Solvothermal synthesis, crystal structure, thermal stability, and Mössbauer spectroscopic investigation of the mixed-valent thioantimonate(III,V) [Ni(dien)2]2Sb4S9

Angewandte Chemie - International Edition

Volumn 41, Issue 23, 2002, Pages 4487-4489

  Stähler, Ralph ^a   Mosel, Bernd Dieter ^b   Eckert, Hellmut ^b   Bensch, Wolfgang ^a  

^a UNIVERSITY OF KIEL   (Germany)

^b UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

Antimony; Mixed valent compounds; Moessbauer spectroscopy; Solvothermal synthesis; Structure elucidation

Indexed keywords

ANTIMONY; CRYSTAL STRUCTURE; NEGATIVE IONS; THERMODYNAMIC STABILITY;

OXIDATION STATES;

SYNTHESIS (CHEMICAL);

ANTIMONY DERIVATIVE; METAL COMPLEX; NICKEL; THIOANTIMONATE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL ANALYSIS; COMPLEX FORMATION; CRYSTAL STRUCTURE; MOSSBAUER SPECTROSCOPY; SYNTHESIS; TECHNIQUE; THERMOGRAVIMETRY; THERMOSTABILITY;

EID: 1542665814     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3773(20021202)41:23<4487::AID-ANIE4487>3.0.CO;2-8     Document Type: Article

References (31)

1. W. S. Sheldrick, M. Wachhold, Coord. Chem. Rev. 1998, 176, 211-322.
2. A.V. Powell, R. Paniagua, P. Vaqueiro, A. M. Chippindale, Chem. Mater. 2002, 14, 1220-1224.
3. W S. Sheldrick, M. Wachhold, Angew. Chem. 1997, 109, 214-234;
4. Angew Chem. Int. Ed. 1997, 36, 206-224.
5. X. Wang, F. Liebau. Acta Crystallogr. Sect. B. 1996, 52, 7-15.
6. W. S. Sheldrick. H.-J. Häusler, Z. Anorg. Allg. Chem. 1988, 557, 105-111.
7. X. Wang, F. Liebau, Z. Kristallogr. 1996, 211, 437-439.
8. A. V. Powell, S. Boissiere, A. M. Chippindale, J. Chem. Soc. Dalton Trans. 2000, 22, 4192-4195.
9. (a) G. Dittmar, H. Schäfer, Z. Anorg. Allg. Chem. 1977, 437, 183-187;
10. (b) G. Dittmar, H. Schäfer, Z. Anorg. Allg. Chem. 1975, 414, 211-219;
11. (c) G. Dittmar, H. Schäfer, Z. Anorg. Allg. Chem. 1978. 414, 93-97;
12. (d) G. Dittmar, H. Schäfer, Z. Anorg. Allg. Chem, 1978, 441, 98-102;
13. (e) B. Eisenmann, H. Schäfer, Z. Naturforsch. B 1979, 34, 383-385;
14. (f) G. Cordier, H. Schäfer. C. Schwidetzky, Z. Naturforsch. B 1984, 39, 131-134;
15. (g) K, Volk, P. Bickert, R. Kolmer, H. Schäfer, Z. Naturforsch. B 1979, 34, 380-382;
16. (h) G. Cordier, H. Schäfer, Rev. Chim. Miner 1981, 18, 218-223;
17. (i) G. Cordier, H. Schäfer, C. Schwidetzky, Rev. Chim. Miner 1985, 22, 722-727;
18. (j) H. A. Graf, H. Schäfer, Z. Naturforsch. B 1972, 27, 735-739.
19. X. Wang, F. Liebau, Acta Crystallogr. Sect. B. 1996, 52, 7-15.
20. 2 using SHELXL-97.[10c] All heavy atoms were refined anisotropically. Several C atoms are disordered with occupancies given in parentheses: C6(50%), C6′(50%), C9(60%), C9′(40%), C11(50%), C11′(50%), C13(70%), C13′(30%). The hydrogen atoms were positioned with idealized geometry and refined with fixed isotropic displacement parameters using a riding model. Final reliability values: R1 = 0.0344 for all reflections, wR2 = 0.0682 for all reflections, goodness-of-fit = 1.058. CCDC-188070 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac. uk);
21. G. M. Sheldrick, SHELXS-97, Program for the Solution of Crystal-Structures, Universiẗt of Göttingen, Göttingen (Germany), 1997;
22. G. M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structures, University of Göttingen, G̈ttingen (Germany), 1997.
23. W. Bensch, C. Näther, R. Stähler, Chem. Commun. 2001, 5, 477-478.
24. R. Stähler, C. Näther, W. Bensch, Acta Crystallogr. Sect. C 2001, 57, 26-27.
25. R. Stähler, W. Bensch, Z. Anorg. Allg. Chem. 2002, 628, 1657-1662.
26. J. Ellermeier, W. Bensch, Monatsh. Chem. 2001, 132, 565-573.
27. R. Stähler, C. Näther, W. Bensch, Eur. J. Inorg. Chem. 2001, 1835-1840.
28. M. Schur, W. Bensch, Acta Crystallogr. Sect. C 2000, 56, 1107-1108.
29. M. Schur, H. Rijnberk, C. Näther, W. Bensch, Polyhedron 1998, 18, 101-107.
30. R. Stähler, C. Näther, W. Bensch, unpublished work.
31. J. G. Stevens in "Chemical Mössbauer Spectroscopy", (Ed.: R. H. Herber) Plenum Press, New York, 1984, p. 319.