Oxidative stability of biodiesel from soybean oil fatty acid ethyl esters;Estabilidade oxidativa de biodiesel de ésteres etílicos de ácidos graxos de soja

Scientia Agricola

Volumn 62, Issue 3, 2005, Pages 291-295

  Ferrari, Roseli Ap ^a   Oliveira, Vanessa da Silva ^a   Scabio, Ardalla ^a  

^a STATE UNIVERSITY OF PONTA GROSSA   (Brazil)

Author keywords

Oxidation; Rancimat ; Transesterification

Indexed keywords

EID: 85016165632     PISSN: 01039016     EISSN: 1678992X     Source Type: Journal    
DOI: 10.1590/S0103-90162005000300014     Document Type: Article

References (32)

1. ABREU, F.R.; LIMA, D.G.; HAMÚ, C.W.; SUAREZ, P.A.Z. Utilization of metal complexes as catalysts in the transesterification of Brazilian vegetable oils with different alcohols. Journal of Molecular Catalysis A: Chemical, v.209, p.29-33, 2004.
2. AGÊNCIA NACIONAL DE PETRÓLEO - ANP. Portaria nº 255 de 15 de setembro de 2003. Disponível em:
3. AL-WIDYAN, M.I.; AL-SHYOUKH, A.O. Experimental evaluation of the transesterification of waste palm oil into biodiesel. Bioresource Tecnology, v.85, p.253-256, 2002.
4. AMERICAN OIL CHEMISTS SOCIETY - AOCS. Official and tentative methods. 3.ed. Chicago: AOCS, 1997. v.1.
5. ANTOLÍN, G.; TINAUT, F.V.; BRICEÑO, Y.; CASTAÑO, V.; PÉRZ, C.; RAMÍREZ, A. I. Optimization of biodiesel production by sunflower oil transesterification. Bioresource Tecnology, v.83, p.111-114, 2002.
6. BAGLEY, S.T.; GRATZ, L.D.; JONSON, J.H.; MCDONALD, J.F. Effects of an oxidation catalytic converter and a biodiesel fuel on the chemical, mutagenic, and particle size characteristics of emissions from a diesel engine. Environmental Science & Technology, v.32, p.1183-1191, 1998.
7. CARDONE, M.; PRATI, M.V.; ROCCO, V.; SEGGIANI, M.; SENATORE, A.; VITOLO, S. Brassica carinata as an alternative oil crop for the production of biodiesel in Italy: engine performance and regulated and unregulated exhaust emissions. Environmental Science & Technology, v.36, p.4656-4662, 2002.
8. COSTA NETO, P.R.; ROSSI, L.F.S.; ZAGONEL, G.F.; RAMOS, L.P. Produção de biocombustível alternativo ao óleo diesel através da transesterificação de óleo de soja usado em frituras. Química Nova, v.23, p.531-537, 2000.
9. DORADO, M.P.; BALLESTEROS, E.; ARNAL, J.M.; GÓMEZ, J.; GIMÉNEZ, F.J.L. Testing waste olive oil methyl ester as a fuel in a diesel engine. Energy & Fuels, v.17, p.1560-1565, 2003.
10. DORADO, M.P.; BALLESTEROS, E.; LÓPEZ, F.J.; MITTELBACH. Optimization of alkali-catalyzed transesterification of Brassica carinata oil for biodiesel production. Energy & Fuels, v.18, p.77-83, 2004.
11. DU PLESSIS, L.M.; DE VILLIERS, J.B.M.; VAN DER WALT, W.H. Stability studies on methyl and ethyl fatty acid esters of sunflower seed oil. Journal of the AOCS, v.62, p.748-752, 1985.
12. DUNN, R.O. Effect of oxidation under accelerated conditions on fuel properties of methyl soyate (biodiesel). Journal of the AOCS, v.79, p.915-920, 2002.
13. ENCINAR, J.M.; GONZÁLEZ, J.F.; SABIO, E.; RAMIRO, M.J. Preparation and properties of biodiesel from Cynara cardunculus L. oil. Industry and Engineering Chemistry Resource, v.38, p.2927-2931, 1999.
14. ENCINAR, J.M.; GONZÁLES, J.F.; RODRÍGUEZ, J.J.; TEJEDOR, A. Biodiesel fuels from vegetables Oils: Transesterification of Cynara cardunculus L. oils with ethanol. Energy & Fuels, v.19, p.443-450, 2002.
15. ERICKSON, D.R. Practical handbook of soybean processing and utilization. Champaign: AOCS Press, 1995. 584p.
16. HAAS, M.J.; SCOTT, K.M.; ALLEMAN, T.L.; MCCORMICK, R.L. Engine performance of biodiesel fuel prepared from soybean soapstock: A high quality renewable fuel produced from a waste feedstock. Energy & Fuels, v.15, p.1207-1212, 2001.
17. HARTEN, B. Uso de centrífugas para los procesos de biodiesel. Aceites & Grasas, v.13, p.98-105, 2003.
18. HARTMAN, L.; LAGO, R.C.A. Rapid preparation of fatty acid methyl esters from lipids. Laboratory Practice, v.8, p.475-476, 1973.
19. HARTMAN, L.; ESTEVES, W. Tecnologia de óleos e gorduras vegetais. São Paulo: SICCT, 1981, 167p. (Série Tecnologia Industrial).
20. KNOTHE, G.; MATHEAUS, A.C.; RYAN III, T.W. Cetane numbers of branched and straight-chain fatty esters determined in an ignition quality tester. Fuel, v.82, p.971-975, 2003.
21. MITTELBACH, M.; GANGL, S. Long storage stability of biodiesel made from rapeseed and used frying oil. Journal of the AOCS, v.78, p.573-577, 2001.
22. MONYEM, A.; VAN GERPEN, J.H. The effect of biodiesel oxidation on engine performance and emissions. Biomass & Bioenergy, v.20, p.317-325, 2001.
23. MONYEM, A.; VAN GERPEN, J.H.; CANAKCI, M. The effect of timing and oxidation emissions from biodiesel-fueled engines. Transactions of the ASAE, v.44, p.35-42, 2001.
24. MUSHRUSH, G.W.; BEAL, E.J.; HUGHES, J.M.; WYNNE, J.H.; SAKRAN, J.V.; HARDY, D.R. Biodiesel fuels: use of soy oil as a blending stock for middle distillate petroleum fuels. Industry and Engineering Chemistry Resource, v.39, p.3945-3948, 2000.
25. MUSHRUSH, G.W.; MOSE, D.G.; WRAY, C.L.; SULLIVAN, K.T. Biofuels as a means of improving the quality of petroleum middle distillate fuels. Energy Sources, v.23, p.649-655, 2001a.
26. MUSHRUSH, G.; BEAL, E.J.; SPENCER, G.; WYNNE, J.H.; LLOYD, C.L.; HUGHES, J.M.; WALL, C.L.; HARDY, D.R. An environmentally benign soybean derived fuel as a blending stock or replacement for home heating oil. Journal of Environmental Science and Health, v.36, p.613-622, 2001b.
27. NASCIMENTO, M.G.; COSTA NETO, P.R.; MAZZUCO, L.M. Biotransformação de óleos e gorduras: utilização de lipases para obtenção de biocombustível. Revista Biotecnologia de Ciência & Desenvolvimento, v.19, p.28-31, 2001.
28. NOUREDDINI, H.; HARKEY, D.; MEDIKONDURU, V.A. Continuous process for the conversion of vegetable oil into methyl esters of fatty acids. Journal of the AOCS, v.75, p.1775-1783, 1998.
29. PACHECO, M.T.B. Obtenção e fracionamento do óleo do fígado de tubarão azul (Prionace glauca) e sua estabilização com antioxidantes. Campinas: UNICAMP 1991. 123p. (Dissertação - Mestrado).
30. SCHUCHARDT, U.; SERCHELI, R.; VARGAS, R.M. Transesterification of vegetable oils: a review. Journal of Brazilian Chemical Society, v.9, p.199-210, 1998.
31. SERDARI, A.; LOIS, E.; STOURNAS, S. Impact of esters of mono- and dicarboxilic acids on diesel fuel quality. Industry and Engineering Chemistry Resource, v.38, p.3543-3548, 1999.
32. WU, W.H.; FOGLIA, T.A.; MARMER, W.N.; DUNN, R.O.; GOERING, C.E.; BRIGGS, T.E. Low-temperature property and engine performance evaluation of ethyl and isopropyl esters of tallow and grease. Journal of the AOCS, v.75, p.1173-1178, 1998.