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Volumn 16, Issue 41, 2010, Pages 12286-12294

N-heterocyclic carbene mediated activation of tetravalent silicon compounds: A critical evaluation

Author keywords

carbenes; Lewis bases; organocatalysis; polymers; silanes

Indexed keywords

CARBENES; CRITICAL EVALUATION; ELECTROPHILES; HYDROSILANES; LEWIS ACID-BASE; LEWIS BASIS; N-HETEROCYCLIC CARBENES; ORGANIC TRANSFORMATIONS; ORGANOCATALYSIS; POLYMERISATION; PRONUCLEOPHILES;

EID: 78249282599     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201001120     Document Type: Review
Times cited : (69)

References (71)
  • 5
    • 53049091364 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2008, 47, 3122 - 3172
    • (2008) Angew. Chem. Int. Ed. , vol.47 , pp. 3122-3172
  • 9
    • 34250797354 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2007, 46, 2768 - 2813.
    • (2007) Angew. Chem. Int. Ed. , vol.46 , pp. 2768-2813
  • 24
    • 53549132547 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2008, 47, 5390 - 5393
    • (2008) Angew. Chem. Int. Ed. , vol.47 , pp. 5390-5393
  • 30
    • 70349854454 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2009, 48, 3322 - 3325.
    • (2009) Angew. Chem. Int. Ed. , vol.48 , pp. 3322-3325
  • 34
    • 36549000812 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2007, 46, 8632 - 8635.
    • (2007) Angew. Chem. Int. Ed. , vol.46 , pp. 8632-8635
  • 37
    • 50249134990 scopus 로고    scopus 로고
    • 1638, and references therein.
    • Angew. Chem. Int. Ed. 2008, 47, 1560 - 1638, and references therein.
    • (2008) Angew. Chem. Int. Ed. , vol.47 , pp. 1560
  • 48
    • 78249233055 scopus 로고    scopus 로고
    • [25]
    • [25]
  • 50
    • 54749110969 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2008, 47, 7433 - 7437
    • (2008) Angew. Chem. Int. Ed. , vol.47 , pp. 7433-7437
  • 52
    • 54749125732 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2008, 47, 7428 - 7432.
    • (2008) Angew. Chem. Int. Ed. , vol.47 , pp. 7428-7432
  • 69
    • 78249259473 scopus 로고    scopus 로고
    • 2 by hydrosilanes has revealed that this reaction proceeds via an energetically favourable transition state involving an NHC-Si interaction, despite the fact that the NHC-Si complex is thermodynamically unstable (F. Huang, G. Lu, L. Zhao, H. Li, Z.-X. Wang, J. Am. Chem. Soc. 2010, DOI:). This study also reveals the exact reaction pathway traversed and that the stability of plausible NHC-Si intermediates are dependent on the exact NHC used in the study. Alternatively, for a further example of a computational study on stable NHC-Si interactions (principally halosilanes), the reader is referred to the study by Nyulászi and co-workers
    • 2 by hydrosilanes has revealed that this reaction proceeds via an energetically favourable transition state involving an NHC-Si interaction, despite the fact that the NHC-Si complex is thermodynamically unstable (F. Huang, G. Lu, L. Zhao, H. Li, Z.-X. Wang, J. Am. Chem. Soc. 2010, DOI:). This study also reveals the exact reaction pathway traversed and that the stability of plausible NHC-Si intermediates are dependent on the exact NHC used in the study. Alternatively, for a further example of a computational study on stable NHC-Si interactions (principally halosilanes), the reader is referred to the study by Nyulászi and co-workers
  • 70
    • 67651048952 scopus 로고    scopus 로고
    • 4164), alongside the corresponding experimental studies reported by Roesky and co-workers
    • O. Hollóczki, L. Nyulászi, Organometallics 2009, 28, 4159 - 4164), alongside the corresponding experimental studies reported by Roesky and co-workers
    • (2009) Organometallics , vol.28 , pp. 4159
    • Hollóczki, O.1    Nyulászi, L.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.