Crystal of semiconducting quantum dots built on covalently bonded T5 [In28Cd6S54]-12: The largest supertetrahedral cluster in solid state

Journal of the American Chemical Society

Volumn 124, Issue 44, 2002, Pages 12944-12945

  Su, Weiping ^a   Huang, Xiaoying ^a   Li, Jing ^a   Fu, Huaxiang ^b  

^a RUTGERS UNIVERSITY   (United States)

^b UNIVERSITY OF ARKANSAS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CADMIUM; INDIUM; NANOPARTICLE; SULFUR;

ARTICLE; COVALENT BOND; CRYSTAL STRUCTURE; CRYSTALLIZATION; DIPOLE; QUANTUM CHEMISTRY; SEMICONDUCTOR; SOLID STATE;

EID: 0037032258     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja027830s     Document Type: Article

References (37)

1. (a) Alivisators, A. P. Science, 1996, 271, 933.
2. (b) Steigerwald, M. L.; Brus, L. E. Acc. Chem. Res. 1990, 23, 183.
3. Brus, L. E. J. Phys. Chem. 1984, 80, 4403.
4. (a) Emepedocles, S.; Bawendi, M. Acc. Chem. Res. 1999, 32, 389.
5. (b) Nirmal, M.; Bras, L. E. Acc. Chem. Res. 1999, 32, 407.
6. (c) Markovich, G.; Collier, C. P.; Henrichs, S. E.; Remacle F.; Levine R. D.; Heath, J. R. Acc. Chem. Res. 1999, 32, 415.
7. Wise, F. W. Acc. Chem. Res. 2000, 33, 773.
8. (a) Peng, X.; Manna, L.; Yang, W.; Wickham, J.; Scher E.; Kadavanich, A.; Alivisators, A. P. Nature 2000, 404, 59.
9. (b) Peng, Z. A. and Peng, X. J. Am. Chem. Soc. 2001, 123, 183.
10. Murray, C. B.; Norris, D. J.; Bawendi, M. G. J. Am. Chem. Soc. 1993, 115, 8706.
11. Chen, S.; Truax L. A.; Sommers J. M. Chem. Mater. 2000, 12, 3864.
12. Nanda, J.; Sapra, S.; Sarma, D. D. Chem. Mater. 2000, 12, 1018.
13. Haram, S. K.; Quinn, B. M.; Bard, A. J. J. Am. Chem. Soc. 2001, 123, 8860.
14. Klimov, V. I.; Mikhailovsky, A. A.; Xu, S.; Malko, A.; Hollingsworth, J. A.; Leatherdale, C. A.; Eisler, H. J.; Bawendi, M. G. Science 2000, 290, 314.
15. Murray, C. B.; Kagan, C. R.; Bawendi, M. G. Science 1995, 270, 1335.
16. Kagan, C. R.; Murray, C. B.; Bawendi, M. G. Phys. Rev. B 1996, 54, 8633.
17. Weiser, G.; Moller, S. Phys. Rev. B 2002, 65, 045203.
18. Jiang P., Bertone J. F.; Colvin V. L., Science 2001, 291, 453.
19. 3.5 were collected.
20. -1) 2977, 2671
21. 4 (T1) tetrahedral unit to form a tetrahedrally shaped cluster. The resultant cluster is a fragment of cubic zinc blende structure. It is generally notated as Tn, where n is the number of tetrahedral subunits linked along each edge. A crystal of supertetrahedral clusters is a periodic lattice built upon Tn.
22. (a) Li, H.; Kim, J.; Groy, T. L.; O'Keeffe, M. O.; Yaghi, O. M. J. Am. Chem. Soc. 2001, 123, 4867.
23. (b) Wang, C.; Li, Y.; Bu, X.; Zheng, N.; Zivikovic, O.; Yang, C.; Feng, P. J. Am. Chem. Soc. 2001, 123, 11506.
24. Soloviev, V. N.; Eichhöfer, A.; Fenske, D.; Banin, U. J. Am. Chem. Soc. 2001, 123, 2354.
25. Cahill, C. L.; Parise, J. B. J. Chem. Soc., Dalton Trans. 2000, 1475.
26. (a) Yaghi, O. M.; Sun, Z.; Richardson, D. A.; Groy, T. L. J. Am. Chem. Soc. 1994, 116, 807.
27. (b) Tan, K.; Darovsky, A.; Parise, J. B. J. Am. Chem. Soc. 1995, 117, 7039.
28. (c) Cahill, C. L.; Ko, Y.; Parise, J. B. Chem. Mater. 1998, 10, 19.
29. (d) Li, H.; Laine, A.; O'Keeffe, M.; Yaghi, O. M. Science 1999, 283, 1145.
30. (e) Li, H.; Eddaoudi, M.; Laine, A.; O'Keeffe, M.; Yaghi, O. M. J. Am. Chem. Soc. 1999, 121, 6096.
31. Optical diffuse reflectance measurements were performed on a Shimadzu UV-3101PC double-beam, double]-monochromator spectrophotometer.
32. Kohn, W.; Sham, L. J. Phys. Rev. 1965, 140, A1133.
33. Troullier, N.; Martins, J. L. Phys. Rev. 1991, B 43, 1993.
34. (a) Huang X. Y., Li J., Fu H.-X., J. Am. Chem. Soc. 2000, 122, 8789.
35. (b) Fu H.-X. In Fundamental Physics of Ferroelectrics; Cohen, R. E., Cohen, Ed.; AIP: New York, 2002; p. 17.
36. Cardona M.; Weinstein M.; Wolff G. A. Phys. Rev. 1965, 140, A633.
37. Chelikowsky J. R.; Cohen M. L. Phys. Rev. B 1976, 14, 556.