Ketone-alcohol hydrogen-transfer equilibria: Is the biooxidation of halohydrins blocked?

Chemistry - A European Journal

Volumn 16, Issue 36, 2010, Pages 11012-11019

  Bisogno, Fabricio R ^a   García Urdiales, Eduardo ^a   Valdés, Haydee ^a   Lavandera, Iván ^a   Kroutil, Wolfgang ^b   Suárez, Dimas ^a   Gotor, Vicente ^a  

^a UNIVERSITY OF OVIEDO   (Spain)

^b UNIVERSITY OF GRAZ   (Austria)

Author keywords

Computational chemistry; Enzyme catalysis; Halohydrins; Hydrogen transfer; Ir spectroscopy

Indexed keywords

2-PROPANOL; ACTIVE SITE; ALCOHOL DEHYDROGENASE; BIO-OXIDATION; CARBONYL COMPOUNDS; CARBONYL GROUPS; DEGREE OF CONVERSION; ELECTRON WITHDRAWING GROUP; ELECTROPHILICITY; ENZYMATIC REDUCTION; ENZYME CATALYSIS; G-VALUES; GENERAL METHOD; HALOHYDRINS; HYDROGEN ACCEPTOR; HYDROGEN TRANSFER; INITIAL RATE; IR ABSORPTION; IR SPECTROSCOPY; ISODESMIC; KINETIC EFFECT; LACTOBACILLUS BREVIS; MEERWEIN-PONNDORF-VERLEY-OPPENAUER; OXIDATION OF ALCOHOLS; REDOX EQUILIBRIUM; REDOX TRANSFORMATIONS; REDUCTION PROCESS; THEORETICAL APPROACH; THERMODYNAMIC CONTROL; TRANSFER EQUILIBRIUM;

CARBONYLATION; CATALYSIS; ENZYMES; HYDROGEN; IRIDIUM; KETONES; OXIDATION; REACTION RATES;

COMPUTATIONAL CHEMISTRY;

ALCOHOL DERIVATIVE; HYDROGEN; KETONE;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; HALOGENATION; MOLECULAR COMPUTER; OXIDATION REDUCTION REACTION; STEREOISOMERISM;

ALCOHOLS; CATALYSIS; COMPUTERS, MOLECULAR; HALOGENATION; HYDROGEN; KETONES; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; STEREOISOMERISM;

EID: 77956953927     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201001233     Document Type: Article

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