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For functionalized Grignard reagents, see: (a) Knochel, P.; Dohle, W.; Gommermann, N.; Kneisel, F. F.; Kopp, F.; Korn, T.; Sapountzis, I.; Vu, V. A. Angew. Chem., Int. Ed. 2003, 42, 4302-4320. For functionalized lithium reagents, see: (b) Nájera, C.; Yus, M. Curr. Org. Chem. 2003, 7, 867-926.
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Korn, T.6
Sapountzis, I.7
Vu, V.A.8
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18
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0037687811
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For functionalized Grignard reagents, see: (a) Knochel, P.; Dohle, W.; Gommermann, N.; Kneisel, F. F.; Kopp, F.; Korn, T.; Sapountzis, I.; Vu, V. A. Angew. Chem., Int. Ed. 2003, 42, 4302-4320. For functionalized lithium reagents, see: (b) Nájera, C.; Yus, M. Curr. Org. Chem. 2003, 7, 867-926.
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Kuriyama, M.1
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Chen, Q.4
Tomioka, K.5
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(c) Tokunaga, N.; Otomaru, Y.; Okamoto, K.; Ueyama, K.; Shintani, R.; Hayashi, T. J. Am. Chem. Soc. 2004, 126, 13584-13585.
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Shintani, R.5
Hayashi, T.6
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22
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0041738169
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Rhodium-catalyzed additions of arylboronic acids to aldehydes and α,β-unsaturated ketones proceed with a high level of functional group compatibility, (a) Hayashi, T.; Yamasaki, K. Chem. Rev. 2003, 103, 2829-2844. (b) Fagnou, K.; Lautens, M. Chem. Rev. 2003, 103, 169-196.
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Hayashi, T.1
Yamasaki, K.2
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23
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0037243669
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Rhodium-catalyzed additions of arylboronic acids to aldehydes and α,β-unsaturated ketones proceed with a high level of functional group compatibility, (a) Hayashi, T.; Yamasaki, K. Chem. Rev. 2003, 103, 2829-2844. (b) Fagnou, K.; Lautens, M. Chem. Rev. 2003, 103, 169-196.
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Fagnou, K.1
Lautens, M.2
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37049096162
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(a) Ramage, R.; Hopton, D.; Parrott, M.; Kenner, G. W.; Moore, G. A. J. Chem. Soc., Perkin Trans. 1 1984, 1357-1370.
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(c) Andersson, P. G.; Guijarro, D.; Tanner, D. J. Org. Chem. 1997, 62, 7364-7375.
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27
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13644259586
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note
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See Supporting Information for details and complete tables of results.
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29
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0001479072
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(b) Boyd, S. E.; Field, L. D.; Hambley, T. W.; Partridge, M. G. Organometallics 1993, 12, 1720-1724.
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Boyd, S.E.1
Field, L.D.2
Hambley, T.W.3
Partridge, M.G.4
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30
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13644270055
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3N complexes, which may transmetalate more rapidly. See: McKinley, N. F.; O'Shea, D. F. J. Org. Chem. 2004, 69, 5088-5090.
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McKinley, N.F.1
O'Shea, D.F.2
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31
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13644264458
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note
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1 = 2-phenylethyl).
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32
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13644259587
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note
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Other ligands screened gave very low conversions; for example, PHA-NEPHOS, DIOP, QUINAP, JOSIPHOS, WALPHOS, MANDYPHOS, i-Pr-PHOX, Me-BPE.
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33
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0000652292
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This ligand is available as "catASium D(R)" from Strem Chemicals, Inc. and ACBR, GmbH. Nagel, U.; Kinzel, E.; Andrade, J.; Prescher, G. Chem. Ber. 1986, 119, 3326-2243.
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Chem. Ber.
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Nagel, U.1
Kinzel, E.2
Andrade, J.3
Prescher, G.4
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34
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13644261054
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note
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Quantities of 3.6 (ref 4c) to 5.0 (ref 4b) equiv of arylboronic acid are generally used with N-toluenesulfonyl imine substrates in similar reactions.
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