Enantioselective organocatalytic conjugate addition of α-nitroacetate to α,β-unsaturated ketones in water

Tetrahedron Letters

Volumn 51, Issue 21, 2010, Pages 2906-2908

  Moon, Hyoung Wook ^a   Kim, Dae Young ^a  

^a Soonchunhyang University   (South Korea)

Author keywords

Nitroacetate; Asymmetric catalysis; Bifunctional organocatalysts; Michael reaction; Nitromethylation

Indexed keywords

ACETIC ACID DERIVATIVE; KETONE DERIVATIVE; NITROALKANE; WATER;

AQUEOUS SOLUTION; ARTICLE; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; CONJUGATION; ENANTIOSELECTIVITY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY;

EID: 77950928145     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2010.03.105     Document Type: Article

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83. 4 and concentrated in vacuo. The crude product was purified by column chromatography on silica gel, eluted by hexane/EtOAc = 5:1 to give the desired product 4.