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Volumn 16, Issue 33, 2010, Pages 10084-10093

Self-sorted assembly in a mixture of donor and acceptor chromophores

Author keywords

Charge transfer; Chromophores; Donor acceptor systems; Self assembly; Self sorting

Indexed keywords

AMIDE FUNCTIONALITIES; AMIDE GROUPS; CHARGE TRANSFER INTERACTION; DIIMIDE; DONOR AND ACCEPTOR; DONOR-ACCEPTOR PAIRS; DONOR-ACCEPTOR SYSTEM; DONOR-ACCEPTORS; HYDROGEN BONDING INTERACTIONS; HYDROGEN BONDINGS; MOLECULAR DESIGN; PRECISE CONTROL; SELF-SORTING; SPECTROSCOPIC STUDIES; SUPRAMOLECULAR APPROACHES; TETRACARBOXYLIC ACID;

EID: 77956102350     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201000596     Document Type: Article
Times cited : (90)

References (51)
  • 25
    • 77956121390 scopus 로고    scopus 로고
    • For self-sorting in various types of supramolecular assembly, see: a
    • For self-sorting in various types of supramolecular assembly, see: a) A. Wu, L. Isaacs, J. Am. Chem. Soc. 2006, 128, 4831;
    • (2006) J. Am. Chem. Soc. , vol.128 , pp. 4831
    • Wu, A.1    Isaacs, L.2
  • 34
    • 33846917687 scopus 로고    scopus 로고
    • For orthogonal self-assembly of donor and acceptor chromophores based on different design strategies, see: a
    • For orthogonal self-assembly of donor and acceptor chromophores based on different design strategies, see: a) T. L. Benanti, P. Saejueng, D. Venkataraman, Chem. Commun. 2007, 692;
    • (2007) Chem. Commun. , pp. 692
    • Benanti, T.L.1    Saejueng, P.2    Venkataraman, D.3
  • 37
    • 77956111042 scopus 로고    scopus 로고
    • 3 95:5 was used as the solvent for self-assembly
    • 3 (95:5) was used as the solvent for self-assembly.
  • 44
    • 77956096658 scopus 로고    scopus 로고
    • There is a small difference between the sum spectrum and the spectrum of the mixture. It is worth noting that even at λ = 600 nm, at which the absorbance should ideally be 0.0, the absorbance is actually very close to zero Figure 3b but not exactly 0.0. The very negligible absorbance arises due to scattering, and the intensity of scattering increases towards lower wavelengths. In the calculated spectrum, the effect of scattering is actually counted twice in the process of mathematical summation of the two individual spectra which might have contributed to the observed minor difference
    • There is a small difference between the sum spectrum and the spectrum of the mixture. It is worth noting that even at λ = 600 nm, at which the absorbance should ideally be 0.0, the absorbance is actually very close to zero (Figure 3b) but not exactly 0.0. The very negligible absorbance arises due to scattering, and the intensity of scattering increases towards lower wavelengths. In the calculated spectrum, the effect of scattering is actually counted twice in the process of mathematical summation of the two individual spectra which might have contributed to the observed minor difference.
  • 45
    • 77956098780 scopus 로고    scopus 로고
    • To get the sole contribution of D1 to the absorption at λ=312 nm, the spectrum was subtracted from the A1 spectrum
    • To get the sole contribution of D1 to the absorption at λ=312 nm, the spectrum was subtracted from the A1 spectrum.
  • 46
    • 77956121763 scopus 로고    scopus 로고
    • Molecular modelling was performed in Chem 3D-ultra 8.0 by using MM2 for energy minimisation
    • Molecular modelling was performed in Chem 3D-ultra 8.0 by using MM2 for energy minimisation.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.