Maximise equilibrium conversion in biphasic catalysed reactions: Mathematical description and practical guideline

Advanced Synthesis and Catalysis

Volumn 348, Issue 12-13, 2006, Pages 1591-1596

  Eckstein, Marrit F ^a,b   Peters, Martina ^b   Lembrecht, Julia ^a   Spiess, Antje C ^b   Greiner, Lasse ^b  

^a UNIVERSITY OF ROSTOCK   (Germany)

^b RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

Biotransformation; Biphasic catalysis; Equilibria; Oxidoreductases; Prediction

Indexed keywords

EID: 33748278369     PISSN: 16154150     EISSN: 15213897     Source Type: Journal    
DOI: 10.1002/adsc.200606079     Document Type: Article

References (25)

1. W. Keim, Green Chem. 2003, 5, 105-111.
2. R. V. Chaudhari, P. L. Mills, Chem. Eng. Sci. 2004, 59, 5337-5344.
3. P. J. Halling, Biotech. Adv. 1987, 5, 47-87.
4. B. Cornils, W. A. Herrmann (Eds.), Applied homogeneous catalysis with organometallic compounds, Wiley-VCH, Weinheim, 2nd edn., 2002.
5. B. Cornils, W. A. Herrmann, I. T. Horvath, W. Leitner, S. Mecking, H. Olivier-Bourbigou, D. Vogt, (Eds.), Multiphase homogeneous catalysis, Wiley-VCH, Weinheim, 2005.
6. H. Gröger, W. Hummel, C. Rollmann, F. Chamouleau, H. Hüsken, H. Werner, K. Wunderlich, K. Abokitse, K. Drauz, S. Buchholz, Tetrahedron 2004, 60, 633-640.
7. M. Villela Filho, T. Stillger, M. Müller, A. Liese, C. Wandrey, Angew. Chem. Int. Ed. 2003, 42, 2933-2996.
8. H. Klein, R. Jackstell, M. Beller, Chem. Commun. 2005, 2283-2285.
9. D. J. Adams, D. J. Cole-Hamilton, E. G. Hope, P. J. Pogorzelec, A. M. Stuart, J. Organomet. Chem. 2004, 689, 1413-1417.
10. P. J. Dyson, Chimia, 2005, 59, 66-71.
11. M. Eckstein, M. Villela Filho, A. Liese, U. Kragl, Chem. Commun. 2004, 1084-1085.
12. H. Pfründer, M. Amidjojo, U. Kragl, D. Weuster-Botz, Angew. Chem. Int. Ed. 2004, 43, 4529-4531.
13. W. Leitner, Pure Appl. Chem. 2004, 76, 635-644.
14. A. J. J. Straathof, Biotech. Bioengin. 2003, 83, 371-375.
15. G. Carrea Trends in Biotechnology 1984, 2, 102-106.
16. M. Heinemann, A. Kümmel, R. Giesen, M. B. Ansorge-Schumacher, J. Büchs, Biocatal. Biotransform. 2003, 21, 115-121.
17. K. Martinek, A. M. Klibanov, G. P. Samokhin, A. N. Semenov, I. V. Berezin, Bioorg. Khim. 1977, 3, 696-702.
18. H. J. Chae, Y. J. Yoo, Chem. Technol. Biotechnol. 1997, 70, 163-170.
19. T. Antczak, D. Hiler, S. Krystynowicz, S. Bielecki, E. Galas, J. Mol. Catal. B: Enzymatic 2001, 11, 1043-1050.
20. L. Greiner, S. Laue, A. Liese, C. Wandrey, Chem. - Eur. J. 2006, 12.
21. Note that mK ≠ 1. For mK = 1 it can be shown that X = S/(1+S) is the continual completion.
22. H. Adkins, R. M. Elofson, A. G. Rossow, C. C. Robinson, J. Am. Chem. Soc. 1949, 3622-3629.
23. S. Gladiali, G. Mestroni, in: Transition Metals for Organic Synthesis (Eds.: M. Beller, C. Bolm), Vol. 1, Wiley-VCH, New York, 1998, p. 97.
24. K. Fan, P. Ouyang, X. Wu, Z. Lu, Chem. Technol. Biotechnol. 2001, 76, 851-856.
25. J. de Bruijn, F. Busser, W. Seinen, J. Hermens, Environ. Toxicol. Chem. 1989, 8, 499-512.