Catalytic enantioselective fluorination of α-chloro-β-keto esters in the presence of chiral nickel complexes

Advanced Synthesis and Catalysis

Volumn 352, Issue 16, 2010, Pages 2783-2786

  Kang, Seung Hee ^a   Kim, Dae Young ^a  

^a Soonchunhyang University   (South Korea)

Author keywords

chloro keto esters; asymmetric catalysis; chiral nickel complexes; electrophilic fluorination

Indexed keywords

EID: 78349269566     PISSN: 16154150     EISSN: 16154169     Source Type: Journal    
DOI: 10.1002/adsc.201000515     Document Type: Article

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90. We have checked the possibility of self-disproportionation of chiral fluorinated products 3 in line with the suggestion made by one of the reviewer. Chiral fluorinated product (3a) was not subjected to the self-disproportionation of enantiomers via chromatographic purification and evaporation steps. See the Supporting Information for details.