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Volumn 34, Issue 8, 2010, Pages 1556-1559

A 1,1′-ferrocenyl phosphine-borane: Synthesis, structure and evaluation in Rh-catalyzed hydroformylation

Author keywords

[No Author keywords available]

Indexed keywords

1,1' FERROCENYLPHOSPHINE BORANE; BORANE DERIVATIVE; PHOSPHINE DERIVATIVE; UNCLASSIFIED DRUG;

EID: 77955074093     PISSN: 11440546     EISSN: 13699261     Source Type: Journal    
DOI: 10.1039/c0nj00117a     Document Type: Article
Times cited : (42)

References (50)
  • 29
    • 47249128527 scopus 로고    scopus 로고
    • 1,1′-Bis(diphenylphosphino)ferrocenes featuring a pendant benzoxazaborolidine moiety were evaluated in Rh-catalyzed hydrogenation and hydroformylation of alkenes, with the aim of benefiting from secondary interactions between the pendant Lewis acid and the substrates:
    • K. A. Ostoja Starzewski N. Steinhauser B. S. Kin Macromolecules 2008 41 4095
    • (2008) Macromolecules , vol.41 , pp. 4095
    • Ostoja Starzewski, K.A.1    Steinhauser, N.2    Kin, B.S.3
  • 35
    • 0344436712 scopus 로고    scopus 로고
    • In ferrocenylboranes, the boron atom is generally tilted towards the metal center as the result of a delocalized through-space Fe→B interaction:
    • S. S. Batsanov Inorg. Mater. 2001 37 871 885
    • (2001) Inorg. Mater. , vol.37 , pp. 871-885
    • Batsanov, S.S.1
  • 42
    • 16844367937 scopus 로고    scopus 로고
    • Biaryl-bridged mono- and di-phosphines have been found to be extremely efficient ligands for the Rh-catalyzed hydroformylation of olefins,19 but to the best of our knowledge, Buchwald-type biarylphosphines such as 4 have not been evaluated so far in this context
    • T. E. Barder S. D. Walker J. R. Martinelli S. L. Buchwald J. Am. Chem. Soc. 2005 127 4685 4696
    • (2005) J. Am. Chem. Soc. , vol.127 , pp. 4685-4696
    • Barder, T.E.1    Walker, S.D.2    Martinelli, J.R.3    Buchwald, S.L.4
  • 45
    • 34250753728 scopus 로고    scopus 로고
    • Secondary interactions between the π system of the Mes group and the metal may also intervene, by analogy with that demonstrated for biarylphosphines within various Pd complexes:
    • C. J. Cobley R. D. J. Froese J. Klosin C. Qin G. T. Whiteker K. A. Abboud Organometallics 2007 26 2986 2999
    • (2007) Organometallics , vol.26 , pp. 2986-2999
    • Cobley, C.J.1    Froese, R.D.J.2    Klosin, J.3    Qin, C.4    Whiteker, G.T.5    Abboud, K.A.6


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.