O/W nano-emulsions with tunable PIT induced by inorganic salts

Colloids and Surfaces A: Physicochemical and Engineering Aspects

Volumn 375, Issue 1-3, 2011, Pages 102-108

  Mei, Zhen ^a   Xu, Jian ^a   Sun, Dejun ^a  

^a SHANDONG UNIVERSITY   (China)

Author keywords

Long term stability; Nano emulsions; Phase inversion temperature (PIT); Spontaneous curvature; Zeta potential

Indexed keywords

COALESCENCE; DROP FORMATION; EMULSIFICATION; OSTWALD RIPENING; PARAFFIN WAXES; PARAFFINS; SALTS; STABILITY; ZETA POTENTIAL;

ABSOLUTE VALUES; CONDUCTIVITY MEASUREMENTS; ELECTROPHORETIC PROPERTY; EMULSION DROPLETS; INORGANIC SALTS; INSTABILITY MECHANISMS; LONG TERM STABILITY; NANO-EMULSIONS; NANOEMULSION; OIL/WATER; PHASE INVERSION TEMPERATURE; PHASE INVERSION TEMPERATURE METHODS; SALTING-OUT; SPAN 80; SPONTANEOUS CURVATURE; TWEEN 80; ZETA POTENTIAL MEASUREMENTS;

EMULSIONS;

INORGANIC SALT; LIQUID PARAFFIN; POLYSORBATE 80; SORBITAN OLEATE;

ARTICLE; CONDUCTANCE; ELECTROPHORESIS; EMULSION; LIGHT SCATTERING; MOLECULAR STABILITY; NANOEMULSION; PHASE INVERSION TEMPERATURE; PRIORITY JOURNAL; TEMPERATURE RELATED PHENOMENA; ZETA POTENTIAL;

EID: 78751624553     PISSN: 09277757     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.colsurfa.2010.11.069     Document Type: Article

References (41)

1. Solans C., Izquierdo P., Nolla J., Azemar N., Garcia-Celma M.J. Nano-emulsions. Curr. Opin. Colloid Interface Sci. 2005, 10:102-110.
2. Tadros T., Izquierdo P., Esquena J., Solans C. Formation and stability of nano-emulsions. Adv. Colloid Interface Sci. 2004, 108-109:303-318.
3. Aubrun O.S., Simonnet J.T., L'Alloret F. Nanoemulsions: a new vehicle for skincare products. Adv. Colloid Interface Sci. 2004, 108-109:145-149.
4. Kang H.S., Kwon S.S., Kim B.H. Nanoemulsion as a vitamin E acetate carrier to enhance infiltration into oral mucous membrane. J. Ind. Eng. Chem. 2002, 8(4):348-353.
5. Wang L.J., Li X.F., Zhang G.Y., Dong J.F., Eastoe J. Oil-in-water nanoemulsions for pesticide formulations. J. Colloid Interface Sci. 2007, 314:230-235.
6. Maruno M., Rocha-Filho P.A. O/W nanoemulsion after 15 years of preparation: a suitable vehicle for pharmaceutical and cosmetic applications. J. Disper. Sci. Technol. 2010, 31:17-22.
7. Izquierdo P., Feng J., Esquena J., Tadros T.F., Dederen J.C., García M.J., Solans C. The influence of surfactant mixing ratio on nano-emulsion formation by the pit method. J. Colloid Interface Sci. 2005, 285:388-394.
8. Forgiarini A., Esquena J., González C., Solans C. Formation and stability of nano-emulsions in mixed nonionic surfactant systems. Prog. Colloid Polym. Sci. 2001, 118:184-189.
9. Liu W.R., Sun D.J., Li C.F., Liu Q., Xu J. Formation and stability of paraffin oil-in-water nano-emulsions prepared by the emulsion inversion point method. J. Colloid Interface Sci. 2006, 303:557-563.
10. Forgiarini A., Esquena J., Gonzalez C., Solans C. Formation of nano-emulsions by low-energy emulsification methods at constant temperature. Langmuir 2001, 17:2076-2083.
11. Förster T., Rybinski W.V. Applications of emulsions. Modern Aspects of Emulsion Science 1998, 395-426. The Royal Society of Chemistry, Cambridge, UK.
12. Morales D., Gutiérrez J.M., Garcia-Celma J.M., Solans C. A study of the relation between bicontinuous microemulsions and oil/water nanoemulsion formation. Langmuir 2003, 19:7196-7200.
13. 6/mineral oil system. Langmuir 2006, 22:3014-3020.
14. Scamehorn J.F. Phenomena in Mixed Surfactant Systems 1986, American Chemical Society, Washington, AD.
15. Huibers P.T.D., Shah D.O. Evidence for synergism in nonionic surfactant mixtures: enhancement of solubilization in water-in-oil microemulsions. Langmuir 1997, 13:5762-5765.
16. Schott H., Royce A. Effect of inorganic additives on solutions of nonionic surfactants V: emulsion stability. J. Pharm. Sci. 1983, 72:1427-1436.
17. Shinoda K., Takeda A.H. The effect of added salts in water on the hydrophile-lipophile balance of nonionic surfactants: the effect of added salts on the phase inversion temperature of emulsions. J. Colloid Interface Sci. 1970, 32:642-646.
18. Anton N., Saulnier P., Béduneau A., Benoit J.-P. Salting-out effect induced by temperature cycling on a water/nonionic surfactant/oil system. J. Phys. Chem. B 2007, 111:3651-3657.
19. Schott H. Salting in of nonionic surfactants by complexation with inorganic salts. J. Colloid Interface Sci. 1973, 43:150-155.
20. Schott H., Han S.K. Effect of inorganic additives on solutions of nonionic surfactants II. J. Pharm. Sci. 1975, 64:658-664.
21. Schott H., Han S.K. Effect of inorganic additives on solutions of nonionic surfactants III: CMC' s and surface properties. J. Pharm. Sci. 1976, 65:975-978.
22. Schott H., Royce A. Effect of inorganic additives on solutions of nonionic surfactants VI: further cloud point relations. J. Pharm. Sci. 1984, 73:793-799.
23. Schott H. Effect of inorganic additives on solutions of nonionic surfactants-X. Micellar properties. J. Colloid Interface Sci. 1995, 173:265-277.
24. Schott H. Effect of inorganic additives on solutions of nonionic surfactants XV. Effect of transition metal salts on the cloud point of octoxynol 9 (Triton X-100). J. Colloid Interface Sci. 1997, 192:458-462.
25. Schott H. Effect of inorganic additives on solutions of nonionic surfactants-XVI. Limiting cloud points of highly polyoxyethylated surfactants. Colloids Surf. A: Physicochem. Eng. Aspects 2001, 186:129-136.
26. Kuo Ch-H., Lee Ch-L. Treatment of a cutting oil emulsion by microwave irradiation. Sep. Sci. Technol. 2009, 44:1799-1815.
27. Ríos G., Pazos C., Coca J. Destabilization of cutting oil emulsions using inorganic salts as coagulants. Colloids Surf. A: Physicochem. Eng. Aspects 1998, 138:383-389.
28. Izquierdo P., Esquena J., Tadros T.F., Dederen C., Garcia M.J., Azemar N., Solans C. Formation and stability of nano-emulsions prepared using the phase inversion temperature method. Langmuir 2002, 18:26-30.
29. Shinoda K., Saito H. The Stability of O/W type emulsions as functions of temperature and the HLB of emulsifiers: the emulsification by PIT-method. J. Colloid Interface Sci. 1969, 30:258-263.
30. Ju T.C., Frank C.W., Gast A.P. CONTIN analysis of colloidal aggregates. Langmuir 1992, 8:2165-2171.
31. Kunieda H., Fukui Y., Uchiyama H., Solans C. Spontaneous formation of highly concentrated water-in-oil emulsions (gel-emulsions). Langmuir 1996, 12:2136-2140.
32. Anton N., Benoit J.-P., Saulnier P. Particular conductive behaviors of emulsion phase inverting. J. Drug Del. Sci. Tech. 2008, 18:0-10.
33. Goel S.K. Critical phenomena in the clouding behavior of nonionic surfactants induced by additives. J. Colloid Interface Sci. 1999, 212:604-609.
34. Goel S.K. Selecting the optimal linear alcohol ethoxylate for enhanced oily soil removal. J. Surfactants Deterg. 1998, 1:213-219.
35. Iwanaga T., Suzuki M., Kunieda H. Effect of added salts or polyols on the liquid crystalline structures of polyoxyethylene-type nonionic surfactants. Langmuir 1998, 14:5775-5781.
36. Hsu J.P., Nacu A. Behavior of soybean oil-in-water emulsion stabilized by nonionic surfactant. J. Colloid Interface Sci. 2003, 259:374-381.
37. Deminiere B., Colin A., Calderon F.L., Bibette J. Lifetime and destruction of concentrated emulsions undergoing coalescence. Modern Aspects of Emulsion Science 1998, 261-291. The Royal Society of Chemistry, Cambridge, UK.
38. Weers J.G. Molecular diffusion in emulsions and emulsion mixtures. Modern Aspects of Emulsion Science 1998, 292-327. The Royal Society of Chemistry, Cambridge, UK.
39. Wia{ogonek}cek A.E. Effect of ionic strength on electrokinetic properties of oil/water emulsions with dipalmitoylphosphatidylcholine. Colloids Surf. A: Physicochem. Eng. Aspects 2007, 302:141-149.
40. Ee S.H.L., Duan X.M., Liew J., Nguyen Q.D. Droplet size and stability of nano-emulsions produced by the temperature phase inversion method. Chem. Eng. J. 2008, 140:626-631.
41. Rao J.J., McClements D.J. Stabilization of phase inversion temperature nanoemulsions by surfactant displacement. J. Agric. Food Chem. 2010, 58:7059-7066.