Reaction of enol ethers with the I2-H2O2 system: Synthesis of 2-iodo-1-methoxy hydroperoxides and their deperoxidation and demethoxylation to 2-iodo ketones

Synthesis

Volumn , Issue 24, 2009, Pages 4159-4166

  Terent'ev, Alexander O ^a   Borisov, Alexander M ^a   Platonov, Maxim M ^a   Starikova, Zoya A ^a   Chernyshev, Vladimir V ^a   Nikishin, Gennady I ^a  

^a N D ZELINSKY INSTITUTE OF ORGANIC CHEMISTRY   (Russian Federation)

Author keywords

Enol ethers; Hydrogen peroxide; Iodine; Peroxidation; Peroxides

Indexed keywords

DEPEROXIDATION; DIETHYL ETHERS; ENOL ETHERS; HYDROPEROXIDES; METHOXY; PEROXIDATION; REACTION CONDITIONS;

ETHERS; HYDROGEN; HYDROGEN PEROXIDE; INDUSTRIAL CHEMICALS; IODINE; KETONES; SYNTHESIS (CHEMICAL);

OXIDATION;

1 BUTYL 2 IODO 1 METHOXYPENTYL HYDROPEROXIDE; 1 HYDROPEROXY 2 IODO 1 METHOXYCYCLOHEXANE; 1 HYDROXYPEROXY 2 IODO 1 METHOXYCYCLOALKANONE; 1 METHOXYCYCLOHEPTENE; 1 METHOXYCYCLOHEXENE; 2 IODO 1 ISOBUTYL 1 METHOXY 3 METHYLBUTYL HYDROPEROXIDE; 2 IODO 1 METHOXY 4 METHYLCYCLOHEXYL HYDROPEROXIDE; 2 IODO 1 METHOXY HYDROPEROXIDE DERIVATIVE; 2 IODO 1 METHOXYCYCLODODECYL HYDROPEROXIDE; 2 IODO 1 METHOXYCYCLOHEPTYL HYDROPEROXIDE; 2 IODO 1 METHOXYCYCLOHEXYL HYDROXYPEROXIDE; 2 IODO 1 METHOXYCYCLOOCTYL HYDROPEROXIDE; 2 IODO 4 METHYLCYCLOHEXANONE; 2 IODO KETONE DERIVATIVE; 2 IODOCYCLOALKANONE; 2 IODOCYCLODODECANONE; 2 IODOCYCLOHEPTANONE; 2 IODOCYCLOHEXANONE; 2 IODOCYCLOOCTANONE; 3 IODO 2,6 DIMETHYLHEPTAN 4 ONE; 4 IODONONAN 5 ONE; 4 TERT BUTYL 2 IODO 1 METHOXYCYCLOHEXYL HYDROPEROXIDE; 4 TERT BUTYL 2 IODOCYCLOHEXANONE; ACETONITRILE; CYCLOALKANONE; ETHER; HYDROGEN PEROXIDE; HYDROPEROXIDE DERIVATIVE; KETONE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; BAEYER VILLIGER REACTION; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; ELECTROPHILICITY; HALOGENATION; HYDROGEN BOND; IODINATION; PEROXIDATION; POLYMERIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION TIME; STOICHIOMETRY; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 78650730715     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0029-1217062     Document Type: Article

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