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Advanced Synthesis and Catalysis
Volumn 352, Issue 18, 2010, Pages 3339-3347
(Cyclopentadienyl)ruthenium-catalyzed regio- and enantioselective decarboxylative allylic etherification of allyl aryl and alkyl carbonates
Author keywords

allylic compounds; catalyst recyclability; enantioselective catalysis; etherification; ruthenium catalysts
Indexed keywords

EID: 78650376497     PISSN: 16154150     EISSN: 16154169     Source Type: Journal    
DOI: 10.1002/adsc.201000696     Document Type: Article
Times cited : (42)
References (94)
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    • Recently the same group showed that carboxylates are also effective nucleophiles, see
    • Recently the same group showed that carboxylates are also effective nucleophiles, see:, N. Kanbayashi, K. Onitsuka, J. Am. Chem. Soc. 2010, 132, 1206-1207.
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    • The loss of enantiopurity is attributed to the instability of the phenyl carbonate on the silica gel used for its purification
    • The loss of enantiopurity is attributed to the instability of the phenyl carbonate on the silica gel used for its purification.
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    • The term cee stands for conservation of enantiomeric excess that is [product ee/reactant ee]× 100
    • The term cee stands for conservation of enantiomeric excess that is [product ee/reactant ee]× 100.
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    • Ligands 2 and ent- 2 have the (+)-(3R,8S) and (-)-(3S,8R) configurations, respectively
    • Ligands 2 and ent- 2 have the (+)-(3R,8S) and (-)-(3S,8R) configurations, respectively.
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    • These carbonates were used without purification to avoid on silica gel the racemization and the rearrangement to the primary carbonate analogues
    • These carbonates were used without purification to avoid on silica gel the racemization and the rearrangement to the primary carbonate analogues.
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    • 1H NMR, 400 MHz) at the beginning and the end of every reaction due to the configurational lability of the CpRu moiety. TRISPHAT-N was used in racemic form only as its dissociation from the complex is necessary to liberate the catalytically active CpRu fragment
    • 1H NMR, 400 MHz) at the beginning and the end of every reaction due to the configurational lability of the CpRu moiety. TRISPHAT-N was used in racemic form only as its dissociation from the complex is necessary to liberate the catalytically active CpRu fragment.

* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.