

Angewandte Chemie - International Edition

Volumn 37, Issue 7, 1998, Pages 961-963

  Uhl, Werner ^a   Pohlmann, Michael ^a   Wartchow, Rudolf ^b  

^a UNIVERSITY OF OLDENBURG   (Germany)

^b Leibniz University Hannover   (Germany)

Author keywords

Clusters; Electron deficiency; Indium; Isolobal relationship; Nickel

Indexed keywords

EID: 0031980690     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980420)37:7<961::AID-ANIE961>3.0.CO;2-4     Document Type: Article

References (44)

1. W. Uhl, W. Hiller, M. Layh, W. Schwarz, Angew. Chem. 1992, 104, 1378; Angew. Chem. Int. Ed. Engl. 1992, 31, 1364.
2. W. Uhl, W. Hiller, M. Layh, W. Schwarz, Angew. Chem. 1992, 104, 1378; Angew. Chem. Int. Ed. Engl. 1992, 31, 1364.
3. W. Uhl, R. Graupner, M. Layh, U. Schüz. J. Organomet. Chem. 1995, 493, C1; see also: R. D. Schluter, A. H. Cowley, D. A. Atwood, R. A. Jones, J. L. Atwood, J. Coord. Chem. 1993, 30, 25.
4. W. Uhl, R. Graupner, M. Layh, U. Schüz. J. Organomet. Chem. 1995, 493, C1; see also: R. D. Schluter, A. H. Cowley, D. A. Atwood, R. A. Jones, J. L. Atwood, J. Coord. Chem. 1993, 30, 25.
5. W. Uhl, S. U. Keimling, K. W. Klinkhammer, W. Schwarz, Angew. Chem. 1997, 109, 64; Angew. Chem. Int. Ed. Engl. 1997, 36, 64.
6. W. Uhl, S. U. Keimling, K. W. Klinkhammer, W. Schwarz, Angew. Chem. 1997, 109, 64; Angew. Chem. Int. Ed. Engl. 1997, 36, 64.
7. [4) A. Haaland, K.-G. Martinsen, H. V. Volden, W. Kaim, E. Waldhör, W. Uhl, U. Schütz, Organometallics 1996, 15, 1146.
8. W. Uhl, S. U. Keimling, S. Pohl, W. Saak, R. Wartchow, Chem. Ber. 1997 130, 1269.
9. W. Uhl, S. U. Keimling, W. Hiller, M. Neumayer, Chem. Ber. 1995, 128, 1137; W. Uhl, S. U. Keimling, W. Hiller, M. Neumayer, ibid. 1996, 129, 397.
10. W. Uhl, S. U. Keimling, W. Hiller, M. Neumayer, Chem. Ber. 1995, 128, 1137; W. Uhl, S. U. Keimling, W. Hiller, M. Neumayer, ibid. 1996, 129, 397.
11. W. Uhl, M. Pohlmann, Organometallics 1997, 16, 2478.
12. C. Dohmeier, C. Robl, M. Tacke, H. Schnöckel, Angew. Chem. 1991, 103, 594; Angew. Chem. Int. Ed. Engl. 1991, 30, 564; C. Dohmeier, H. Krautscheid, H. Schnöckel, ibid. 1994, 106, 2570; 1994,. 33, 2482; Review: C. Dohmeier, D. Loos, H. Schnöckel, ibid. 1996, 108, 141; 1996, 35, 129.
13. C. Dohmeier, C. Robl, M. Tacke, H. Schnöckel, Angew. Chem. 1991, 103, 594; Angew. Chem. Int. Ed. Engl. 1991, 30, 564; C. Dohmeier, H. Krautscheid, H. Schnöckel, ibid. 1994, 106, 2570; 1994,. 33, 2482; Review: C. Dohmeier, D. Loos, H. Schnöckel, ibid. 1996, 108, 141; 1996, 35, 129.
14. C. Dohmeier, C. Robl, M. Tacke, H. Schnöckel, Angew. Chem. 1991, 103, 594; Angew. Chem. Int. Ed. Engl. 1991, 30, 564; C. Dohmeier, H. Krautscheid, H. Schnöckel, ibid. 1994, 106, 2570; 1994,. 33, 2482; Review: C. Dohmeier, D. Loos, H. Schnöckel, ibid. 1996, 108, 141; 1996, 35, 129.
15. C. Dohmeier, C. Robl, M. Tacke, H. Schnöckel, Angew. Chem. 1991, 103, 594; Angew. Chem. Int. Ed. Engl. 1991, 30, 564; C. Dohmeier, H. Krautscheid, H. Schnöckel, ibid. 1994, 106, 2570; 1994,. 33, 2482; Review: C. Dohmeier, D. Loos, H. Schnöckel, ibid. 1996, 108, 141; 1996, 35, 129.
16. C. Dohmeier, C. Robl, M. Tacke, H. Schnöckel, Angew. Chem. 1991, 103, 594; Angew. Chem. Int. Ed. Engl. 1991, 30, 564; C. Dohmeier, H. Krautscheid, H. Schnöckel, ibid. 1994, 106, 2570; 1994,. 33, 2482; Review: C. Dohmeier, D. Loos, H. Schnöckel, ibid. 1996, 108, 141; 1996, 35, 129.
17. C. Dohmeier, C. Robl, M. Tacke, H. Schnöckel, Angew. Chem. 1991, 103, 594; Angew. Chem. Int. Ed. Engl. 1991, 30, 564; C. Dohmeier, H. Krautscheid, H. Schnöckel, ibid. 1994, 106, 2570; 1994,. 33, 2482; Review: C. Dohmeier, D. Loos, H. Schnöckel, ibid. 1996, 108, 141; 1996, 35, 129.
18. J. Weiss, D. Stetzkamp, B. Nuber, R. A. Fischer. C. Boehme, G. Frenking, Angew. Chem 1997, 109, 95; Angew. Chem. Int. Ed. Engl. 1997, 36, 70; the terminal coordination of a GaMe fragment, which is, however, further coordinated by TMEDA, is described in: M. M. Schulte, E. Herdtweck, G. Raudaschl-Sieber, R. A. Fischer, ibid. 1996, 108, 489; 1996, 35, 424.
19. J. Weiss, D. Stetzkamp, B. Nuber, R. A. Fischer. C. Boehme, G. Frenking, Angew. Chem 1997, 109, 95; Angew. Chem. Int. Ed. Engl. 1997, 36, 70; the terminal coordination of a GaMe fragment, which is, however, further coordinated by TMEDA, is described in: M. M. Schulte, E. Herdtweck, G. Raudaschl-Sieber, R. A. Fischer, ibid. 1996, 108, 489; 1996, 35, 424.
20. J. Weiss, D. Stetzkamp, B. Nuber, R. A. Fischer. C. Boehme, G. Frenking, Angew. Chem 1997, 109, 95; Angew. Chem. Int. Ed. Engl. 1997, 36, 70; the terminal coordination of a GaMe fragment, which is, however, further coordinated by TMEDA, is described in: M. M. Schulte, E. Herdtweck, G. Raudaschl-Sieber, R. A. Fischer, ibid. 1996, 108, 489; 1996, 35, 424.
21. J. Weiss, D. Stetzkamp, B. Nuber, R. A. Fischer. C. Boehme, G. Frenking, Angew. Chem 1997, 109, 95; Angew. Chem. Int. Ed. Engl. 1997, 36, 70; the terminal coordination of a GaMe fragment, which is, however, further coordinated by TMEDA, is described in: M. M. Schulte, E. Herdtweck, G. Raudaschl-Sieber, R. A. Fischer, ibid. 1996, 108, 489; 1996, 35, 424.
22. S. S. Al-Juaid, N. H. Buttrus, C. Eaborn, P. B. Hitchcock, A. T. L. Roberts, J. D. Smith, A. C. Sullivan, J. Chem. Soc. Chem. Commun. 1986, 908.
23. W. Uhl, M. Layh, W. Miller, J. Organomet. Chem. 1989, 368, 139; W. Uhl, R. Graupner, H. Reuter, ibid. 1996, 523, 227; B. Neumüller, F. Gahlmann, M. Schäfer, S. Magull, ibid. 1992, 440, 263; A. J. Carty, M. J. S. Gynane, M. F. Lappert, S. J. Miles, A. Singh, N. J. Taylor, Inorg. Chem. 1980, 19, 3637.
24. W. Uhl, M. Layh, W. Miller, J. Organomet. Chem. 1989, 368, 139; W. Uhl, R. Graupner, H. Reuter, ibid. 1996, 523, 227; B. Neumüller, F. Gahlmann, M. Schäfer, S. Magull, ibid. 1992, 440, 263; A. J. Carty, M. J. S. Gynane, M. F. Lappert, S. J. Miles, A. Singh, N. J. Taylor, Inorg. Chem. 1980, 19, 3637.
25. W. Uhl, M. Layh, W. Miller, J. Organomet. Chem. 1989, 368, 139; W. Uhl, R. Graupner, H. Reuter, ibid. 1996, 523, 227; B. Neumüller, F. Gahlmann, M. Schäfer, S. Magull, ibid. 1992, 440, 263; A. J. Carty, M. J. S. Gynane, M. F. Lappert, S. J. Miles, A. Singh, N. J. Taylor, Inorg. Chem. 1980, 19, 3637.
26. W. Uhl, M. Layh, W. Miller, J. Organomet. Chem. 1989, 368, 139; W. Uhl, R. Graupner, H. Reuter, ibid. 1996, 523, 227; B. Neumüller, F. Gahlmann, M. Schäfer, S. Magull, ibid. 1992, 440, 263; A. J. Carty, M. J. S. Gynane, M. F. Lappert, S. J. Miles, A. Singh, N. J. Taylor, Inorg. Chem. 1980, 19, 3637.
27. 3 groups are rotationally disordered, and six positions are observed for the three Si atoms with occupancy factors of 0.5. Two methyl groups lie on a mirror plane with bonds to two Si atoms, and the third methyl group occupies two positions above and below this plane. The cyclopentane molecules are strongly disordered over cristallographic symmetry elements; positions of the hydrogen atoms were not calculated. Cristallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-100776. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: (+44) 1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
28. D. Braga, F. Grepioni, A. G. Orpen, Organometallics 1993, 12, 1481; J. C. Marriott, J. A. Salthouse, M. J. Ware, J. M. Freeman, J. Chem. Soc. Chem. Commun. 1970, 595; C. Elschenbroich, M. Nowotny, A. Behrendt, W. Massa, S. Wocadlo, Angew. Chem. 1992, 104, 1388; Angew. Chem. Int. Ed. Engl. 1992, 31, 1343; M. B. Hursthouse, K. J. Izod, M. Motevalli, P. Thornton, Polyhedron 1994, 13, 151; E. Singleton, H. E. Oosthuizen, Adv. Organomet. Chem. 1983, 22, 209, and references therein.
29. D. Braga, F. Grepioni, A. G. Orpen, Organometallics 1993, 12, 1481; J. C. Marriott, J. A. Salthouse, M. J. Ware, J. M. Freeman, J. Chem. Soc. Chem. Commun. 1970, 595; C. Elschenbroich, M. Nowotny, A. Behrendt, W. Massa, S. Wocadlo, Angew. Chem. 1992, 104, 1388; Angew. Chem. Int. Ed. Engl. 1992, 31, 1343; M. B. Hursthouse, K. J. Izod, M. Motevalli, P. Thornton, Polyhedron 1994, 13, 151; E. Singleton, H. E. Oosthuizen, Adv. Organomet. Chem. 1983, 22, 209, and references therein.
30. D. Braga, F. Grepioni, A. G. Orpen, Organometallics 1993, 12, 1481; J. C. Marriott, J. A. Salthouse, M. J. Ware, J. M. Freeman, J. Chem. Soc. Chem. Commun. 1970, 595; C. Elschenbroich, M. Nowotny, A. Behrendt, W. Massa, S. Wocadlo, Angew. Chem. 1992, 104, 1388; Angew. Chem. Int. Ed. Engl. 1992, 31, 1343; M. B. Hursthouse, K. J. Izod, M. Motevalli, P. Thornton, Polyhedron 1994, 13, 151; E. Singleton, H. E. Oosthuizen, Adv. Organomet. Chem. 1983, 22, 209, and references therein.
31. D. Braga, F. Grepioni, A. G. Orpen, Organometallics 1993, 12, 1481; J. C. Marriott, J. A. Salthouse, M. J. Ware, J. M. Freeman, J. Chem. Soc. Chem. Commun. 1970, 595; C. Elschenbroich, M. Nowotny, A. Behrendt, W. Massa, S. Wocadlo, Angew. Chem. 1992, 104, 1388; Angew. Chem. Int. Ed. Engl. 1992, 31, 1343; M. B. Hursthouse, K. J. Izod, M. Motevalli, P. Thornton, Polyhedron 1994, 13, 151; E. Singleton, H. E. Oosthuizen, Adv. Organomet. Chem. 1983, 22, 209, and references therein.
32. D. Braga, F. Grepioni, A. G. Orpen, Organometallics 1993, 12, 1481; J. C. Marriott, J. A. Salthouse, M. J. Ware, J. M. Freeman, J. Chem. Soc. Chem. Commun. 1970, 595; C. Elschenbroich, M. Nowotny, A. Behrendt, W. Massa, S. Wocadlo, Angew. Chem. 1992, 104, 1388; Angew. Chem. Int. Ed. Engl. 1992, 31, 1343; M. B. Hursthouse, K. J. Izod, M. Motevalli, P. Thornton, Polyhedron 1994, 13, 151; E. Singleton, H. E. Oosthuizen, Adv. Organomet. Chem. 1983, 22, 209, and references therein.
33. D. Braga, F. Grepioni, A. G. Orpen, Organometallics 1993, 12, 1481; J. C. Marriott, J. A. Salthouse, M. J. Ware, J. M. Freeman, J. Chem. Soc. Chem. Commun. 1970, 595; C. Elschenbroich, M. Nowotny, A. Behrendt, W. Massa, S. Wocadlo, Angew. Chem. 1992, 104, 1388; Angew. Chem. Int. Ed. Engl. 1992, 31, 1343; M. B. Hursthouse, K. J. Izod, M. Motevalli, P. Thornton, Polyhedron 1994, 13, 151; E. Singleton, H. E. Oosthuizen, Adv. Organomet. Chem. 1983, 22, 209, and references therein.
34. M. Veith, L. Stahl, V. Much, J. Chem. Soc. Chem. Commun. 1990, 359.
35. F. Demartin, M. C. Iapalucci, G. Longoni, Inorg. Chem. 1993, 32, 5536; R. E. Marsh, I. Bernal, Acta Crystallogr. Sect. B 1995, 51, 300; R. A. Fischer, W. Scherer, M. Kleine, Angew. Chem. 1993, 105, 778; Angew. Chem. Int. Ed. Engl. 1993, 32, 748; R. A. Fischer, E. Herdtweck, T. Priermeier, Inorg. Chem. 1994, 33, 934; R. A. Fischer, S. Nlate, H. Hoffmann, E. Herdtweck, J. Blümel, Organometallics 1996, 15, 5746; J. J. Schneider, U. Denninger, J. Hagen, C. Krüger, D. Bläser, R. Boese. Chem. Ber. 1997, 130, 1433.
36. F. Demartin, M. C. Iapalucci, G. Longoni, Inorg. Chem. 1993, 32, 5536; R. E. Marsh, I. Bernal, Acta Crystallogr. Sect. B 1995, 51, 300; R. A. Fischer, W. Scherer, M. Kleine, Angew. Chem. 1993, 105, 778; Angew. Chem. Int. Ed. Engl. 1993, 32, 748; R. A. Fischer, E. Herdtweck, T. Priermeier, Inorg. Chem. 1994, 33, 934; R. A. Fischer, S. Nlate, H. Hoffmann, E. Herdtweck, J. Blümel, Organometallics 1996, 15, 5746; J. J. Schneider, U. Denninger, J. Hagen, C. Krüger, D. Bläser, R. Boese. Chem. Ber. 1997, 130, 1433.
37. F. Demartin, M. C. Iapalucci, G. Longoni, Inorg. Chem. 1993, 32, 5536; R. E. Marsh, I. Bernal, Acta Crystallogr. Sect. B 1995, 51, 300; R. A. Fischer, W. Scherer, M. Kleine, Angew. Chem. 1993, 105, 778; Angew. Chem. Int. Ed. Engl. 1993, 32, 748; R. A. Fischer, E. Herdtweck, T. Priermeier, Inorg. Chem. 1994, 33, 934; R. A. Fischer, S. Nlate, H. Hoffmann, E. Herdtweck, J. Blümel, Organometallics 1996, 15, 5746; J. J. Schneider, U. Denninger, J. Hagen, C. Krüger, D. Bläser, R. Boese. Chem. Ber. 1997, 130, 1433.
38. F. Demartin, M. C. Iapalucci, G. Longoni, Inorg. Chem. 1993, 32, 5536; R. E. Marsh, I. Bernal, Acta Crystallogr. Sect. B 1995, 51, 300; R. A. Fischer, W. Scherer, M. Kleine, Angew. Chem. 1993, 105, 778; Angew. Chem. Int. Ed. Engl. 1993, 32, 748; R. A. Fischer, E. Herdtweck, T. Priermeier, Inorg. Chem. 1994, 33, 934; R. A. Fischer, S. Nlate, H. Hoffmann, E. Herdtweck, J. Blümel, Organometallics 1996, 15, 5746; J. J. Schneider, U. Denninger, J. Hagen, C. Krüger, D. Bläser, R. Boese. Chem. Ber. 1997, 130, 1433.
39. F. Demartin, M. C. Iapalucci, G. Longoni, Inorg. Chem. 1993, 32, 5536; R. E. Marsh, I. Bernal, Acta Crystallogr. Sect. B 1995, 51, 300; R. A. Fischer, W. Scherer, M. Kleine, Angew. Chem. 1993, 105, 778; Angew. Chem. Int. Ed. Engl. 1993, 32, 748; R. A. Fischer, E. Herdtweck, T. Priermeier, Inorg. Chem. 1994, 33, 934; R. A. Fischer, S. Nlate, H. Hoffmann, E. Herdtweck, J. Blümel, Organometallics 1996, 15, 5746; J. J. Schneider, U. Denninger, J. Hagen, C. Krüger, D. Bläser, R. Boese. Chem. Ber. 1997, 130, 1433.
40. F. Demartin, M. C. Iapalucci, G. Longoni, Inorg. Chem. 1993, 32, 5536; R. E. Marsh, I. Bernal, Acta Crystallogr. Sect. B 1995, 51, 300; R. A. Fischer, W. Scherer, M. Kleine, Angew. Chem. 1993, 105, 778; Angew. Chem. Int. Ed. Engl. 1993, 32, 748; R. A. Fischer, E. Herdtweck, T. Priermeier, Inorg. Chem. 1994, 33, 934; R. A. Fischer, S. Nlate, H. Hoffmann, E. Herdtweck, J. Blümel, Organometallics 1996, 15, 5746; J. J. Schneider, U. Denninger, J. Hagen, C. Krüger, D. Bläser, R. Boese. Chem. Ber. 1997, 130, 1433.
41. F. Demartin, M. C. Iapalucci, G. Longoni, Inorg. Chem. 1993, 32, 5536; R. E. Marsh, I. Bernal, Acta Crystallogr. Sect. B 1995, 51, 300; R. A. Fischer, W. Scherer, M. Kleine, Angew. Chem. 1993, 105, 778; Angew. Chem. Int. Ed. Engl. 1993, 32, 748; R. A. Fischer, E. Herdtweck, T. Priermeier, Inorg. Chem. 1994, 33, 934; R. A. Fischer, S. Nlate, H. Hoffmann, E. Herdtweck, J. Blümel, Organometallics 1996, 15, 5746; J. J. Schneider, U. Denninger, J. Hagen, C. Krüger, D. Bläser, R. Boese. Chem. Ber. 1997, 130, 1433.
42. J. Weiss, T. Priermeier, R. A. Fischer, Inorg. Chem. 1996, 35, 71.
43. J. Weiss, A. Frank, E. Herdtweck, S. Nlate, M. Mattner, R. A. Fischer, Chem. Ber. 1996, 129, 297.
44. R. A. Fischer, M. Kleine, O. Lehmann, M. Stuke, Chem. Mat. 1995, 7, 1863.