[Cd16In64S134]44-: 31-Å tetrahedron with a large cavity

Angewandte Chemie - International Edition

Volumn 42, Issue 16, 2003, Pages 1819-1821

  Li, Hailian ^a   Kim, Jaheon ^a   O'Keeffe, Michael ^b   Yaghi, Omar M ^a  

^a UNIVERSITY OF MICHIGAN   (United States)

^b ARIZONA STATE UNIVERSITY   (United States)

Author keywords

Clusters; Indium; Microporous materials; Sulfides; Supertetrahedra

Indexed keywords

CRYSTAL STRUCTURE; NEGATIVE IONS;

TETRAHEDRAL UNITS;

CADMIUM COMPOUNDS;

CADMIUM DERIVATIVE;

AQUEOUS SOLUTION; ARTICLE; ATOM; CATION EXCHANGE; CHEMICAL COMPOSITION; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; ELECTROCHEMICAL ANALYSIS; QUANTUM MECHANICS; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0038031682     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200250748     Document Type: Article

References (45)

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2. Some recent papers which give references to earlier work are: a) S. Empedocles, M. Bawendi, Acc. Chem. Res. 1999, 32, 389-396; b) U. Banin, Y. Cao, D. Katz, O. Milo, Nature 1999, 400, 542-544; c) V. I. Klimov, A. A. Mikhailovsky, S. Xu, A. Malko, J. A. Hollingsworth, C. A. Leatherdale, H.-J. Eisler, M. Bawendi, Science 2000, 290, 314-317; d) F. W. Wise, Acc. Chem. Res. 2000, 33, 773-780; e) X. Peng, I. Manna, W. Yang, J. Wickham, E. Scher, A. Kadavanich, A. P. Alivistos, Nature 2000, 404, 59-61; f) X. Huang, J. Li, J. Am. Chem. Soc. 2000, 122, 8789-8790; g) V. N. Soloviev, A. Eichhöfer, D. Fenske, U. Banin, J. Am. Chem. Soc. 2001, 123, 2354-2364; h) M. Fuentes-Cabrera, H. Wang, B. Daniels, O. F. Sankey, Phys. Rev. B 2002, 66, 045109; i) P. N. Trikalitis, K. K. Rangan, T. Bakas, M. G. Kanatzidis, Nature 2001, 410, 671-675.
3. Some recent papers which give references to earlier work are: a) S. Empedocles, M. Bawendi, Acc. Chem. Res. 1999, 32, 389-396; b) U. Banin, Y. Cao, D. Katz, O. Milo, Nature 1999, 400, 542-544; c) V. I. Klimov, A. A. Mikhailovsky, S. Xu, A. Malko, J. A. Hollingsworth, C. A. Leatherdale, H.-J. Eisler, M. Bawendi, Science 2000, 290, 314-317; d) F. W. Wise, Acc. Chem. Res. 2000, 33, 773-780; e) X. Peng, I. Manna, W. Yang, J. Wickham, E. Scher, A. Kadavanich, A. P. Alivistos, Nature 2000, 404, 59-61; f) X. Huang, J. Li, J. Am. Chem. Soc. 2000, 122, 8789-8790; g) V. N. Soloviev, A. Eichhöfer, D. Fenske, U. Banin, J. Am. Chem. Soc. 2001, 123, 2354-2364; h) M. Fuentes-Cabrera, H. Wang, B. Daniels, O. F. Sankey, Phys. Rev. B 2002, 66, 045109; i) P. N. Trikalitis, K. K. Rangan, T. Bakas, M. G. Kanatzidis, Nature 2001, 410, 671-675.
4. Some recent papers which give references to earlier work are: a) S. Empedocles, M. Bawendi, Acc. Chem. Res. 1999, 32, 389-396; b) U. Banin, Y. Cao, D. Katz, O. Milo, Nature 1999, 400, 542-544; c) V. I. Klimov, A. A. Mikhailovsky, S. Xu, A. Malko, J. A. Hollingsworth, C. A. Leatherdale, H.-J. Eisler, M. Bawendi, Science 2000, 290, 314-317; d) F. W. Wise, Acc. Chem. Res. 2000, 33, 773-780; e) X. Peng, I. Manna, W. Yang, J. Wickham, E. Scher, A. Kadavanich, A. P. Alivistos, Nature 2000, 404, 59-61; f) X. Huang, J. Li, J. Am. Chem. Soc. 2000, 122, 8789-8790; g) V. N. Soloviev, A. Eichhöfer, D. Fenske, U. Banin, J. Am. Chem. Soc. 2001, 123, 2354-2364; h) M. Fuentes-Cabrera, H. Wang, B. Daniels, O. F. Sankey, Phys. Rev. B 2002, 66, 045109; i) P. N. Trikalitis, K. K. Rangan, T. Bakas, M. G. Kanatzidis, Nature 2001, 410, 671-675.
5. Some recent papers which give references to earlier work are: a) S. Empedocles, M. Bawendi, Acc. Chem. Res. 1999, 32, 389-396; b) U. Banin, Y. Cao, D. Katz, O. Milo, Nature 1999, 400, 542-544; c) V. I. Klimov, A. A. Mikhailovsky, S. Xu, A. Malko, J. A. Hollingsworth, C. A. Leatherdale, H.-J. Eisler, M. Bawendi, Science 2000, 290, 314-317; d) F. W. Wise, Acc. Chem. Res. 2000, 33, 773-780; e) X. Peng, I. Manna, W. Yang, J. Wickham, E. Scher, A. Kadavanich, A. P. Alivistos, Nature 2000, 404, 59-61; f) X. Huang, J. Li, J. Am. Chem. Soc. 2000, 122, 8789-8790; g) V. N. Soloviev, A. Eichhöfer, D. Fenske, U. Banin, J. Am. Chem. Soc. 2001, 123, 2354-2364; h) M. Fuentes-Cabrera, H. Wang, B. Daniels, O. F. Sankey, Phys. Rev. B 2002, 66, 045109; i) P. N. Trikalitis, K. K. Rangan, T. Bakas, M. G. Kanatzidis, Nature 2001, 410, 671-675.
6. Some recent papers which give references to earlier work are: a) S. Empedocles, M. Bawendi, Acc. Chem. Res. 1999, 32, 389-396; b) U. Banin, Y. Cao, D. Katz, O. Milo, Nature 1999, 400, 542-544; c) V. I. Klimov, A. A. Mikhailovsky, S. Xu, A. Malko, J. A. Hollingsworth, C. A. Leatherdale, H.-J. Eisler, M. Bawendi, Science 2000, 290, 314-317; d) F. W. Wise, Acc. Chem. Res. 2000, 33, 773-780; e) X. Peng, I. Manna, W. Yang, J. Wickham, E. Scher, A. Kadavanich, A. P. Alivistos, Nature 2000, 404, 59-61; f) X. Huang, J. Li, J. Am. Chem. Soc. 2000, 122, 8789-8790; g) V. N. Soloviev, A. Eichhöfer, D. Fenske, U. Banin, J. Am. Chem. Soc. 2001, 123, 2354-2364; h) M. Fuentes-Cabrera, H. Wang, B. Daniels, O. F. Sankey, Phys. Rev. B 2002, 66, 045109; i) P. N. Trikalitis, K. K. Rangan, T. Bakas, M. G. Kanatzidis, Nature 2001, 410, 671-675.
7. Some recent papers which give references to earlier work are: a) S. Empedocles, M. Bawendi, Acc. Chem. Res. 1999, 32, 389-396; b) U. Banin, Y. Cao, D. Katz, O. Milo, Nature 1999, 400, 542-544; c) V. I. Klimov, A. A. Mikhailovsky, S. Xu, A. Malko, J. A. Hollingsworth, C. A. Leatherdale, H.-J. Eisler, M. Bawendi, Science 2000, 290, 314-317; d) F. W. Wise, Acc. Chem. Res. 2000, 33, 773-780; e) X. Peng, I. Manna, W. Yang, J. Wickham, E. Scher, A. Kadavanich, A. P. Alivistos, Nature 2000, 404, 59-61; f) X. Huang, J. Li, J. Am. Chem. Soc. 2000, 122, 8789-8790; g) V. N. Soloviev, A. Eichhöfer, D. Fenske, U. Banin, J. Am. Chem. Soc. 2001, 123, 2354-2364; h) M. Fuentes-Cabrera, H. Wang, B. Daniels, O. F. Sankey, Phys. Rev. B 2002, 66, 045109; i) P. N. Trikalitis, K. K. Rangan, T. Bakas, M. G. Kanatzidis, Nature 2001, 410, 671-675.
8. Some recent papers which give references to earlier work are: a) S. Empedocles, M. Bawendi, Acc. Chem. Res. 1999, 32, 389-396; b) U. Banin, Y. Cao, D. Katz, O. Milo, Nature 1999, 400, 542-544; c) V. I. Klimov, A. A. Mikhailovsky, S. Xu, A. Malko, J. A. Hollingsworth, C. A. Leatherdale, H.-J. Eisler, M. Bawendi, Science 2000, 290, 314-317; d) F. W. Wise, Acc. Chem. Res. 2000, 33, 773-780; e) X. Peng, I. Manna, W. Yang, J. Wickham, E. Scher, A. Kadavanich, A. P. Alivistos, Nature 2000, 404, 59-61; f) X. Huang, J. Li, J. Am. Chem. Soc. 2000, 122, 8789-8790; g) V. N. Soloviev, A. Eichhöfer, D. Fenske, U. Banin, J. Am. Chem. Soc. 2001, 123, 2354-2364; h) M. Fuentes-Cabrera, H. Wang, B. Daniels, O. F. Sankey, Phys. Rev. B 2002, 66, 045109; i) P. N. Trikalitis, K. K. Rangan, T. Bakas, M. G. Kanatzidis, Nature 2001, 410, 671-675.
9. Some recent papers which give references to earlier work are: a) S. Empedocles, M. Bawendi, Acc. Chem. Res. 1999, 32, 389-396; b) U. Banin, Y. Cao, D. Katz, O. Milo, Nature 1999, 400, 542-544; c) V. I. Klimov, A. A. Mikhailovsky, S. Xu, A. Malko, J. A. Hollingsworth, C. A. Leatherdale, H.-J. Eisler, M. Bawendi, Science 2000, 290, 314-317; d) F. W. Wise, Acc. Chem. Res. 2000, 33, 773-780; e) X. Peng, I. Manna, W. Yang, J. Wickham, E. Scher, A. Kadavanich, A. P. Alivistos, Nature 2000, 404, 59-61; f) X. Huang, J. Li, J. Am. Chem. Soc. 2000, 122, 8789-8790; g) V. N. Soloviev, A. Eichhöfer, D. Fenske, U. Banin, J. Am. Chem. Soc. 2001, 123, 2354-2364; h) M. Fuentes-Cabrera, H. Wang, B. Daniels, O. F. Sankey, Phys. Rev. B 2002, 66, 045109; i) P. N. Trikalitis, K. K. Rangan, T. Bakas, M. G. Kanatzidis, Nature 2001, 410, 671-675.
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39. 2O)50: C 11.33, H 2.73, N 3.52, S 24.56, Cd 10.28, In 42.00; found C 11.28, H 2.35, N 3.61, S 22.94, Cd 10.56, In 41.82.
40. -3, respectively. CCDC-197754 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via wwwccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+44) 1223-336-033; or deposit@ccdc.cam.ac.uk).
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42. -1 (w).
43. 5 super-supertetrahedron.
44. 5, diamond nets see M. O'Keeffe, S. T, Hyde, Z. Kristallogr. 1996, 211, 73-78.
45. 5, diamond nets see M. O'Keeffe, S. T, Hyde, Z. Kristallogr. 1996, 211, 73-78.