Unprecedented peroxidase-like activity of rhodnius prolixus nitrophorin 2: Identification of the [FeIV=O Por•]+ and [FeIV=O Por](Tyr38•) intermediates and their role(s) in substrate oxidation

Biochemistry

Volumn 49, Issue 41, 2010, Pages 8857-8872

  Singh, Rahul ^a   Berry, Robert E ^b   Yang, Fei ^b   Zhang, Hongjun ^b   Walker, F Ann ^b   Ivancich, Anabella ^a  

^a DIF   (France)

^b University of Arizona   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; ABSORPTION SPECTROSCOPY; AMINO ACIDS; ANTIFERROMAGNETISM; BODY FLUIDS; ELECTRON SPIN RESONANCE SPECTROSCOPY; HYDROGEN; HYDROGEN BONDS; HYDROGEN PEROXIDE; NITRIC OXIDE; OXIDATION; PARAMAGNETIC RESONANCE; PORPHYRINS;

ACIDIC PH; ANTIFERROMAGNETIC COUPLING INTERACTIONS; BIFUNCTIONAL; BIOLOGICAL FUNCTIONS; DUAL FUNCTION; ELECTRON PARAMAGNETIC RESONANCE; ELECTRONIC ABSORPTION; ELECTRONIC ABSORPTION SPECTROSCOPY; ENZYMATIC REACTION; EPR SPECTRA; HEME POCKETS; HEME PROPIONATES; HEME PROTEINS; HYDROGEN BONDING INTERACTIONS; KINETIC STUDY; NATURALLY OCCURRING; NITROPHORIN; PEROXIDASE ACTIVITIES; PH-DEPENDENT; RADICAL SITES; STOPPED FLOW; STRUCTURAL DIFFERENCES; SUBSTRATE OXIDATION;

REACTION INTERMEDIATES;

FERROMAGNETIC MATERIAL; HEMOPROTEIN; HISTAMINE; HYDROGEN PEROXIDE; NITROPHORIN 2; NORADRENALIN; PEROXIDASE; TYROSINE; UNCLASSIFIED DRUG; HEME; INSECT PROTEIN; IRON; NITROPHORIN; SALIVA PROTEIN;

ABSORPTION SPECTROSCOPY; ARTICLE; CONTROLLED STUDY; ELECTRON SPIN RESONANCE; ENZYME ACTIVITY; ENZYME METABOLISM; ENZYME SUBSTRATE; HYDROGEN BOND; INSECT; MOLECULAR INTERACTION; NONHUMAN; PH; PRIORITY JOURNAL; PROTEIN STRUCTURE; RHODNIUS PROLIXUS; SALIVA; AMINO ACID SUBSTITUTION; ANIMAL; BEETLE; BINDING SITE; CHEMISTRY; ENZYMOLOGY; GENETICS; KINETICS; METABOLISM; MISSENSE MUTATION; OXIDATION REDUCTION REACTION;

HEXAPODA; RHODNIUS PROLIXUS;

AMINO ACID SUBSTITUTION; ANIMALS; BEETLES; BINDING SITES; ELECTRON SPIN RESONANCE SPECTROSCOPY; HEME; HEMEPROTEINS; INSECT PROTEINS; IRON; KINETICS; MUTATION, MISSENSE; OXIDATION-REDUCTION; PEROXIDASE; SALIVARY PROTEINS AND PEPTIDES;

EID: 77957898207     PISSN: 00062960     EISSN: 15204995     Source Type: Journal    
DOI: 10.1021/bi100499a     Document Type: Article

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