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Volumn 131, Issue 12, 2009, Pages 4236-4238

Fluxionality of [(Ph 3P) 3Rh(X)]: The extreme case of X = CF 3

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION PARAMETER; AXIAL POSITIONS; CARBON ATOMS; ELECTRON DONATION; ELECTRON-WITHDRAWING EFFECTS; ELECTRONIC FACTORS; EXTREME CASE; FLUXIONALITY; INTRAMOLECULAR EXCHANGE; LIGAND EXCHANGES; NUMBER OF SPECIES; TRANS INFLUENCE; TRANSITION STATE; VACANT SITES; VARIABLE TEMPERATURE;

EID: 67849101404     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9005699     Document Type: Article
Times cited : (43)

References (41)
  • 12
    • 0000136549 scopus 로고    scopus 로고
    • 2] (M = Cd, Hg) has been proposed, but neither complex was detected because of facile hydrolysis leading to Rh carbonyl species. See: Burrell, A. K.; Clark, G. R.; Jeffrey, J. G.; Rickard, C. E. F.; Roper, W. R. J. Oreanomet. Chem. 1990, 388, 391.
    • 2] (M = Cd, Hg) has been proposed, but neither complex was detected because of facile hydrolysis leading to Rh carbonyl species. See: Burrell, A. K.; Clark, G. R.; Jeffrey, J. G.; Rickard, C. E. F.; Roper, W. R. J. Oreanomet. Chem. 1990, 388, 391.
  • 13
    • 67849126104 scopus 로고    scopus 로고
    • See the Supporting Information for details
    • See the Supporting Information for details.
  • 14
    • 84869558842 scopus 로고    scopus 로고
    • P-Rh = 158 Hz).
    • P-Rh = 158 Hz).
  • 15
    • 84869584975 scopus 로고    scopus 로고
    • 5
    • 5
  • 16
    • 84869592445 scopus 로고    scopus 로고
    • 10
    • 10
  • 17
    • 84869590071 scopus 로고    scopus 로고
    • -1)is much higher in energy than singlet TS(2′-I′) and I′.
    • -1)is much higher in energy than singlet TS(2′-I′) and I′.
  • 19
    • 84869590073 scopus 로고    scopus 로고
    • 10
    • 10
  • 25
    • 0001230587 scopus 로고    scopus 로고
    • 3 and other polyfluoroalkyl ligands, see: (a) Bennett, M. A.; Chee, H.-K.; Robertson, G. B. Inore. Chem. 1979, 18, 1061.
    • 3 and other polyfluoroalkyl ligands, see: (a) Bennett, M. A.; Chee, H.-K.; Robertson, G. B. Inore. Chem. 1979, 18, 1061.
  • 30
    • 67849091702 scopus 로고    scopus 로고
    • See, for example:, Blackwell: Oxford, U.K
    • See, for example: Uneyama, K. Oreanofluorine Chemistry; Blackwell: Oxford, U.K., 2006.
    • (2006) Oreanofluorine Chemistry
    • Uneyama, K.1
  • 34
    • 84869592437 scopus 로고    scopus 로고
    • 25b,c
    • 25b,c
  • 41
    • 85161747750 scopus 로고    scopus 로고
    • No evidence has been obtained for substantial contributions of the proposed H-bonding interactions of the Rh complexes with solvent molecules. See: Carlton, L. Maen. Reson. Chem. 2004, 42, 760
    • No evidence has been obtained for substantial contributions of the proposed H-bonding interactions of the Rh complexes with solvent molecules. See: Carlton, L. Maen. Reson. Chem. 2004, 42, 760.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.