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Volumn 45, Issue 31, 2006, Pages 5169-5173

Trigonal pyramids: Alternative ground-state structures for sixteen-electron complexes

Author keywords

Alkene ligands; Density functional calculations; Rhodium; Si ligands; Silanes

Indexed keywords

COMPLEXATION; GROUND STATE; MOLECULAR STRUCTURE; OLEFINS; RHODIUM; SILANES;

EID: 33747238226     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200601352     Document Type: Article
Times cited : (15)

References (31)
  • 1
    • 33747227847 scopus 로고    scopus 로고
    • note
    • I complexes with approximately planar structures.
  • 4
    • 0001251096 scopus 로고
    • 3(L) fragments (M = V, Mo, Fe) with TP structures were observed in transition metal sulfide clusters: a) I. Noda, B. S. Snyder, R. H. Holm, Inorg. Chem. 1986, 25, 3851;
    • (1986) Inorg. Chem. , vol.25 , pp. 3851
    • Noda, I.1    Snyder, B.S.2    Holm, R.H.3
  • 20
    • 33747262636 scopus 로고    scopus 로고
    • note
    • 3 group was found.
  • 21
    • 33747224317 scopus 로고    scopus 로고
    • note
    • -1).
  • 22
    • 33747324019 scopus 로고    scopus 로고
    • The synthesis of the related dibenzophosphasemibullvalene was recently reported: J. Geier, G. Frison, H. Grützmacher, Angew. Chem. 2003, 115, 4085;
    • (2003) Angew. Chem. , vol.115 , pp. 4085
    • Geier, J.1    Frison, G.2    Grützmacher, H.3
  • 24
    • 33747272328 scopus 로고    scopus 로고
    • -3. All non-hydrogen atoms were refined anisotropically. The contribution of the hydrogen atoms in their calculated positions was included in the refinement by using a riding model. CCDC-602113 (3), -602114 (4), and -602115 (5) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
  • 30
    • 33747210961 scopus 로고    scopus 로고
    • note
    • Note that most Lewis acids change their structure on complexation of a nucleophile, for instance, from trigonal planar to tetrahedral.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.