Toward an Improved Understanding of the Unusual Reactivity of Pd 0/Trialkylphosphane Catalysts in Cross-Couplings of Alkyl Electrophiles: Quantifying the Factors That Determine the Rate of Oxidative Addition

Angewandte Chemie - International Edition

Volumn 42, Issue 46, 2003, Pages 5749-5752

  Hills, Ivory D ^a   Netherton, Matthew R ^a   Fu, Gregory C ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

Cross coupling; Homogeneous catalysis; Palladium; Phosphane ligands; Reaction mechanisms

Indexed keywords

ADDITION REACTIONS; CATALYSTS; OXIDATION;

ELECTROPHILES;

PALLADIUM COMPOUNDS;

ALKANE DERIVATIVE; PALLADIUM; TRIPHOSPHANE; UNCLASSIFIED DRUG;

ADDITION REACTION; ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; OXIDATION; REACTION ANALYSIS; REACTION TIME; REDUCTION;

ALKYLATION; KINETICS; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; PALLADIUM; PHOSPHINES; STEREOISOMERISM; THERMODYNAMICS;

EID: 0348134860     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200352858     Document Type: Article

References (56)

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53. 3.[3b-d]
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55. -1 higher in energy than the eclipsed conformation. b) These calculations are, of course, imperfect, since they do not account for effects such as solvation.
56. 2 structures in Figure 2b are not the direct result of calculations-they are derived from computed structures 1 and 2.