Oxidative stability of biodiesel fuel

Proceedings of the Institution of Mechanical Engineers, Part D: Journal of Automobile Engineering

Volumn 225, Issue 1, 2011, Pages 99-114

  Bannister, C D ^a   Chuck, C J ^a   Bounds, M ^a   Hawley, J G ^a  

^a University of Bath   (United Kingdom)

Author keywords

biodiesel; degradation; emissions; engine durability; oxidation; review

Indexed keywords

BIODIESEL; BLENDING; DEGRADATION; FATTY ACIDS; KETONES; OILS AND FATS; OXIDATION; PARTICULATE EMISSIONS; REVIEWS; THERMAL PROCESSING (FOODS);

CHEMICAL COMPONENT; COMPLEX PROCESSES; DECOMPOSITION PRODUCTS; ENGINE DURABILITY; FATTY ACID ALKYL ESTERS; FATTY ACID PROFILES; OXIDATIVE STABILITY; STORAGE CONTAINER;

FUEL STORAGE;

EID: 78651401861     PISSN: 09544070     EISSN: None     Source Type: Journal    
DOI: 10.1243/09544070JAUTO1549     Document Type: Review

References (88)

1. Dunn, R. O. Low-temperature flow properties of vegetable oil/cosolvent blend diesel fuels. J. Am. Oil Chemists Soc., 2002, 79, 709-715.
2. Knothe, G., Van Gerpen, J., and Krahl, J. The biodiesel handbook, 2005 (AOCS Press, Campaign, Illinois).
3. Schuchardt, U., Sercheli, R. R., and Vargas, M. Transesterification of vegetable oils: a review. J. Braz. Chem. Soc., 1998, 9, 199-210.
4. Pinto, A. C., Guarieiro, L. L. N., Rezende, M. J. C., Ribeiro, N. M., Torres, E. A., Lopes, W. A., Pereira, P., and de Andrade, J. B. Biodiesel an overview. J. Braz. Chem. Soc., 2005, 16, 1313-1330.
5. Chisti, Y. Biodiesel from microalgae. Biotechnol. Adv., 2007, 25, 294-306.
6. Knothe, G. 'Designer' biodiesel: optimising fatty ester composition to improve fuel properties. Energy Fuels, 2008, 22, 1358-1364.
7. Bannister, C. D., Hawley, J. G., Ali, H. M., Chuck, C. J., Price, P., Chrysafi, S., Brown, A., and Pickford, W. The impact of biodiesel blend ratio on vehicle performance and emissions. Proc. IMechE, Part D: J. Automobile Engineering, 2010, 224(3), 405-421. DOI: 10.1243/09544070JAUTO1270.
8. Chuck, C. J., Bannister, C. D., Hawley, J. G., Davidson, M. G., La Bruna, I., and Paine, A. Predictive model to assess the molecular structure of biodiesel fuel. Energy Fuels, 2009, 23, 2290-2294.
9. Lapuerta, M., Armas, O., and Rodriguez-Fernandez, J. Effect of biodiesel fuels on diesel engine emissions. Prog. Energy Combust. Sci., 2008, 34, 198-223. (Pubitemid 351179079)
10. Freedman, B. and Bagby, M. O. Predicting cetane numbers of n-alcohols and methyl esters from their physical properties. J. Am. Oil Chemists Soc., 1990, 67, 565-571.
11. Rodrigues, J. D., Cardoso, F. D., Lachter, E. R., Estevao,L. R. M., Lima, E., and Nascimento,R. S. V. Correlating chemical structure and physical properties of vegetable oil esters. J. Am. Oil Chemists Soc., 2006, 83, 353-357.
12. Knothe, G. Dependence of biodiesel fuel properties on the structure of fatty acid alkyl esters. Fuel Processing Technol., 2005, 86, 1059-1070.
13. Dunn, R. O. Effect of oxidation under accelerated conditions on fuel properties of methyl soyate (biodiesel). J. Am. Oil Chemists Soc., 2002, 79, 915-920.
14. Demirbas, A. Biodiesel: a realistic fuel alternative for diesel engines, 2008 (Springer, London).
15. Dinkov, R., Hristov, G., Stratiev, D., and Aldayri, V. B. Effect of commercially available antioxidants over biodiesel/diesel blends stability. Fuel, 2009, 88, 732-737.
16. Dodos, G. S., Zannikos, F., and Stournas, S. Effect of metals in the oxidation stability and lubricity of biodiesel fuel. SAE technical paper 2009-01-1829, 2009.
17. Morcos, M., Parsons, G., Lauterwasser, F., Boons, M., and Hartgers, W. Detection methods for accurate measurements of the fame biodiesel content in used crankcase engine oil. SAE technical paper 2009-01-2661, 2009.
18. Fang, H. L., Alleman, T. L., and McCormick, R. L. Quantification of biodiesel content in fuels and lubricants by FTIR and NMR spectroscopy. SAE technical paper 2006-01-3301, 2006.
19. Agarwal, A. K. Experimental investigations of the effect of biodiesel utilization on lubricating oil tribology in diesel engines. Proc. IMechE, Part D: J. Automobile Engineering, 2005, 219(5), 703-713. DOI: 10.1243/ 095440705X11239. (Pubitemid 40729883)
20. Fang, H. L., Whitacre, S. D., Yamaguchi, E. S., and Boons, M. Biodiesel impact on wear protection of engine oils. SAE technical paper 2007-01-4141, 2007.
21. Andreae, M., Fang, H., and Bhandary, K. Biodiesel and fuel dilution of engine oil. SAE technical paper 2007-01-4036, 2007.
22. Ogawa, T., Kajiya, S., Kosaka, S., Tajima, I., and Yamamoto, M. Analysis of oxidative deterioration of biodiesel fuel. SAE technical paper 2008-01-2502, 2008.
23. Fang, H. L. and McCormick, R. L. Spectroscopic study of biodiesel degradation pathyways. SAE technical paper 2006-01-3300, 2006.
24. 1H-NMR and effect of contact area with air. Eur. J. Lipid Sci. Technol., 2006, 108, 493-500.
25. Monyem, A., Canakci, M., and Van Gerpen, J. H. Investigation of biodiesel thermal stability under simulated in-use conditions. Appl. Engng Agric., 2000, 16, 373-378.
26. Neff, W. E., Selke, E., Mounts, T. L., Rinsch, W., Frankel, E. N., and Zeitoun, M. A. M. Effect of triacylglycerol composition and structures on oxida-tive stability of oils from selected soybean germ-plasm. J. Am. Oil Chemists Soc., 1992, 69, 111-118.
27. Knothe, G. Some aspects of biodiesel oxidative stability. Fuel Processing Technol., 2007, 88, 669-677.
28. Morita, M. and Tokita, M. The real radical generator other than main-product hydroperoxide in lipid autoxidation. Lipids, 2006, 41, 91-95.
29. Yamane, K., Kawasaki, K., Sone, K., Hara, T., and Prakoso, T. Oxidation stability of biodiesel and its effects on diesel combustion and emission characteristics. Int. J. Engine Res., 2007, 8(3), 307-319. DOI: 10.1243/14680874JER00207. (Pubitemid 351229143)
30. Dunn, R. O. Oxidative stability of soybean oil fatty acid methyl esters by oil stability index (OSI). J. Am. Oil Chemists Soc., 2005, 82, 381-387.
31. Dunn, R. O. Effect of temperature on the oil stability index (OSI) of biodiesel. Energy Fuels, 2008, 22, 657-662.
32. Ferrari, R. A., Oliveira, V. D., and Scabio, A. Oxidative stability of biodiesel from soybean oil fatty acid ethyl esters. Scient. Agric., 2005, 62, 291-295.
33. Mittelbach, M. and Schober, S. The influence of antioxidants on the oxidation stability of biodiesel. J. Am. Oil Chemists Soc., 2003, 80, 817-823.
34. Schober, S. and Mittellbach, M. The impact of antioxidants on biodiesel oxidation stability. Eur. J. Lipid Sci. Technol., 2004, 106, 382-389.
35. Stavinoha, L. L. and Howell, S. Potential analytical methods for stability testing of biodiesel and biodiesel blends. SAE technical paper 1999-01-3520, 1999.
36. BLT - Bundesanstalt für Landtechnik (Eds), Stability of biodiesel used as a fuel for diesel engines and heating systems, Presentation of the BIOSTAB project results, Graz, Austria, 3 July 2003 (Federal Institute of Agricultural Engineering, Wieselburg).
37. Pahgova, J., Jorikova, L., and Cvengros, J. Study of FAME stability. Energy Fuels, 2008, 22, 1991-1996.
38. EN 14112:2003, Fat and oil derivatives - fatty acid methyl esters (FAME) - determination of oxidation stability (accelerated oxidation test), 2003 (Comité Européen de Normalisation, Brussels).
39. ASTM D6751, Standard specification for biodiesel fuel blend stock (B100) for distillate fuels. In Annual book of ASTM standards, vol.05.04, 2007 (ASTM International, West Conshohocken, Pennsylania).
40. Tian, K. and Dasgupta, P. K. Determination of oxidative stability of oils and fats. Analyt. Chem., 1999, 71, 1692-1698.
41. Knothe, G. and Dunn, R. O. Dependence of oil stability index of fatty compounds on their structure and concentration and presence of metals. J. Am. Oil Chemists Soc., 2003, 80, 1021-1026.
42. Canakci, M., Monyem, A., and Van Gerpen, J. Accelerated oxidation processes in biodiesel. Trans. ASAE, 1999, 42, 1565-1572.
43. Bouaid, A., Martinez, M., and Aracil, J. Production of biodiesel from bioethanol and brassica carinata oil: oxidation stability study. Bioresource Technol., 2009, 100, 2234-2239.
44. Bostyn, S., Duval-Onen, F., Porte, C., Coic, J. P., and Fauduet, H. Kinetic modelling of the degradation of the alpha-tocopherol in biodiesel-rape methyl ester. Bioresource Technol., 2008, 99, 6439-6445.
45. Frohlich, A. and Schober, S. The influence of tocopherols on the oxidation stability of methyl esters. J. Am. Oil Chemists Soc., 2007, 84, 579-585.
46. Xin, J., Imahara, H., and Saka, S. Kinetics on the oxidation of biodiesel stabilized with antioxidant. Fuel, 2008, 87, 1807-1813.
47. Ogawa, T., Kajiya, S., Kosaka, S., and Okada, M. Analysis of oxidative deterioration of biodiesel fuel. SAE technical paper 2008-01-2502, 2008.
48. Bannister, C. D., Chuck, C. J., Hawley, J. G., Price, P., and Chrysafi, S. S. Factors affecting the decomposition of biodiesel under simulated engine sump oil conditions. Proc. IMechE, Part D: J. Automobile Engineering, 2010, 224(7), 927-940. DOI: 10.1243/ 09544070JAUTO1395.
49. 1H NMR and chemometrics. Talanta, 2009, 78, 660-664.
50. 1H nuclear magnetic resonance in the study of edible oils and fats. Trends Food Sci. Technol., 2001, 12, 328-338.
51. Bondioli, P., Gasparoli, A., Della Bella, L., Taglia-bue, S., and Toso, G. Biodiesel stability under commercial storage conditions over one year. Eur. J. Lipid Sci. Technol., 2003, 105, 735-741.
52. Bondioli, P., Gasparoli, A., Lanzani, A., Fedeli, E., Veronese, S., and Sala, M. Storage stability of bio-diesel. J. Am. Oil Chemists Soc., 1995, 72, 699-702.
53. Thompson, J. C., Peterson, C. L., Reece, D. L., and Beck, S. M. Two-year storage study with methyl and ethyl esters of rapeseed. Trans. ASAE, 1998, 41, 931-939.
54. Dunn, R. O. Oxidative stability of biodiesel by dynamic mode pressurized-differential scanning calorimetry (p-DSC). Trans. ASABE, 2006, 49, 1633-1641.
55. Dunn, R. O. Effect of antioxidants on the oxidative stability of methyl soyate (biodiesel). Fuel Processing Technol., 2005, 86, 1071-1085.
56. Nik, W. B. W., Ani, F. N., and Masjuki, H. H. Thermal stability evaluation of palm oil as energy transport media. Energy Conversion Managmt, 2005, 46, 2198-2215.
57. Knothe, G. Structure indices in FA chemistry. How relevant is the iodine value? J. Am. Oil Chemists Soc., 2002, 79, 847-854.
58. Clague, A. D. H., Donnet, J. B., Wang, T. K., and Peng, J. C. M. A comparison of diesel engine soot with carbon black. Carbon, 1999, 37, 1553-1565
59. Rounds, F. G. Carbon: cause of diesel engine wear? SAE technical paper 770829, 1977.
60. Gautam, M., Durbha, M., Chitoor, K., Jaraiedi, M., Mariwalla, N., and Ripple, D. Contribution of soot contaminated oils to wear. SAE technical paper 981406, 1998.
61. Green, D. A. and Lewis, R. Effect of soot on oil properties wear of engine components. J. Phys. D, Appl. Phys., 2007, 40, 5488-5501.
62. Shayler, P., Allen, A. J., Leong, D. K. W., Pegg, I., Brown, A. J., and Dumenil, J.-C. Characterising lubricating oil viscosity to describe effects on engine friction. SAE technical paper 2007-01-1984, 2007.
63. Bannister, C. D., Hawley, J. G., Brace, C. J., Pegg, I., Dumenil, J. C., and Brown, A. Determining the effect of lubricating oil properties on diesel engine fuel economy. In Proceedings of the Conference on Internal combustion engines: performance, fuel economy and emissions, London, UK, 11-12 December 2008, pp. 247-258 (Chandos Publishing, Oxford).
64. Moore, S. L. The effect of viscosity grade on piston ring wear and oil film thickness in two particular diesel engines. SAE technical paper 874184, 1987.
65. Petiteaux, M. and Monsallier, G. Impacts of biodiesel blends on fuel filter functions, laboratory and field tests results. SAE technical paper 2009-01-1876, 2009.
66. Taniguchi, S., Yoshida, K., Kitano, K., and Sakata, I. Effect of biodiesel fuel oxidation deterioration on exhaust emissions in a diesel vehicle. SAE technical paper 2008-08-0296, 2008.
67. Wadumesthrige, K., Smith, J. C., Wilson, J. R., Salley, S. O., and Ng, K. Y. S. Investigation of the parameters affecting the cetane number of biodie-sel. J. Am. Oil Chemists Soc., 2008, 85, 1073-1081.
68. Knothe, G., Matheaus, A. C., and Ryan, T. W. Cetane numbers of branched and straight-chain fatty esters determined in an ignition quality tester. Fuel, 2003, 82(8), 971-975.
69. Monyem, A. and Van Gerpen, J. H. The effect of biodiesel oxidation on engine performance and emissions. Biomass Bioenergy, 2001, 20, 317-325.
70. Tang, H., De Guzman, R. C., Salley, S. O., and Ng, S. K. Y. The oxidative stability of biodiesel: effects of fame composition and antioxidant. Lipid Tech-nol., 2008, 20, 249-252.
71. Karavalakis, G., Karonis, D., and Stournas, S. Evalutation of the oxidation stability of diesel/ biodiesel blends using the modified rancimat method. SAE technical paper 2009-01-1828, 2009.
72. Gunstone, F. D., Harwood, J. L., and Padley, F. B. The lipid handbook, 2nd edition, 1994 (Cambridge University Press, Cambridge).
73. Mittelbach, M. and Gangl, S. Long storage stability of biodiesel made from rapeseed and used frying oil. J. Am. Oil Chemists Soc., 2001, 78, 573-577.
74. Kalitchin, Z. D., Ivanov, S. K., Tanielyan, S. K., Boneva, M. I., Georgiev, P. T., Ivanov, A., and Kanariev, K. Chemical-stability of diesel fuels and sediment formation therein.1. Evaluation of the chemical-stability of diesel fuels by following the kinetics of sediment formation. Fuel, 1992, 71, 437-442.
75. Clark, B., Wang, A., Salley, S. O., and Ng, S. K. Y. Catalytic effects of transition metals on the oxidative stability of various biodiesels. In Proceeedings of the AIChE Annual Meeting 2007, Salt Lake City, Utah, USA, 4-9 November 2007, paper 394a (American Institute of Chemical Engineers, New York).
76. Miyata, I., Takei, Y., Tsurutani, K., and Okada, M. Effects of bio-fuels on vehicle performance: degradation mechanism analysis of bio-fuels. SAE technical paper 2004-01-3031, 2004.
77. Liang, Y. C., May, C. Y., Foon, C. S., Ngan, M. A., Hock, C. C., and Basiron, Y. The effect of natural and synthetic antioxidants on the oxidative stability of palm diesel. Fuel, 2006, 85, 867-870.
78. Kowalski, B. Evaluation of activities of antioxidants in rapeseed oil matrix by pressure differential scanning calorimetry. Thermochim. Acta, 1993, 213, 135-146.
79. Kowalski, B. Evaluation of the stability of some antioxidants for fat-based foods. Thermochim. Acta, 1991, 177, 9-14.
80. Kowalski, B. Thermal-oxidative decomposition of edible oils and fats - DSC studies. Thermochim. Acta, 1991, 184, 49-57.
81. Bessee, G. B. and Fey, J. P. Compatibility of elastomers and metals in biodiesel fuel blends. SAE technical paper 971690, 1997.
82. Waynick, J. A. Characterization of biodiesel oxidation and oxidation products. Technical literature review, CRC Project AVFL-2b, Task 1 results, SwRIH Project 08-10721, National Renewable Energy Laboratory, US Department of Energy, Golden, Colorado, USA, August 2005.
83. Perez, J. M. Oxidative properties of lubricants using thermal analysis. Thermochim. Acta, 2000, 357, 47-56.
84. Hasenhuettl, G. L. and Wan, P. J. Temperature effects on the determination of oxidative stability with the metrohm Rancimat. J. Am. Oil Chemists Soc., 1992, 69, 525-527.
85. Mittelbach, M. and Remschmidt, C. Biodiesel - the comprehensive handbook, 2004 (Karl-Franzens University, Graz).
86. 2+ or ultraviolet light. J. Am. Oil Chemists Soc., 1998, 75, 1717-1721.
87. Ghazali, Z., Wan Nik, W. B., Ku Bulat, K. H., Ani, F. N., and Xian, L. F. The effect of light on the oxidative stability of palm olein. In Proceedings of the First International Conference on Natural resources engineering and technology, Putrajaya, Malaysia, 2006, pp. 631-637.
88. Bouaid, A., Martinez, M., and Aracil, J. Long storage stability of biodiesel from vegetable and used frying oils. Fuel, 2007, 86, 2596-2602.