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The simulations used to calculate the spectra involved a smaller number of water molecules (500 instead of 1500) and infinite plates (obtained by adjusting the box size to the plate lattice parameters and periodic boundary conditions). The resulting distance between the two plates is 2.1 nm, and the water layer is approximately 1.2 nm thick. Although this confinement very slightly slows down the water dynamics, we verified that the vibrational spectra and their relaxation dynamics are not affected
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