Highly enantioselective synthesis of (diarylmethyl)amines by rhodium-catalyzed arylation of N-nosylimines using a chiral bicyclo[3.3.0]diene ligand

Synthesis

Volumn , Issue 19, 2010, Pages 3263-3267

  Wang, Li ^a   Wang, Zhi Qian ^b   Xu, Ming Hua ^a,b   Lin, Guo Qiang ^b  

^a SHANGHAI INSTITUTE OF MATERIA MEDICA   (China)

^b SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

amines; arylations; asymmetric catalysis; diarylmethylamines; rhodium

Indexed keywords

ARYLATIONS; ARYLBORONIC ACIDS; ASYMMETRIC CATALYSIS; DIARYLMETHYLAMINES; DIENE LIGANDS; ENANTIOPURE; ENANTIOSELECTIVE SYNTHESIS; HIGH YIELD; RHODIUM-CATALYZED;

AMINES; AROMATIC COMPOUNDS; CATALYSIS; CHELATION; OLEFINS; RHODIUM;

RHODIUM COMPOUNDS;

(DIARYLMETHYL)AMINE DERIVATIVE; 1 (4 CHLOROPHENYL) 1 PHENYLMETHANAMINE; 2 (4 NOSYL) 3 PHENYLISOINDOLIN 1 ONE; 2 [(4 NITROPHENYL)SULFONYL] 3 PHENYLISOINDOLIN 1 ONE; ARYLBORONIC ACID DERIVATIVE; BICYCLO[3.3.0]DIENE; BORONIC ACID DERIVATIVE; CHEMICAL COMPOUND; LIGAND; N (DIARYLMETHYL) 4 NITROBENZENESULFONAMIDE DERIVATIVE; N (DIARYLMETHYL)NOSYLAMIDE DERIVATIVE; N [(2 CHLOROPHENYL)(4 METHOXYPHENYL)METHYL] 4 NITROBENZENESULFONAMIDE; N [(2 CHLOROPHENYL)(PHENYL)METHYL] 4 NITROBENZENESULFONAMIDE; N [(2 METHOXYPHENYL)(4 METHOXYPHENYL)METHYL] 4 NITROBENZENESULFONAMIDE; N [(4 CHLOROPHENYL)(4 METHOXYPHENYL)METHYL] 4 NITROBENZENESULFONAMIDE; N [(4 CHLOROPHENYL)(PHENYL)METHYL] 4 NITROBENZENESULFONAMIDE; N [(4 METHOXYPHENYL)(1 NAPHTHYL)METHYL] 4 NITROBENZENESULFONAMIDE; N [(4 METHOXYPHENYL)(4 METHYLPHENYL)METHYL] 4 NITROBENZENESULFONAMIDE; N [2 FURYL(PHENYL)METHYL] 4 NITROBENZENESULFONAMIDE; N NOSYLIMINE DERIVATIVE; RHODIUM; UNCLASSIFIED DRUG;

ARTICLE; ARYLATION; CATALYSIS; CHEMICAL INTERACTION; CHEMICAL MODIFICATION; CHEMICAL STRUCTURE; CHIRALITY; CONTROLLED STUDY; DECOMPOSITION; ENANTIOSELECTIVITY; PHYSICAL CHEMISTRY; SYNTHESIS;

EID: 77957126891     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0030-1258210     Document Type: Article

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