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2O (0.2 mL) were placed in a thick Pyrex tube (ca. 20 cm long). The sealed tube was heated at 170 °C for 15 days to yield light-yellow block-shaped crystals. The crystals were washed with ethanol, dried, and stored under vacuum (27% yield based on In). Elem anal. Calcd: C, 10.97; H, 3.07; N, 8.53. Found: C, 10.91; H, 3.13; N, 8.56. Synthesis of 2: The light-yellow crystals of 2 were prepared by a method similar to that used in the synthesis of the crystals of 1 except that Co powder was replaced by Ni powder (yield 42%, based on In). Elem anal. Calcd: C, 10.97; H, 3.07; N, 8.53. Found: C, 10.93; H, 3.12; N, 8.55. IR data of 1 and 2 are given in the Supporting Information. The CCDC reference numbers for 1 and 2 are 800560 and 800561, respectively.
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