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Volumn 44, Issue 16, 2005, Pages 5686-5695

Unusual syntheses, structures, and electronic properties of compounds containing ternary, T3-type supertetrahedral M/Sn/S anions [M 5Sn(μ3-S)4(SnS4) 4]10- (M = Zn, Co)

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Indexed keywords


EID: 23844512150     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic050466o     Document Type: Article
Times cited : (85)

References (70)
  • 25
    • 0003472375 scopus 로고
    • Verlag Chemie GmbH: Weinheim, Germany 8. Aufl., Kobalt B
    • (a) Gmelins Handbuch der Anorganischen Chemie; Verlag Chemie GmbH: Weinheim, Germany 1964; 8. Aufl., Kobalt B.
    • (1964) Gmelins Handbuch der Anorganischen Chemie
  • 28
    • 33645334119 scopus 로고    scopus 로고
    • note
    • 3+), however, lead to redox processes under the given reaction conditions. Variations of both the reaction conditions and the starting materials that allow the formation of stable ternary networks containing further transition metal ions are the focus of our current work.
  • 30
    • 33645353011 scopus 로고    scopus 로고
    • note
    • +. The overall effect is the reduction of the positive charge available; it does not increase it. Similarly, it was found that refinement of Na(10) and its coordinated waters with unit occupancy was unsatisfactory, but that Na(10) could be successfully refined at half occupancy, together with an adjacent one-half of an oxygen atom (O(34A) in the cif file), which made normal hydrogen-bonding distances to adjacent ordered oxygen atoms possible, while the oxygen atoms coordinated to Na(10) could all be split and refined as pairs of one-half of an oxygen. It was found that the disorder at these three sites was correlated; the disordered oxygen atoms labeled A in the cif file, together with Na(11) and Na(12), form one set of atoms that made sensible nonbonding contacts, while the oxygen atoms labeled B in the cif file, with Na(10), Na(13), and Na(14), formed a second mutually consistent set. Two further oxygen atoms, O(5), O(19), O(23), and O(26), were also disordered, but without correlating to either of the two above sets of atoms.
  • 33
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.